The molecular and electronic structure of edge-sharing bioctahedral [N(n-Bu)4]3[Re2(mnt)5] is reported here. Despite the short intermetal bond length of 2.6654(2) Å with computed bond order of 1.2, the unpaired electron is localised by the asymmetric ligand distribution, as demonstrated by its remarkable EPR spectrum.
Y. Yan, J. T. Mague, J. P. Donahue and S. Sproules, Chem. Commun., 2015, 51, 5482 DOI: 10.1039/C4CC09397F
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