A C–C bond migration event during the cycloisomerization of 1,6-enynes is described. Two different catalytic systems, iridium- or platinum-based, are able to induce this process. Alkyl migrations of larger rings and acyclic groups indicate that the reaction is not fully driven by the release of ring strain.
S. M. Stevenson, E. T. Newcomb and E. M. Ferreira, Chem. Commun., 2014, 50, 5239 DOI: 10.1039/C3CC47499B
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