Synthesis and reactivity of N-heterocyclic carbene (NHC) gold-fluoroalkoxide complexes

Pierre Arnaut, Nestor Bracho Pozsoni, Fady Nahra, Nikolaos V. Tzouras and Steven P. Nolan

Dalton Trans., 2024, 53, 11952
DOI: 10.1039/D4DT01402B

Gold(i)–NHC-catalysed synthesis of benzofurans via migratory cyclization of 2-alkynylaryl ethers

Quang Le, Christopher C. Dillon, Dana A. Lichtenstein, Jeremy W. Pisor, Kristina D. Closser and Hubert Muchalski

Org. Biomol. Chem., 2020, 18, 8186
DOI: 10.1039/D0OB01538E

Margit Kriechbaum and Uwe Monkowius

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem., 2013, 109, 188
DOI: 10.1039/c3ic90022c

Heavier carbene analogues and their derivatives as κ-El, κ2-El,N, and κ2-N,N′ ligands: different reactivity patterns for acyclic and cyclic diamidogermylenes and -stannylenes

Joseph K. West, Gregory L. Fondong, Bruce C. Noll and Lothar Stahl

Dalton Trans., 2013, 42, 3835
DOI: 10.1039/c2dt32443a

Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(i)-alkylperoxo complexes

Alba Collado, Adrián Gómez-Suárez, Yoshihiro Oonishi, Alexandra M. Z. Slawin and Steven P. Nolan

Chem. Commun., 2013, 49, 10745
DOI: 10.1039/c3cc47030j

Quantifying electronic similarities between NHC–gold(i) complexes and their isolobal imidazolium precursors

Luis Miguel Azofra, Richard M. P. Veenboer, Laura Falivene, Sai V. C. Vummaleti, Albert Poater, Steven P. Nolan and Luigi Cavallo

Phys. Chem. Chem. Phys., 2019, 21, 15615
DOI: 10.1039/C9CP02844G

Synthesis and characterisation of Pd(ii) and Au(i) complexes with mesoionic carbene ligands bearing phosphinoferrocene substituents and isomeric carbene moieites

Karel Škoch, Petr Vosáhlo, Ivana Císařová and Petr Štěpnička

Dalton Trans., 2020, 49, 1011
DOI: 10.1039/C9DT04521J

Recent progress in the homogeneous gold-catalysed cycloisomerisation reactions

Mahender Kumar, Kajal Kaliya and Sushil K. Maurya

Org. Biomol. Chem., 2023, 21, 3276
DOI: 10.1039/D2OB02015G

Monoaurated vs. diaurated intermediates: causality or independence?

Mariarosa Anania, Lucie Jašíková, Jan Zelenka, Elena Shcherbachenko, Juraj Jašík and Jana Roithová

Chem. Sci., 2020, 11, 980
DOI: 10.1039/C9SC05662A

Dinuclear gold(i) complexes: from bonding to applications

Tahani A. C. A. Bayrakdar, Thomas Scattolin, Xinyuan Ma and Steven P. Nolan

Chem. Soc. Rev., 2020, 49, 7044
DOI: 10.1039/D0CS00438C

Iridium(I) Hydroxides: Powerful Synthons for Bond Activation

Byron J. Truscott, David J. Nelson, Cristina Lujan, Alexandra M. Z. Slawin and Steven P. Nolan

Chemistry A European J, 2013, 19, 7904
DOI: 10.1002/chem.201300669

[{Au(NHC)}2(μ-OH)][BF4]: Silver-Free and Acid-Free Catalysts for Water-Inclusive Gold-Mediated Organic Transformations

Adrián Gómez-Suárez, Yoshihiro Oonishi, Sebastien Meiries and Steven P. Nolan

Organometallics, 2013, 32, 1106
DOI: 10.1021/om301249r

Quantum chemical insight into C–H⋯F bonding interactions between noncovalently bonded ion-pairs in N-heterocyclic carbene complexes of gold(I) [(NHC*)2Au]+[PF6]−and gold(III) [(NHC*)2AuCl2]+[PF6]−

Krishna K. Pandey, Ravi Vishwakarma and Pankaj K. Bariya

Journal of Organometallic Chemistry, 2015, 795, 34
DOI: 10.1016/j.jorganchem.2014.11.028

Gold and Palladium Hetero-Bis-NHC Complexes: Characterizations, Correlations, and Ligand Redistributions

Shuai Guo, Haresh Sivaram, Dan Yuan and Han Vinh Huynh

Organometallics, 2013, 32, 3685
DOI: 10.1021/om400313r

Synthesis and characterisation of Au(I)-(ITent) complexes

Scott R. Patrick, Alba Collado, Sebastien Meiries, Alexandra M.Z. Slawin and Steven P. Nolan

Journal of Organometallic Chemistry, 2015, 775, 152
DOI: 10.1016/j.jorganchem.2014.04.022

Stereoselective Gold(I)-Catalyzed Intermolecular Hydroalkoxlation of Alkynes

Richard M. P. Veenboer, Stéphanie Dupuy and Steven P. Nolan

ACS Catal., 2015, 5, 1330
DOI: 10.1021/cs501976s

Gold(I)‐N‐Heterocyclic Carbene Synthons in Organometallic Synthesis

Thomas Scattolin, Giovanni Tonon, Eleonora Botter, Sebastien G. Guillet, Nikolaos V. Tzouras and Steven P. Nolan

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301961

Heteroleptic Silver(I) and Gold(I) N-Heterocyclic Carbene Complexes: Structural Characterization, Computational Analysis, Tyrosinase Inhibitory, and Biological Effects

Abdollah Neshat, Atiyeh Mahdavi, Mohammad Reza Yousefshahi, Mahdi Cheraghi, Vaclav Eigner, Monika Kucerakova, Michal Dusek, Forough Rezaie and Babak Kaboudin

Inorg. Chem., 2023, 62, 16710
DOI: 10.1021/acs.inorgchem.3c01759

The Importance of Hydrogen Bonding to Stereoselectivity and Catalyst Turnover in Gold-Catalyzed Cyclization of Monoallylic Diols

Thomas Ghebreghiorgis, Berenger Biannic, Brian H. Kirk, Daniel H. Ess and Aaron Aponick

J. Am. Chem. Soc., 2012, 134, 16307
DOI: 10.1021/ja306333a

Valence Tautomerism Induced Proton Coupled Electron Transfer:X−H Bond Oxidation with a Dinuclear Au(II) Hydroxide Complex

Kristopher M. Hess, Isaac F. Leach, Lisa Wijtenhorst, Hangyul Lee and Johannes E. M. N. Klein

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202318916

Hydroxide complexes of the late transition metals: Organometallic chemistry and catalysis

David J. Nelson and Steven P. Nolan

Coordination Chemistry Reviews, 2017, 353, 278
DOI: 10.1016/j.ccr.2017.10.012

Optimization of Catalysts and Conditions in Gold(I) Catalysis—Counterion and Additive Effects

Zhichao Lu, Tingting Li, Sagar R. Mudshinge, Bo Xu and Gerald B. Hammond

Chem. Rev., 2021, 121, 8452
DOI: 10.1021/acs.chemrev.0c00713

Efficient Generation and Increased Reactivity in Cationic Gold via Brønsted Acid or Lewis Acid Assisted Activation of an Imidogold Precatalyst

Junbin Han, Naoto Shimizu, Zhichao Lu, Hideki Amii, Gerald B. Hammond and Bo Xu

Org. Lett., 2014, 16, 3500
DOI: 10.1021/ol501443m

Synthesis of N-Heterocyclic Carbene Gold Complexes Using Solution-Phase and Solid-State Protocols

Jonathan D. Egbert, Alexandra M. Z. Slawin and Steven P. Nolan

Organometallics, 2013, 32, 2271
DOI: 10.1021/om301187a

New [Au(NHC)(OH)] Complexes for Silver-Free Protocols

Scott R. Patrick, Adrián Gómez-Suárez, Alexandra M. Z. Slawin and Steven P. Nolan

Organometallics, 2014, 33, 421
DOI: 10.1021/om4010065

Synthesis, Characterization, and Catalytic Activity of Cationic NHC Gold(III) Pyridine Complexes

Serena Orbisaglia, Béatrice Jacques, Pierre Braunstein, Damien Hueber, Patrick Pale, Aurélien Blanc and Pierre de Frémont

Organometallics, 2013, 32, 4153
DOI: 10.1021/om400338k

Hydrophenoxylation of Alkynes by Cooperative Gold Catalysis

Yoshihiro Oonishi, Adrián Gómez‐Suárez, Anthony R. Martin and Steven P. Nolan

Angewandte Chemie, 2013, 125, 9949
DOI: 10.1002/ange.201304182

Synthesis of a Sterically Encumbered Pincer Au(III)−OH Complex

Silène Engbers, Evgeniya A. Trifonova, Kristopher M. Hess, Folkert de Vries and Johannes E. M. N. Klein

Eur J Inorg Chem, 2021, 2021, 3561
DOI: 10.1002/ejic.202100305

NHC–Gold(I) Complexes as Effective Catalysts for the Carboxylative Cyclization of Propargylamines with Carbon Dioxide

Shun Hase, Yoshihito Kayaki and Takao Ikariya

Organometallics, 2013, 32, 5285
DOI: 10.1021/om400949m

Correlation of Experimental and Calculated Reaction Enthalpies with Ligand Donor Strengths

Julian Löffler, Sofie M. P. Vanden Broeck, Catherine S. J. Cazin, Steven P. Nolan and Viktoria H. Gessner

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202300151

Recent Advances in N-Heterocyclic Carbene Coinage Metal Complexes in A3-Coupling and Carboxylation Reaction

Assunta D’Amato, Marco Sirignano, Simona Russo, Rubina Troiano, Annaluisa Mariconda and Pasquale Longo

Catalysts, 2023, 13, 811
DOI: 10.3390/catal13050811

Mechanistic Aspects of the Carboxylative Cyclization of Propargylamines and Carbon Dioxide Catalyzed by Gold(I) Complexes Bearing anN-Heterocyclic Carbene Ligand

Shun Hase, Yoshihito Kayaki and Takao Ikariya

ACS Catal., 2015, 5, 5135
DOI: 10.1021/acscatal.5b01335

Expedient Syntheses of Neutral and Cationic Au(I)–NHC Complexes

Richard M. P. Veenboer, Danila Gasperini, Fady Nahra, David B. Cordes, Alexandra M. Z. Slawin, Catherine S. J. Cazin and Steven P. Nolan

Organometallics, 2017, 36, 3645
DOI: 10.1021/acs.organomet.7b00622

Cyclization of Gold Acetylides: Synthesis of Vinyl Sulfonates via Gold Vinylidene Complexes

Janina Bucher, Thomas Wurm, Kumara Swamy Nalivela, Matthias Rudolph, Frank Rominger and A. Stephen K. Hashmi

Angew Chem Int Ed, 2014, 53, 3854
DOI: 10.1002/anie.201310280

Hydration reactions catalyzed by transition metal–NHC (NHC = N-heterocyclic carbene) complexes

Pengcheng Gao and Michal Szostak

Coordination Chemistry Reviews, 2023, 485, 215110
DOI: 10.1016/j.ccr.2023.215110

Understanding the Surprising Oxidation Chemistry of Au−OH Complexes

Silène Engbers and Johannes E. M. N. Klein

ChemPhysChem, 2023, 24
DOI: 10.1002/cphc.202200475

Hydrophenoxylation of Alkynes by Cooperative Gold Catalysis

Yoshihiro Oonishi, Adrián Gómez‐Suárez, Anthony R. Martin and Steven P. Nolan

Angew Chem Int Ed, 2013, 52, 9767
DOI: 10.1002/anie.201304182

PMO‐Immobilized AuI–NHC Complexes: Heterogeneous Catalysts for Sustainable Processes

Els De Canck, Fady Nahra, Kevin Bevernaege, Sofie Vanden Broeck, Judith Ouwehand, Diederick Maes, Steven P. Nolan and Pascal Van Der Voort

ChemPhysChem, 2018, 19, 430
DOI: 10.1002/cphc.201701102

Cyclisierung von Goldacetyliden: Synthese von Vinylsulfonaten über Vinylidengold‐Komplexe

Janina Bucher, Thomas Wurm, Kumara Swamy Nalivela, Matthias Rudolph, Frank Rominger and A. Stephen K. Hashmi

Angewandte Chemie, 2014, 126, 3934
DOI: 10.1002/ange.201310280

Hydrohydrazination of Arylalkynes Catalyzed by an Expanded Ring N‐Heterocyclic Carbene (er‐NHC) Gold Complex Under Solvent‐Free Conditions

Oleg S. Morozov, Pavel S. Gribanov, Andrey F. Asachenko, Pavel V. Dorovatovskii, Victor N. Khrustalev, Viktor B. Rybakov and Mikhail S. Nechaev

Adv Synth Catal, 2016, 358, 1463
DOI: 10.1002/adsc.201500658

Counterion Effects in Homogeneous Gold Catalysis

Minqiang Jia and Marco Bandini

ACS Catal., 2015, 5, 1638
DOI: 10.1021/cs501902v

Synthesis of Alkenylgold(I) Complexes Relevant to Catalytic Carboxylative Cyclization of Unsaturated Amines and Alcohols

Shun Hase, Kyohei Yamashita and Yoshihito Kayaki

Molecules, 2024, 29, 1331
DOI: 10.3390/molecules29061331

Synthesis, characterization and luminescence studies of gold(I)–NHC amide complexes

Adrián Gómez-Suárez, David J Nelson, David G Thompson, David B Cordes, Duncan Graham, Alexandra M Z Slawin and Steven P Nolan

Beilstein J. Org. Chem., 2013, 9, 2216
DOI: 10.3762/bjoc.9.260

A novel route for large-scale synthesis of [Au(NHC)(OH)] complexes

Fady Nahra, Scott R. Patrick, Alba Collado and Steven P. Nolan

Polyhedron, 2014, 84, 59
DOI: 10.1016/j.poly.2014.06.017

Valence Tautomerism Induced Proton Coupled Electron Transfer:X−H Bond Oxidation with a Dinuclear Au(II) Hydroxide Complex

Kristopher M. Hess, Isaac F. Leach, Lisa Wijtenhorst, Hangyul Lee and Johannes E. M. N. Klein

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202318916

Synthesis, X-ray structure, DFT calculations and anticancer activity of a selenourea coordinated gold(I)-carbene complex

Adam A.A. Seliman, Muhammad Altaf, Nurudeen A. Odewunmi, Abdel-Nasser Kawde, Wiktor Zierkiewicz, Saeed Ahmad, Saleh Altuwaijri and Anvarhusein A. Isab

Polyhedron, 2017, 137, 197
DOI: 10.1016/j.poly.2017.08.003

Reduction of Ketones with Silanes Catalysed by a Cyclopentadienyl-Functionalised N-Heterocyclic Iron Complex

Rita Lopes, João M. S. Cardoso, Lorena Postigo and Beatriz Royo

Catal Lett, 2013, 143, 1061
DOI: 10.1007/s10562-013-1081-8

N-Heterocyclic Carbene Gold Complexes in a Photocatalytic CO2 Reduction Reaction

Dinesh Nugegoda, Nikolaos V. Tzouras, Steven P. Nolan and Jared H. Delcamp

Inorg. Chem., 2022, 61, 18802
DOI: 10.1021/acs.inorgchem.2c03487

Reactivity of Gold Hydrides: O2 Insertion into the Au–H Bond

Dragoş-Adrian Roşca, Julio Fernandez-Cestau, David L. Hughes and Manfred Bochmann

Organometallics, 2015, 34, 2098
DOI: 10.1021/om501165z

Dual Gold Catalysis: σ,π‐Propyne Acetylide and Hydroxyl‐Bridged Digold Complexes as Easy‐To‐Prepare and Easy‐To‐Handle Precatalysts

A. Stephen K. Hashmi, Tobias Lauterbach, Pascal Nösel, Mie Højer Vilhelmsen, Matthias Rudolph and Frank Rominger

Chemistry A European J, 2013, 19, 1058
DOI: 10.1002/chem.201203010