Optimizing CO2 electroreduction: theoretical insights for enhancing efficiency across elementary steps

Hengan Wang, Xinchen Kang and Buxing Han

Chem. Soc. Rev., 2025, 54, 10156
DOI: 10.1039/D5CS00780A

In situ probing the dynamic reconstruction of copper–zinc electrocatalysts for CO2 reduction

Yen-Po Huang, Ching-Wei Tung, Tai-Lung Chen, Chia-Shuo Hsu, Mei-Yi Liao, Hsiao-Chien Chen and Hao Ming Chen

Nanoscale, 2022, 14, 8944
DOI: 10.1039/D2NR01478E

Sonoelectrosynthesis of monodisperse metal nanoparticles

Kelly K. Rudman, Seyyedamirhossein Hosseini, Kaustav Chatterjee, Benjamin Johnson and Sara E. Skrabalak

Nanoscale, 2022, 14, 6471
DOI: 10.1039/D2NR00167E

Cation- and CO2-assisted electrochemical synthesis of clean, shape-controlled Cu nanocrystals for selective CO2 reduction to C2+ products

Wei-Ting Tu, Tsung-Han Tsai, Ding-Huei Tsai, Yi-Ting Xie, Hsuan-Yu Liu, Ming-Kang Tsai, Tsu-Chin Chou and Yung-Tin (Frank) Pan

J. Mater. Chem. A, 2025, 13, 34827
DOI: 10.1039/D5TA05614D

Nanoengineering of metal-based electrocatalysts for carbon dioxide (CO2) reduction: A critical review

Sina Pourebrahimi, Majid Pirooz, Shabnam Ahmadi, Mohammad Kazemeini and Leila Vafajoo

Materials Today Physics, 2023, 38, 101250
DOI: 10.1016/j.mtphys.2023.101250

Reaction Environment Regulation for Electrocatalytic CO2 Reduction in Acids

Min Zeng, Wensheng Fang, Yiren Cen, Xinyi Zhang, Yongming Hu and Bao Yu Xia

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202404574

Nanostructure engineering of Cu electrocatalyst for the selective C2+ hydrocarbons in electrochemical CO2 reduction

Rohini Subhash Kanase, Kelvin Berm Lee, Maheswari Arunachalam, Ramesh Poonchi Sivasankaran, Jihun Oh and Soon Hyung Kang

Applied Surface Science, 2022, 584, 152518
DOI: 10.1016/j.apsusc.2022.152518

Alkylamine‐Functionalized Carbon Supports to Enhance the Silver Nanoparticles Electrocatalytic Reduction of CO2 to CO

Francesco Mattarozzi, Karen van den Akker, Matt L. J. Peerlings, Maaike E. T. Vink‐van Ittersum, Nienke L. Visser, Rim C. J. van de Poll, Emiel J. M. Hensen, Peter Ngene and Petra E. de Jongh

ChemElectroChem, 2023, 10
DOI: 10.1002/celc.202300295

Electrosynthesized CuMgAl Layered Double Hydroxides as New Catalysts for the Electrochemical Reduction of CO2

Martina Serafini, Federica Mariani, Andrea Fasolini, Eleonora Tosi Brandi, Erika Scavetta, Francesco Basile and Domenica Tonelli

Adv Funct Materials, 2023, 33
DOI: 10.1002/adfm.202300345

Exploring C1-C3 variations and Fischer–Tropsch chemistry via electrochemical CO2 reduction on electrodeposited Cu/Ag and Ag/Cu electrodes

Seon Young Hwang, Gaeun Yun, So Young Kim, Yunji Gwon, Sooyeon Bae, Choong Kyun Rhee and Youngku Sohn

Electrochimica Acta, 2024, 507, 145100
DOI: 10.1016/j.electacta.2024.145100

Pd-Decorated Cu2O–Ag Catalyst Promoting CO2 Electroreduction to C2H4 by Optimizing CO Intermediate Adsorption and Hydrogenation

Xianbin Xu, Difei Xiao, Yugang Gao, Wenbo Li, Miaomiao Gao, Shuang Zhao, Zeyan Wang, Zhaoke Zheng, Peng Wang, Hefeng Cheng, Yuanyuan Liu, Ying Dai and Baibiao Huang

ACS Appl. Mater. Interfaces, 2024, 16, 16243
DOI: 10.1021/acsami.4c00472

Porous Zn Conformal Coating on Dendritic‐Like Ag with Enhanced Selectivity and Stability for CO2 Electroreduction to CO

Yajiao Zhou, Ganghai Ni, Kuangzhe Wu, Qin Chen, Xiqing Wang, Weiwei Zhu, Zhen He, Hongmei Li, Junwei Fu and Min Liu

Advanced Sustainable Systems, 2023, 7
DOI: 10.1002/adsu.202200374

Unraveling the synergistic effects of Cu-Ag tandem catalysts during electrochemical CO2 reduction using nanofocused X-ray probes

Marvin L. Frisch, Longfei Wu, Clément Atlan, Zhe Ren, Madeleine Han, Rémi Tucoulou, Liang Liang, Jiasheng Lu, An Guo, Hong Nhan Nong, Aleks Arinchtein, Michael Sprung, Julie Villanova, Marie-Ingrid Richard and Peter Strasser

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-43693-2

Recent progress in CO2 reduction using bimetallic electrodes containing copper

Hannah L.A. Dickinson and Mark D. Symes

Electrochemistry Communications, 2022, 135, 107212
DOI: 10.1016/j.elecom.2022.107212

Tuning the CO2 Reduction Selectivity of an Immobilized Molecular Ag Complex beyond CO

Mani Balamurugan, Jun Ho Jang, Jeong Eun Kim, Won Il Choi, Young In Jo, Sunghak Park, Elumalai Varathan and Ki Tae Nam

Inorg. Chem., 2024, 63, 7992
DOI: 10.1021/acs.inorgchem.4c01140

Dynamic Evolution of Active Sites in Electrocatalytic CO2 Reduction Reaction: Fundamental Understanding and Recent Progress

Wenchuan Lai, Zesong Ma, Jiawei Zhang, Yuliang Yuan, Yan Qiao and Hongwen Huang

Adv Funct Materials, 2022, 32
DOI: 10.1002/adfm.202111193

Tandem catalytic CO2 electroreduction via in situ restructured silver nanoparticles on copper spheres

Yue Li, Jingjing Wu, Hongyu Pan, Jing Ling, Qian Zhang, BiYun Min, YiFan Wang and Xianglong Lu

Materials Letters, 2025, 397, 138847
DOI: 10.1016/j.matlet.2025.138847

Recent advances in application of tandem catalyst for electrocatalytic CO2 reduction

Jiamin Ma, Chunmei Liu, Meng Bai, Zimei Fu, Peipei Zhao, Yang Gao, Man Zhao, Yingluo He, He Xiao and Jianfeng Jia

Molecular Catalysis, 2023, 551, 113632
DOI: 10.1016/j.mcat.2023.113632

Halide-guided active site exposure in bismuth electrocatalysts for selective CO2 conversion into formic acid

Shuang Yang, Hongyu An, Sven Arnouts, Hui Wang, Xiang Yu, Jim de Ruiter, Sara Bals, Thomas Altantzis, Bert M. Weckhuysen and Ward van der Stam

Nat Catal, 2023, 6, 796
DOI: 10.1038/s41929-023-01008-0

Reaction Environment Regulation for Electrocatalytic CO2 Reduction in Acids

Min Zeng, Wensheng Fang, Yiren Cen, Xinyi Zhang, Yongming Hu and Bao Yu Xia

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202404574

Carbon dioxide and "methanol" economy: advances in the catalytic synthesis of methanol from CO₂

A. L. Maximov and I. P. Beletskaya

RUSS CHEM REV, 2024, 93, RCR5101
DOI: 10.59761/RCR5101

Review on Long-Term Stability of Electrochemical CO2 Reduction

Juan Miguel Álvarez-Gómez and Ana Sofia Varela

Energy Fuels, 2023, 37, 15283
DOI: 10.1021/acs.energyfuels.3c01847

Enhancing the Mechanical Performance of Fiber‐Reinforced Polymer Composites Using Carbon Nanotubes as an Effective Nano‐Phase Reinforcement

Zihong Wu, Yan Zhao, Kang Yang, Juan Guan, Shaokai Wang, Yizhuo Gu, Min Li, Yiyu Feng, Wei Feng and Robert O. Ritchie

Adv Materials Inter, 2023, 10
DOI: 10.1002/admi.202201935

Sub‐Second Time‐Resolved Surface‐Enhanced Raman Spectroscopy Reveals Dynamic CO Intermediates during Electrochemical CO2 Reduction on Copper

Hongyu An, Longfei Wu, Laurens D. B. Mandemaker, Shuang Yang, Jim de Ruiter, Jochem H. J. Wijten, Joris C. L. Janssens, Thomas Hartman, Ward van der Stam and Bert M. Weckhuysen

Angew Chem Int Ed, 2021, 60, 16576
DOI: 10.1002/anie.202104114

Effect of size distribution, skewness and roughness on the optical properties of colloidal plasmonic nanoparticles

Rituraj Borah and Sammy W. Verbruggen

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 640, 128521
DOI: 10.1016/j.colsurfa.2022.128521

The Necessity for Multiscale In Situ Characterization of Tailored Electrocatalyst Nanoparticle Stability

Ward van der Stam

Chem. Mater., 2023, 35, 386
DOI: 10.1021/acs.chemmater.2c03286

Systematic Nonenzymatic Glucose Detection Using Hydrogel-Protected Ag–Cu/MWCNTs Nanocomposites

Jian-Kai Huang, Sin-Yu Chen and Meng-Chang Lin

ACS Omega, 2025, 10, 48844
DOI: 10.1021/acsomega.5c06932

Recent advancements in carbon/metal-based nano-catalysts for the reduction of CO2 to value-added products

Arun Kumar Senthilkumar, Mohanraj Kumar, Melvin S. Samuel, Selvarajan Ethiraj, Mohd Shkir and Jih-Hsing Chang

Chemosphere, 2024, 364, 143017
DOI: 10.1016/j.chemosphere.2024.143017

Tandem strategy for electrochemical CO2 reduction reaction

Bing Zhang, Linlin Wang, Di Li, Zongmiao Li, Ran Bu and Yingying Lu

Chem Catalysis, 2022, 2, 3395
DOI: 10.1016/j.checat.2022.10.017

Insights into the dynamic evolution of catalytic active centers of the electrocatalytic carbon dioxide reduction reaction

Bashir Adegbemiga Yusuf, Waleed Yaseen, Suci Meng, Jimin Xie, Funmilayo O. Fapohunda, Rosalynn Nankya, Atika Ibrahim Muhammad, Meng Xie and Yuanguo Xu

Coordination Chemistry Reviews, 2023, 492, 215273
DOI: 10.1016/j.ccr.2023.215273

A colloidal approach for the synthesis of catalytically active solid–liquid–solid nanoparticles

Coline Boulanger, Daniel Arenas Esteban, Krishna Kumar, Jari Leemans, Petru P. Albertini, Haoxuan You, Eachann Assendjee, Dragos C. Stoian, Sara Bals and Raffaella Buonsanti

Nat. Synth, 2025, 4, 1513
DOI: 10.1038/s44160-025-00871-y

Near-Unity Electrochemical CO2 to CO Conversion over Sn-Doped Copper Oxide Nanoparticles

Shuang Yang, Zhaochun Liu, Hongyu An, Sven Arnouts, Jim de Ruiter, Floriane Rollier, Sara Bals, Thomas Altantzis, Marta C. Figueiredo, Ivo A.W. Filot, Emiel J.M. Hensen, Bert M. Weckhuysen and Ward van der Stam

ACS Catal., 2022, 12, 15146
DOI: 10.1021/acscatal.2c04279

On the stability of electrochemical CO2 reduction reaction to formate at indium electrodes at biocompatible conditions

Paniz Izadi, Aykut Kas, Philip Haus and Falk Harnisch

Electrochimica Acta, 2023, 462, 142733
DOI: 10.1016/j.electacta.2023.142733

Sub‐Second Time‐Resolved Surface‐Enhanced Raman Spectroscopy Reveals Dynamic CO Intermediates during Electrochemical CO2 Reduction on Copper

Hongyu An, Longfei Wu, Laurens D. B. Mandemaker, Shuang Yang, Jim de Ruiter, Jochem H. J. Wijten, Joris C. L. Janssens, Thomas Hartman, Ward van der Stam and Bert M. Weckhuysen

Angewandte Chemie, 2021, 133, 16712
DOI: 10.1002/ange.202104114

Exploring the effect of temperature on the stability and scalability of CO2 electrolysis systems with copper electrodes

Kevin Fernández-Caso, Jurriaan Peeters and Ruud Kortlever

Current Opinion in Chemical Engineering, 2026, 51, 101231
DOI: 10.1016/j.coche.2026.101231

Electrochemical CO2/CO reduction on Ag/Cu electrodes and exploring minor Fischer–Tropsch reaction pathways

Gaeun Yun, Seon Young Hwang, Ju Young Maeng, Young Jun Kim, Choong Kyun Rhee and Youngku Sohn

Applied Surface Science, 2024, 649, 159179
DOI: 10.1016/j.apsusc.2023.159179

Electrochemistry-Induced Restructuring of Tin-Doped Indium Oxide Nanocrystal Films of Relevance to CO2 Reduction

Tawney A. Knecht, Shannon W. Boettcher and James E. Hutchison

J. Electrochem. Soc., 2021, 168, 126521
DOI: 10.1149/1945-7111/ac40ca

Tuning charge transfer and ion diffusion in 3D nanotubular arrays by engineering vacancy and implanting sodiophilic seeds for dendrite-free sodium metal anodes

Yulei Li, Xiaofei Zhang, Tongzhen Wang, Jie Yang, Jiewu Cui, Jian Yan, Jiaqin Liu, Hark Hoe Tan, Yan Yu and Yucheng Wu

Journal of Power Sources, 2024, 602, 234349
DOI: 10.1016/j.jpowsour.2024.234349

Recent Advances in Bimetallic Cu‐Based Nanocrystals for Electrocatalytic CO2 Conversion

Biva Talukdar, Shruti Mendiratta, Michael H. Huang and Chun‐Hong Kuo

Chemistry An Asian Journal, 2021, 16, 2168
DOI: 10.1002/asia.202100583

Understanding the Electrocatalytic Interface: A Review of Advances in CO2ER Mechanisms and Materials

Zirwa Noor, Erum Pervaiz, Waheed Miran, Ronny Mönnig, Kevin M. Van Geem and Mohamed A. Shenashen

Energy Fuels, 2026, 40, 987
DOI: 10.1021/acs.energyfuels.5c03429

Perspectives on Cu–Ag Bimetallic Catalysts for Electrochemical CO2 Reduction Reaction: A Mini-Review

Peiqi Guo, Kaili Liu, Xu Liu, Ruhan Liu and Zongyou Yin

Energy Fuels, 2024, 38, 5659
DOI: 10.1021/acs.energyfuels.3c05194

Electrochemical Fingerprints of Nanostructured Cu and Ag Electrodes

Andrea Conte, Sara Bonacchi and Sabrina Antonello

ACS Electrochem., 2025, 1, 1903
DOI: 10.1021/acselectrochem.5c00172