Issue 25, 2015

Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

Abstract

The synthesis and structural characterization is reported for [Fe(dien)2][FeSe2]2 and [Fe(tren)][FeSe2]2, two new mixed-valence compounds that contain infinite 1(FeSe2) tetrahedral chains separated by Fe–amine complexes. The inter- and intra-chain magnetic interactions can be controlled by changing the denticity of the amine while preserving the general structural motif.

Graphical abstract: Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

Supplementary files

Article information

Article type
Communication
Submitted
30 Жов 2014
Accepted
30 Лис 2014
First published
01 Гру 2014

Chem. Commun., 2015,51, 5355-5358

Author version available

Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe–amine complexes

J. T. Greenfield, C. Pak, S. Kamali, K. Lee and K. Kovnir, Chem. Commun., 2015, 51, 5355 DOI: 10.1039/C4CC08608B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements