Issue 18, 2011

New insights into the aggregation of silver pyrazolides using sterically hindered bidentate pyrazole ligands

Abstract

Recrystallisation of Ag[L1] (HL1 = 3{5}-[pyrid-2-yl]-5{3}-tert-butylpyrazole) in the presence of halide anions leads to two polymorphs of [Ag3(μ-Br)(μ-L1)2], which differ in their mode of supramolecular association, and the cluster [Ag10(μ-L1)8]Cl2. In contrast, Ag[L2] (HL2 = 3{5}-[isoquinol-1-yl]-5{3}-tert-butyl-pyrazole) crystallises as a cyclic tetrameric molecule.

Graphical abstract: New insights into the aggregation of silver pyrazolides using sterically hindered bidentate pyrazole ligands

Supplementary files

Article information

Article type
Communication
Submitted
04 Січ 2011
Accepted
15 Бер 2011
First published
30 Бер 2011

Chem. Commun., 2011,47, 5187-5189

New insights into the aggregation of silver pyrazolides using sterically hindered bidentate pyrazole ligands

J. J. Henkelis, C. A. Kilner and M. A. Halcrow, Chem. Commun., 2011, 47, 5187 DOI: 10.1039/C1CC00054C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements