Issue 12, 2002
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Direct NH-aziridination of α,β-unsaturated ketones

Jiaxi Xu*a  and  Peng Jiaoa  

* Corresponding authors

a Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Abstract

1-Aryl-α,β-unsaturated ketones were directly aziridinated, N-unsubstituted, in a one-pot reaction with satisfactory yields by N,N′-diamino-1,4-diazoniabicyclo[2.2.2]octane dinitrate, a nitrogen–nitrogen ylide precursor, in the presence of sodium hydride.

Graphical abstract: Direct NH-aziridination of α,β-unsaturated ketones

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Article information

DOI
https://doi.org/10.1039/B200046F
Article type
Paper
Submitted
08 Jan 2002
Accepted
12 Apr 2002
First published
07 May 2002

J. Chem. Soc., Perkin Trans. 1, 2002, 1491-1493

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Direct NH-aziridination of α,β-unsaturated ketones

J. Xu and P. Jiao, J. Chem. Soc., Perkin Trans. 1, 2002, 1491 DOI: 10.1039/B200046F

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