Issue 3, 2014

Making syngas electrocatalytically using a polypyridyl ruthenium catalyst

Abstract

Electrocatalytic reduction of carbon dioxide to carbon monoxide and of water/weak acids to hydrogen by a class of polypyridyl ruthenium complexes both occur by well-defined mechanisms involving common intermediates. Based on available mechanistic insight, conditions have been found for competitive electrocatalytic reduction of CO2–H2O–H2PO4 mixtures by a single metal complex catalyst to give syngas products with the H2 : CO ratio controllable by controlling the composition of the solutions.

Graphical abstract: Making syngas electrocatalytically using a polypyridyl ruthenium catalyst

Supplementary files

Article information

Article type
Communication
Submitted
23 Вер 2013
Accepted
06 Лис 2013
First published
07 Лис 2013

Chem. Commun., 2014,50, 335-337

Making syngas electrocatalytically using a polypyridyl ruthenium catalyst

Z. Chen, P. Kang, M. Zhang and T. J. Meyer, Chem. Commun., 2014, 50, 335 DOI: 10.1039/C3CC47251E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements