Themed collection Nanoscale 10th Anniversary: Top Cited Articles
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Defective TiO2 with oxygen vacancies: synthesis, properties and photocatalytic applications
The summary and perspective on synthesis, properties and photocatalytic applications of defective TiO2 with oxygen vacancies have been outlined in this review.
Nanoscale, 2013,5, 3601-3614
https://doi.org/10.1039/C3NR00476G
Fluorescent silver nanoclusters
Silver nanoclusters are a class of fluorophores with attractive features, including brightness, photostability and subnanometer size. Here we overview the different stabilizers and we discuss the recent advances.
Nanoscale, 2011,3, 1963-1970
https://doi.org/10.1039/C1NR00006C
Nanostructured carbon–metal oxide composite electrodes for supercapacitors: a review
This paper presents a comprehensive review of the research progress in the carbon–metal oxide composites for supercapacitor electrodes.
Nanoscale, 2013,5, 72-88
https://doi.org/10.1039/C2NR32040A
Three-dimensional graphene architectures
Learn more about the methodology for preparing three-dimensional graphene micro-/nanoarchitectures and their potential applications.
Nanoscale, 2012,4, 5549-5563
https://doi.org/10.1039/C2NR31467C
Nanostructured metal oxide -based materials as advanced anodes for lithium-ion batteries
The beneficial effects of proper nanostructuring and advanced compositing on lithium storage properties of three types of metal oxide anodes have been reviewed.
Nanoscale, 2012,4, 2526-2542
https://doi.org/10.1039/C2NR11966H
Microwave chemistry for inorganic nanomaterials synthesis
Microwave irradiation as heating tool offers unique opportunities for the synthesis of inorganic nanomaterials. We outline the general principles, advantages, limitations and applications of this approach.
Nanoscale, 2010,2, 1358-1374
https://doi.org/10.1039/B9NR00377K
Upscaling of polymer solar cell fabrication using full roll-to-roll processing
Upscaling of the manufacture of polymer solar cells is detailed with emphasis on cost analysis and practical approach.
Nanoscale, 2010,2, 873-886
https://doi.org/10.1039/B9NR00430K
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Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems
We present the science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems, targeting an evolution in technology, that might lead to impacts and benefits reaching into most areas of society.
Nanoscale, 2015,7, 4598-4810
https://doi.org/10.1039/C4NR01600A
Graphitic carbon nitride based nanocomposites: a review
This review summarizes recent advances in the design, synthesis, mechanistic understanding and multifunctional applications of g-C3N4 based heterojunctions/heterostructures.
Nanoscale, 2015,7, 15-37
https://doi.org/10.1039/C4NR03008G
Nanoparticles for photothermal therapies
The state of the art regarding the use of nanoparticles for photothermal therapies is reviewed in detail.
Nanoscale, 2014,6, 9494-9530
https://doi.org/10.1039/C4NR00708E
Engineering BiOX (X = Cl, Br, I) nanostructures for highly efficient photocatalytic applications
In this review, an overview of nanostructure engineering in BiOX (X = Cl, Br, I) semiconductors to achieve their highly efficient photocatalytic applications is surveyed.
Nanoscale, 2014,6, 2009-2026
https://doi.org/10.1039/C3NR05529A
Focusing on luminescent graphene quantum dots : current status and future perspectives
Recent progress on graphene quantum dots is presented, mainly focusing on the top-down synthetic routes, optical properties and applications.
Nanoscale, 2013,5, 4015-4039
https://doi.org/10.1039/C3NR33849E
A review of fabrication and applications of carbon nanotube film-based flexible electronics
This article comprehensively reviews the recent progress and outlook of carbon nanotube film-based flexible electronics.
Nanoscale, 2013,5, 1727-1752
https://doi.org/10.1039/C3NR33560G
Recent progress on graphene -based photocatalysts: current status and future perspectives
The current status of applications of graphene-based photocatalysts for conversion of solar to chemical energy has been updated; in particular, future perspectives including opportunities and challenges on this topic are proposed in this review.
Nanoscale, 2012,4, 5792-5813
https://doi.org/10.1039/C2NR31480K
Thermometry at the nanoscale
Non-invasive precise thermometers working at the nanoscale with high spatial resolution, where the conventional methods are ineffective, have emerged over the last couple of years as a very active field of research.
Nanoscale, 2012,4, 4799-4829
https://doi.org/10.1039/C2NR30663H
Luminescence nanothermometry
The different approaches for luminescence based temperature sensing at the nanoscale are described, analyzed and compared.
Nanoscale, 2012,4, 4301-4326
https://doi.org/10.1039/C2NR30764B
The role of nanomaterials in redox-based supercapacitors for next generation energy storage devices
This review describes recent advances and prospective applications of nanostructured electrode materials for redox-based supercapacitors.
Nanoscale, 2011,3, 839-855
https://doi.org/10.1039/C0NR00594K
TEMPO-oxidized cellulose nanofibers
TEMPO-oxidized cellulose nanofibers (TOCN) have uniform and ultrafine widths, high crystallinity and high aspect ratios, with surface carboxylate groups in high density. The TOCN films have extremely low oxygen permeability.
Nanoscale, 2011,3, 71-85
https://doi.org/10.1039/C0NR00583E
2D materials: to graphene and beyond
This review attempts to illustrate the different alternatives in the field of 2D materials (single-layers) from graphene to alternative inorganic materials such as metal chalcogenides, oxides, hydroxides, and metal–organic frameworks.
Nanoscale, 2011,3, 20-30
https://doi.org/10.1039/C0NR00323A
Quantum sized, thiolate -protected gold nanoclusters
This review will focus on a special type of ultra-small (<2 nm) yet robust gold nanoparticles that are protected by thiolates, so-called gold thiolate nanoclusters.
Nanoscale, 2010,2, 343-362
https://doi.org/10.1039/B9NR00160C
An 80.11% FF record achieved for perovskite solar cells by using the NH4Cl additive
CH3NH3PbI3/PC61BM solar cells fabricated using the NH4Cl additive gave a decent PCE of 9.93% and a very outstanding FF of 80.11%.
Nanoscale, 2014,6, 9935-9938
https://doi.org/10.1039/C4NR02425G
Highly conductive NiCo2S4 urchin-like nanostructures for high-rate pseudocapacitors
A 3D highly conductive urchin-like NiCo2S4 nanostructure that exhibits excellent high-rate supercapacitive performance has been synthesized.
Nanoscale, 2013,5, 8879-8883
https://doi.org/10.1039/C3NR02958A
Facile synthesis of low crystalline MoS2 nanosheet -coated CNTs for enhanced hydrogen evolution reaction
A networked MoS2/CNT nanocomposite has been synthesized by a facile solvothermal method. The as-prepared sample exhibits high catalytic activity for electrocatalytic hydrogen evolution.
Nanoscale, 2013,5, 7768-7771
https://doi.org/10.1039/C3NR02994H
All-solid-state hybrid solar cells based on a new organometal halide perovskite sensitizer and one-dimensional TiO2 nanowire arrays
A novel organometal halide perovskite (CH3NH3PbI2Br) is synthesized as a light absorber to sensitize one-dimensional (1D) TiO2 nanowire arrays (NWAs) for all-solid-state hybrid solar cells with enhanced photovoltaic properties.
Nanoscale, 2013,5, 3245-3248
https://doi.org/10.1039/C3NR00218G
Biocompatible polydopamine fluorescent organic nanoparticles : facile preparation and cell imaging
The preparation of water soluble and biocompatible fluorescent organic nanoparticles via the one-pot oxidation of polydopamine for cell imaging is presented.
Nanoscale, 2012,4, 5581-5584
https://doi.org/10.1039/C2NR31281F
One-pot green synthesis of optically pH-sensitive carbon dots with upconversion luminescence
Optically pH-sensitive carbon dots was facilely developed by directly heating ascorbic acid aqueous solution at 90 °C.
Nanoscale, 2012,4, 5572-5575
https://doi.org/10.1039/C2NR31319G
Porous graphitic carbon nitride synthesized via direct polymerization of urea for efficient sunlight-driven photocatalytic hydrogen production
Porous graphitic carbon nitride synthesized with urea in a less-energy cost process leads to a greatly enhanced photocatalytic hydrogen production rate.
Nanoscale, 2012,4, 5300-5303
https://doi.org/10.1039/C2NR30948C
Facile synthesis of hierarchical MoS2 microspheres composed of few-layered nanosheets and their lithium storage properties
Hierarchical MoS2 microspheres composed of few-layered nanosheets show enhanced lithium storage properties.
Nanoscale, 2012,4, 95-98
https://doi.org/10.1039/C1NR11552A
6.5% efficient perovskite quantum-dot-sensitized solar cell
Highly efficient perovskite quantum-dot-sensitized solar cell.
Nanoscale, 2011,3, 4088-4093
https://doi.org/10.1039/C1NR10867K
Differential nano-bio interactions and toxicity effects of pristine versus functionalized graphene
Hydrophobic pristine graphene shows significantly different cell–material interactions and nanotoxicity compared to carboxyl functionalized hydrophilic graphene.
Nanoscale, 2011,3, 2461-2464
https://doi.org/10.1039/C1NR10172B
Absolute quantum yield measurements of colloidal NaYF4: Er3+ , Yb3+ upconverting nanoparticles
A straightforward method is presented to measure absolute quantum yields of upconverting nanoparticles based on an integrating sphere and a standard fluorimeter.
Nanoscale, 2010,2, 1417-1419
https://doi.org/10.1039/C0NR00253D
Cobalt nanoparticles embedded in N-doped carbon as an efficient bifunctional electrocatalyst for oxygen reduction and evolution reactions
A hybrid composite of Co NPs embedded in N-doped carbon was prepared. With the synergistic interactions, the hybrid catalyst exhibits efficient bifunctional catalytic activity and stability toward both ORR and OER.
Nanoscale, 2014,6, 15080-15089
https://doi.org/10.1039/C4NR04357J
Edge-enriched graphene quantum dots for enhanced photo-luminescence and supercapacitance
Graphene quantum dots synthesized from activated graphene using ultrasonication and chemical activation shows high edge-enriched states resulting in excellent luminescence and capacitance properties.
Nanoscale, 2014,6, 11988-11994
https://doi.org/10.1039/C4NR02365J
Hierarchical porous carbon aerogel derived from bagasse for high performance supercapacitor electrode
A facile method to prepare hierarchical porous carbon (HPC) aerogels using bagasse is proposed. The HPC aerogels exhibited high supercapacitive performance with excellent capacitance retention of about 93.9% over 5000 cycles.
Nanoscale, 2014,6, 12120-12129
https://doi.org/10.1039/C4NR03574G
Highly graphitized nitrogen-doped porous carbon nanopolyhedra derived from ZIF-8 nanocrystals as efficient electrocatalysts for oxygen reduction reactions
Nitrogen-doped graphitic porous carbon nanopolyhedra synthesized by direct carbonization of ZIF-8 nanocrystals exhibited highly efficient oxygen reduction in alkaline media.
Nanoscale, 2014,6, 6590-6602
https://doi.org/10.1039/C4NR00348A
Cost-effective and eco-friendly synthesis of novel and stable N-doped ZnO/g-C3N4 core–shell nanoplates with excellent visible-light responsive photocatalysis
Novel and stable N-doped ZnO/g-C3N4 core–shell nanoplates with enhanced photocatalysis via direct Z-scheme mechanism were prepared by a facile self-assembly process.
Nanoscale, 2014,6, 4830-4842
https://doi.org/10.1039/C3NR05271K
Synthesis and microwave absorption enhancement of graphene@Fe3O4@SiO2@NiO nanosheet hierarchical structures
Hierarchical structures of graphene@Fe3O4@SiO2@NiO nanosheets were prepared by combining the versatile sol–gel process with a hydrothermal reaction.
Nanoscale, 2014,6, 3157-3164
https://doi.org/10.1039/C3NR05313J
Wearable multifunctional sensors using printed stretchable conductors made of silver nanowires
We present multifunctional sensors for strain, pressure and touch detection, which exhibit a fast response, good wearability and pressure mapping function.
Nanoscale, 2014,6, 2345-2352
https://doi.org/10.1039/C3NR05496A
Nitrogen-doped, carbon-rich, highly photoluminescent carbon dots from ammonium citrate
N-doped carbon dots were synthesized using ammonium citrate as a solo precursor under hydrothermal conditions.
Nanoscale, 2014,6, 1890-1895
https://doi.org/10.1039/C3NR05380F
Nitrogen doped porous carbon fibres as anode materials for sodium ion batteries with excellent rate performance
Nitrogen-doped activated porous carbon fibres (ACFs) were prepared as anode materials for Na-ion batteries. They exhibit excellent electrochemical performance, especially rate performance. The influence of nitrogen functionalities on charge transfer and electrochemical performance of N-doped carbon anode for Na ion batteries is discussed.
Nanoscale, 2014,6, 1384-1389
https://doi.org/10.1039/C3NR05374A
Highly luminescent S, N co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalysts
A facile hydrothermal synthesis route to N and S, N co-doped graphene quantum dots (GQDs) was developed by using citric acid as the C source and urea or thiourea as N and S sources.
Nanoscale, 2013,5, 12272-12277
https://doi.org/10.1039/C3NR04402E
Lattice dynamics in mono- and few-layer sheets of WS2 and WSe2
Characteristic A1g and E2g1 phonon modes for WS2 and WSe2 show distinct thickness dependence, which allows rapid identification of layer thickness.
Nanoscale, 2013,5, 9677-9683
https://doi.org/10.1039/C3NR03052K
Oxygen vacancy induced band gap narrowing of ZnO nanostructures by an electrochemically active biofilm
An electrochemically active biofilm was utilized to narrow the band gap of ZnO nanostructures.
Nanoscale, 2013,5, 9238-9246
https://doi.org/10.1039/C3NR02678G
Nanostructured graphene /Fe3O4 incorporated polyaniline as a high performance shield against electromagnetic pollution
Graphene/Fe3O4 incorporated polyaniline has been synthesized for EMI shielding which contributes to high microwave absorption value of 26 dB.
Nanoscale, 2013,5, 2411-2420
https://doi.org/10.1039/C3NR33962A
A facile route to synthesize multiporous MnCo2O4 and CoMn2O4 spinel quasi-hollow spheres with improved lithium storage properties
Multiporous MnCo2O4 and CoMn2O4 quasi-hollow microspheres are fabricated in a facile way and display excellent cycling stability and good rate capability, indicating their potential application in lithium ion batteries.
Nanoscale, 2013,5, 2045-2054
https://doi.org/10.1039/C2NR33576J
Novel hollow Pt-ZnO nanocomposite microspheres with hierarchical structure and enhanced photocatalytic activity and stability
The remarkable photocatalytic performance of hollow and hierarchical Pt-ZnO nanocomposite microspheres originated from their unique nanostructures and low recombination rate of the e−/h+ pairs.
Nanoscale, 2013,5, 2142-2151
https://doi.org/10.1039/C2NR33595F
Dopamine as the coating agent and carbon precursor for the fabrication of N-doped carbon coated Fe3O4 composites as superior lithium ion anodes
Dopamine has been used as coating agent and carbon precursor to prepare N-doped and thickness controlled carbon coated Fe3O4 composites.
Nanoscale, 2013,5, 1168-1175
https://doi.org/10.1039/C2NR33043A
Comparison of electrochemical performances of olivine NaFePO4 in sodium-ion batteries and olivine LiFePO4 in lithium-ion batteries
Electrochemical performances of an olivine NaFePO4 cathode in sodium-ion batteries are compared with an identical LiFePO4 cathode in lithium-ion batteries.
Nanoscale, 2013,5, 780-787
https://doi.org/10.1039/C2NR32758A
Enhancing electrochemical reaction sites in nickel–cobalt layered double hydroxides on zinc tin oxide nanowires: a hybrid material for an asymmetric supercapacitor device
An asymmetric supercapacitor is fabricated based on a NixCo1−x LDHs–Zn2SnO4 nanowires hybrid material with an enhanced faradic reaction area.
Nanoscale, 2012,4, 7266-7272
https://doi.org/10.1039/C2NR31590D
Wafer-scale MoS2 thin layers prepared by MoO3 sulfurization
Wafer-scale MoS2 thin layers can be obtained by a two-step thermal process.
Nanoscale, 2012,4, 6637-6641
https://doi.org/10.1039/C2NR31833D
Very long Ag nanowire synthesis and its application in a highly transparent, conductive and flexible metal electrode touch panel
A highly transparent and flexible conductor from very long silver nanowire percolation network electrodes was developed for touch panel demonstration.
Nanoscale, 2012,4, 6408-6414
https://doi.org/10.1039/C2NR31254A
Graphene oxide–Fe3O4 magnetic nanocomposites with peroxidase-like activity for colorimetric detection of glucose
Graphene oxide–Fe3O4 magnetic nanocomposites demonstrate intrinsic peroxidase-like activity and enhanced affinity toward H2O2. They were employed as novel peroxidase mimetics to catalyze oxidation of the peroxidase substrate 3,3,5,5-tetramethylbenzidine (TMB) in the presence of H2O2. Kinetic analysis indicated that the catalysis is in accord with typical Michaelis–Menten kinetics, following a ping-pong mechanism.
Nanoscale, 2012,4, 3969-3976
https://doi.org/10.1039/C2NR12109C
The effect of nanowire length and diameter on the properties of transparent, conducting nanowire films
Experimental measurements of films composed of nanowires with well-defined lengths and widths were combined with 3D finite-difference time-domain calculations to determine the structure-property relationships of transparent, conducting nanowire networks.
Nanoscale, 2012,4, 1996-2004
https://doi.org/10.1039/C2NR30126A
Preparation and visible light photocatalytic activity of Ag/TiO2/graphene nanocomposite
The combination of surface plasmon resonance effect of Ag nanoparticles and excellent electrical properties of graphene can significantly improve the photocatalytic activity of TiO2 under visible light irradiation.
Nanoscale, 2011,3, 4411-4417
https://doi.org/10.1039/C1NR10604J
Enhanced photocatalytic H2-production activity of graphene -modified titania nanosheets
Graphene-modified TiO2 nanosheet composites with 0.2–2.0 wt% graphene, prepared by a microwave-hydrothermal method, exhibit an enhanced photocatalytic H2-production activity.
Nanoscale, 2011,3, 3670-3678
https://doi.org/10.1039/C1NR10610D
In situ assembly of well-dispersed Ag nanoparticles (AgNPs) on electrospun carbon nanofibers (CNFs) for catalytic reduction of 4-nitrophenol
We synthesized carbon nanofibers/silver nanoparticles (CNFs/AgNPs) composite nanofibers which exhibited high catalytic activity in the reduction of 4-nitrophenol.
Nanoscale, 2011,3, 3357-3363
https://doi.org/10.1039/C1NR10405E
In situ
self-assembly of mild chemical reduction graphene for three-dimensional architectures
Graphene hydrogels and aerogels have been prepared by the self-assembly of reduced graphene oxide under mild reduction conditions.
Nanoscale, 2011,3, 3132-3137
https://doi.org/10.1039/C1NR10355E
NiO
nanosheets grown on graphene nanosheets as superior anode materials for Li-ion batteries
NiO nanosheets were grown on graphene nanosheets and showed highly reversible capacities and good rate capability for Li-ion batteries.
Nanoscale, 2011,3, 2615-2620
https://doi.org/10.1039/C1NR10070J
Curcumin -loaded biodegradable polymeric micelles for colon cancer therapy in vitro and in vivo
Encapsulation of curcumin in MPEG-PCL micelles renders curcumin intravenously injectable, enhancing pharmacokinetics, antiangiogenesis and anticancer activity of curcumin in vivo.
Nanoscale, 2011,3, 1558-1567
https://doi.org/10.1039/C0NR00758G
Graphene based gene transfection
Graphene is for the first time used as a non-toxic nano-vector for effective gene transfection.
Nanoscale, 2011,3, 1252-1257
https://doi.org/10.1039/C0NR00680G
Facile synthesis of metal oxide /reduced graphene oxide hybrids with high lithium storage capacity and stable cyclability
A one-step solvothermal route was developed to prepare metal oxide/reduced graphene oxide (rGO) nanohybrids with promising Li storage properties.
Nanoscale, 2011,3, 1084-1089
https://doi.org/10.1039/C0NR00744G
The kinetics and mechanisms of amorphous calcium carbonate (ACC) crystallization to calcite , viavaterite.
A summary of the processes and solid phases involved in the two-stage crystallization pathway of calcite from Amorphous Calcium Carbonate (ACC).
Nanoscale, 2011,3, 265-271
https://doi.org/10.1039/C0NR00589D
Size-dependent properties of magnetic iron oxide nanocrystals
The size-dependent magnetic properties of Fe3−xO4 nanocrystals synthesized by thermal decomposition were established by taking into account surface effect, nanocrystals compositions and dipolar interactions.
Nanoscale, 2011,3, 225-232
https://doi.org/10.1039/C0NR00521E
Nanocomposites of size-controlled gold nanoparticles and graphene oxide: Formation and applications in SERS and catalysis
Formation of Au nanoparticle-graphene oxide and -reduced graphene oxide composites by simple physisorption is described. These nanocomposites exhibit significantly higher SERS and catalytic activities than the corresponding Au nanoparticles.
Nanoscale, 2010,2, 2733-2738
https://doi.org/10.1039/C0NR00473A
Anatase TiO2 nanosheets with exposed (001) facets: improved photoelectric conversion efficiency in dye -sensitized solar cells
Dye-sensitized solar cells are fabricated based on anatase TiO2 nanosheets with exposed {001} facets, exhibiting higher photoelectric conversion efficiencies than TiO2 nanoparticles and Degussa P25 solar cells.
Nanoscale, 2010,2, 2144-2149
https://doi.org/10.1039/C0NR00427H
A nanostructured graphene /polyaniline hybrid material for supercapacitors
In this paper, a novel method for the preparation of a nanostructured polyaniline/graphene hybrid material was developed. In addition to its thin, uniformity and flexible merits, it also shows excellent electrochemical performances than pristine individuals for supercapacitors.
Nanoscale, 2010,2, 2164-2170
https://doi.org/10.1039/C0NR00224K
Ultrasmall near-infrared gold nanoclusters for tumor fluorescence imaging in vivo
Ultrasmall NIR gold nanoclusters with bright NIR fluorescence, high photostability and biocompatibility appear as very promising contrast imaging agents for in vivo fluorescence tumor imaging.
Nanoscale, 2010,2, 2244-2249
https://doi.org/10.1039/C0NR00359J
Nanoelectronic biosensors based on CVD grown graphene
We demonstrate the use of large-sized CVD grown graphene films configured as field-effect transistors for real-time biomolecular sensing.
Nanoscale, 2010,2, 1485-1488
https://doi.org/10.1039/C0NR00142B
Preparation of graphene by a low-temperature thermal reduction at atmosphere pressure
Graphene oxide in a mixture of DMAc and water can be easily reduced to graphene by simply heating it.
Nanoscale, 2010,2, 559-563
https://doi.org/10.1039/B9NR00191C
Nanostructured Pt decorated graphene and multi walled carbon nanotube based room temperature hydrogen gas sensor
Herein, we report the fabrication of hydrogen gas sensors based on noble nanometal decorated one dimensional multi walled carbon nanotubes and two dimensional graphene by a simple drop casting technique.
Nanoscale, 2009,1, 382-386
https://doi.org/10.1039/B9NR00015A
About this collection
As part of the celebrations for Nanoscale’s 10th Anniversary in 2019, we wanted to celebrate some of the most exceptional research that you, our authors, have published in the journal over the last 10 years.
This online article collection features the top 20 most highly cited review articles, and the top 50 most highly cited research articles published in Nanoscale since the launch of the journal in 2009.
All articles in the collection are free to read until the end of 2019. Access them via your free Royal Society of Chemistry publishing personal account