Liang Zeng, Yin Zhang, Ming Hu, Xuan-Hui Ouyang and Jin-Heng Li
Chem. Soc. Rev., 2026,55, 955-1007
Abstract
Recent advancements in research on halogen atom transfer (XAT)-driven carbon radical chemistry for organohalides from the perspective of various relayed radicals such as aryl, alkyl, silyl, and boryl radicals are discussed.
Wei Shi, Bin Guan, Jian Tian, Chao Yang, Lin Guo, Yating Zhao and Wujiong Xia
Chem. Sci., 2025,16, 5967-5975
Abstract
A photocatalytic phosphine-mediated strategy for the dehalogenative deuteration of unactivated alkyl halides is herein reported.
Jia-Wei Hu, Jian Cao and Li-Wen Xu
Org. Chem. Front., 2024,11, 4757-4761
Abstract
A visible light-induced organophotocatalytic strategy for dehalogenative deuteration of a wide variety of primary, secondary, and tertiary alkyl bromides is reported.
Duo Zhang, Lei Yu and Guodong Zhang
Chem. Commun., 2026, Advance Article
Abstract
This review summarizes recent advances in silanecarboxylic acids as versatile reagents in organic synthesis, emphasizing their applications as CO sources and silyl radical precursors.
Javier Corpas, Maialen Alonso and Daniele Leonori
Chem. Sci., 2024,15, 19113-19118
Abstract
The Sonogashira-like alkynylation of alkyl halides is achieved by a photocatalytic approach exploiting amine-ligated boryl radicals as halogen-atom transfer mediators in combination with alkynyl sulfones as SOMOphilic reagents.