Issue 4, 2016

Cycloaddition of carbonyl compounds and alkynes to (di)silenes and (di)germenes: reactivity and mechanism

Abstract

The chemistry of silenes, germenes, disilenes and digermenes has been extensively studied over the last 35 years; however, not much is known about the mechanisms of many of the fundamental reactions of this class of compounds, including cycloadditions. This review describes the current understanding of the reaction pathways for the cycloaddition of carbonyl compounds and alkynes to (di)tetrelenes. The question of whether or not the cycloaddition reactions of (di)tetrelenes follow the Woodward–Hoffman rules, established for alkenes and alkynes, is addressed.

Graphical abstract: Cycloaddition of carbonyl compounds and alkynes to (di)silenes and (di)germenes: reactivity and mechanism

Article information

Article type
Review Article
Submitted
01 Лип 2015
First published
03 Вер 2015

Chem. Soc. Rev., 2016,45, 1019-1035

Author version available

Cycloaddition of carbonyl compounds and alkynes to (di)silenes and (di)germenes: reactivity and mechanism

K. K. Milnes, L. C. Pavelka and K. M. Baines, Chem. Soc. Rev., 2016, 45, 1019 DOI: 10.1039/C5CS00522A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements