Recent progress in conversion reaction metal oxide anodes for Li-ion batteries

Abstract

Transition metal oxides (TMOs) based on conversion reactions are attractive candidate anode materials for lithium-ion batteries (LIBs) because of their high theoretical capacity and safety characteristics. In this review, we have summarized recent progress in the rational design and efficient synthesis of TMOs with controllable morphologies, compositions, and micro-/nanostructures, along with their Li storage behaviors. Single metal oxides of manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), ruthenium (Ru), chromium (Cr), molybdenum (Mo), and tungsten (W) and their common binary metal oxides have been discussed in this review. Finally, the less well-known merits of conversion reactions are put forward, and the design of metal oxide electrodes making full use of these merits has been proposed.