Reticular chemistry has proven to be invaluable over time, thanks to the structural versatility, and tailored porosity observed in structures like metal–organic frameworks (MOFs), covalent–organic frameworks (COFs), and metal–organic polyhedra (MOPs).
By combining two different ligands and metals, MOFs can be fine-tuned for effective encapsulation and delivery of two anticancer drugs.
Multivariate metal–organic frameworks (MTV-MOFs), inspired by the sequence-controlled organization of natural systems, offer a promising platform for tailoring functional properties through precise structural modularity.
We report a strategy of optimizing the content and distribution of nitrogen sites in MOFs by a multivariate strategy to precisely improve water uptake at P/P0 = 0.2, thus boosting the cooling performance for refrig-2 applications.
Summary of the synthesis, structures and catalytic applications of Zr- and Ti-based MOFs.