Iron complexes supported by silyl-NHC chelate ligands: synthesis and use for double hydroboration of nitriles

Takashi Komuro, Kohei Hayasaka, Kasumi Takahashi, Nozomu Ishiwata, Kota Yamauchi, Hiromi Tobita and Hisako Hashimoto

Dalton Trans., 2024, 53, 4041
DOI: 10.1039/D3DT03605G

Iridium complexes featuring a tridentate SiPSi ligand: from dimeric to monomeric 14, 16 or 18-electron species

Cynthia A. Cuevas-Chávez, Laure Vendier, Sylviane Sabo-Etienne and Virginia Montiel-Palma

Dalton Trans., 2019, 48, 14010
DOI: 10.1039/C9DT03136G

Planar three-coordinate iron(ii) complexes supported by sterically demanding –Si(SiMe3)2(SiMe2tBu) ligands

Reon Ishii and Yusuke Sunada

Dalton Trans., 2024, 53, 1421
DOI: 10.1039/D3DT04130A

Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

Atsushi Tahara, Yusuke Sunada, Takashi Takeshita, Ryoko Inoue and Hideo Nagashima

Chem. Commun., 2018, 54, 11192
DOI: 10.1039/C8CC04780D

Recent progress in transition metal complexes supported by multidentate ligands featuring group 13 and 14 elements as coordinating atoms

Takashi Komuro, Yumiko Nakajima, Jun Takaya and Hisako Hashimoto

Coordination Chemistry Reviews, 2022, 473, 214837
DOI: 10.1016/j.ccr.2022.214837

Recent topics of iridium-catalyzed hydrosilylation of tertiary amides to silylhemiaminals

Atsushi Tahara and Hideo Nagashima

Tetrahedron Letters, 2020, 61, 151423
DOI: 10.1016/j.tetlet.2019.151423

Ru‐Catalyzed Deoxygenative Transfer Hydrogenation of Amides to Amines with Formic Acid/Triethylamine

Yixiao Pan, Zhenli Luo, Xin Xu, Haoqiang Zhao, Jiahong Han, Lijin Xu, Qinghua Fan and Jianliang Xiao

Adv Synth Catal, 2019, 361, 3800
DOI: 10.1002/adsc.201900406

Square-Planar Iron(II) Silyl Complexes: Synthesis, Characterization, and Insertion Reactivity

C. Vance Thompson, Hadi D. Arman and Zachary J. Tonzetich

Organometallics, 2019, 38, 2979
DOI: 10.1021/acs.organomet.9b00335

Synthesis and Unique Catalytic Reactivity of Metal Complexes with Chelate-Type Silyl Ligands Connected by Xanthene

Takashi Komuro and Hiromi Tobita

J. Syn. Org. Chem., Jpn., 2018, 76, 1301
DOI: 10.5059/yukigoseikyokaishi.76.1301

Catalysts for Regio- and Stereoselective C(sp3)–H Deuteration of Tricyclohexylphosphine with Benzene-d6 Generated via Dehydrochlorination of Chlorido(dihydrido)iridium Complexes Containing a Xanthene-Based Bis(silyl) Chelate Ligand

Takashi Komuro, Junpei Asagami, Hironori Higashi, Keita Sato, Hisako Hashimoto and Hiromi Tobita

Organometallics, 2021, 40, 3113
DOI: 10.1021/acs.organomet.1c00359

Iron Catalysts with Silyl‐NHC Chelate Ligands: Controlling Factors for Hydroboration vs. Dehydrogenative Borylation of Olefins

Nozomu Ishiwata, Takashi Komuro, Kasumi Takahashi, Yasuaki Zenzai, Hiromi Tobita and Hisako Hashimoto

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202500709

Unusual Reactivity of Silicon Grease Towards Metal Alkoxides: Serendipity for Structural Chemistry

Vanessa Nahrstedt, Aida Raauf, Corinna Hegemann, Veronika Brune, Johannes Schläfer and Sanjay Mathur

Zeitschrift anorg allge chemie, 2021, 647, 1102
DOI: 10.1002/zaac.202000474

Donor–Acceptor π-Conjugated Enamines: Functional Group-Compatible Synthesis from Amides and Their Photoabsorption and Photoluminescence Properties

Atsushi Tahara, Ikumi Kitahara, Daichi Sakata, Yoichiro Kuninobu and Hideo Nagashima

J. Org. Chem., 2019, 84, 15236
DOI: 10.1021/acs.joc.9b02267

Iron-disilyl-complex-induced activation of carbonyl compounds in the deoxygenative formation of iron-carbene complexes

Yuto Suga and Yusuke Sunada

Commun Chem, 2025, 8
DOI: 10.1038/s42004-025-01604-0

O-Metalation of silanols and POSS silanols over Amberlyst-15 catalyst: A facile route to unsymmetrical siloxanes, borasiloxanes and germasiloxanes

Krzysztof Kuciński and Grzegorz Hreczycho

Inorganica Chimica Acta, 2019, 490, 261
DOI: 10.1016/j.ica.2019.03.025

Stabilization of Trans Disilyl Coordination at Square-Planar Platinum Complexes

Cynthia A. Cuevas-Chávez, Julio Zamora-Moreno, Miguel A. Muñoz-Hernández, Christian Bijani, Sylviane Sabo-Etienne and Virginia Montiel-Palma

Organometallics, 2018, 37, 720
DOI: 10.1021/acs.organomet.7b00566

Synthesis of ruthenium–bis(silyl) chelate complexes without carbonyl ligands by reactions of a bis(allyl)ruthenium(II) complex with bis(hydrosilyl)xanthene and phosphines

Takeo Kitano, Takashi Komuro, Keita Sato and Hiromi Tobita

Journal of Organometallic Chemistry, 2020, 919, 121316
DOI: 10.1016/j.jorganchem.2020.121316

Disilaruthena- and Ferracyclic Complexes Containing Isocyanide Ligands as Effective Catalysts for Hydrogenation of Unfunctionalized Sterically Hindered Alkenes

Yusuke Sunada, Hajime Ogushi, Taiji Yamamoto, Shoko Uto, Mina Sawano, Atsushi Tahara, Hiromasa Tanaka, Yoshihito Shiota, Kazunari Yoshizawa and Hideo Nagashima

J. Am. Chem. Soc., 2018, 140, 4119
DOI: 10.1021/jacs.8b00812

Seven‐Coordinate Ruthenium Complex with an SiNN‐Pincer Ligand as a Catalyst for Vinyl C─H Deuteration of Olefins

Takashi Komuro, Daiki Mochizuki, Nozomu Ishiwata, Hiromi Tobita and Hisako Hashimoto

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202500514

Platinum-catalyzed reactions of 2,3-bis(dimethylsilyl)pyridine with mono- and di-substituted alkynes

Akinobu Naka, Shouta Yoshima and Mitsuo Ishikawa

Inorganica Chimica Acta, 2021, 517, 120210
DOI: 10.1016/j.ica.2020.120210

Exploiting the Versatility of Phosphinobenzylsilanes for the Stabilization of 14‐Electron Rhodium(III) and Iridium(III) Complexes

María Vicky Corona‐González, Julio Zamora‐Moreno, Miguel A. Muñoz‐Hernández, Laure Vendier, Sylviane Sabo‐Etienne and Virginia Montiel‐Palma

Eur J Inorg Chem, 2019, 2019, 1854
DOI: 10.1002/ejic.201900107

Are Many Achievements Always Superior to One Serendipity?

Hideo Nagashima

J. Synth. Org. Chem. Jpn., 2021, 79, 72
DOI: 10.5059/yukigoseikyokaishi.79.72

Iridium-PPh3 Catalysts for Conversion of Amides to Enamines

Yuta Une, Atsushi Tahara, Yasumitsu Miyamoto, Yusuke Sunada and Hideo Nagashima

Organometallics, 2019, 38, 852
DOI: 10.1021/acs.organomet.8b00835

Design and Development of Iron-based Non-precious Metal Catalyst Systems

Yusuke Sunada and Hideo Nagashima

J. Syn. Org. Chem., Jpn., 2017, 75, 1253
DOI: 10.5059/yukigoseikyokaishi.75.1253