I. V. Bakaev, V. I. Komlyagina, A. A. Ulantikov, N. F. Romashev and A. L. Gushchin
New J. Chem., 2024,48, 18456-18464
Abstract
In this work, synthetic routes for previously unknown Rh complexes with a redox-active 2-(pyridin-2-yl)hydrazino acenaphthene-1-one (Py-mhan) are proposed and their electrochemical behavior is investigated.
Chengnan Wu, Nikolai F. Romashev, Veronika I. Komlyagina, Tamara Petrović, Ivan V. Bakaev, Pavel A. Abramov, Yuan Wang, Alexey A. Ryadun, Iakov S. Fomenko, Taotao Zou, Artem L. Gushchin and Maria V. Babak
Inorg. Chem. Front., 2026,13, 403-419
From themed collection:
Special collection for the 11th Asian Biological Inorganic Chemistry Conference
Abstract
The Rh(I) complex 3a with the 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian) ligand induces type I immunogenic cell death (ICD), whereas the analogous Ir(I) complex does not, revealing metal-specific immunogenicity.
Anton N. Lukoyanov, Yulia V. Zvereva, Anton V. Cherkasov, Grigory Yu. Zhigulin, Nikita P. Kharitonov and Sergey Yu. Ketkov
CrystEngComm, 2025,27, 1749-1762
Abstract
During the hydrolysis of metal complexes based on the dianion of (E)-2-(2,6-diisopropylphenylimino)acenaphthylene-1(2H)-one, various ligand protonation products are obtained depending on the reaction conditions.
Elena E. Bardina, Nikita Y. Shmelev, Yana N. Albrekht, Winnie Ka Yiu Koon, Pavel A. Abramov, Irina V. Mirzaeva, Dmitriy G. Sheven’, Evgeniya V. Makotchenko, Iakov S. Fomenko, Anton N. Lukoyanov, Maxim N. Sokolov, Maria V. Babak and Artem L. Gushchin
New J. Chem., 2023,47, 18251-18259
Abstract
This article reports on the synthesis and structure of novel cationic gold(I) complexes with BIAN/MIAN ligands, displaying redox activity and the antichelate effect.
Tatyana S. Koptseva, Alexandra A. Skatova, Mikhail V. Moskalev, Roman V. Rumyantcev and Igor L. Fedushkin
Dalton Trans., 2024,53, 17308-17312
Abstract
This work demonstrates unusual hydro-coupling of isocyanates using paramagnetic acenaphthene-1,2-diimine aluminum hydrides.