The photoreduction of Zn(II) to Zn metal catalyzed by 8-hydroxyquinoline derivatives is reported. Structure–activity relationships, ideal reaction conditions, and the reaction kinetics are described and a mechanism involving an in situ formed quinolate complex is portrayed.
A. C. Brooks, K. Basore and S. Bernhard, Chem. Commun., 2014, 50, 5196 DOI: 10.1039/C3CC47633B
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