Issue 32, 2009

Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

Abstract

Rhodium-catalyzed asymmetric arylation of imines using electronically and sterically-modified chiral diene ligands gave the corresponding diarylmethylamines in high yield and with high enantioselectivity using just 0.3 mol% of catalyst.

Graphical abstract: Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

Supplementary files

Article information

Article type
Communication
Submitted
06 Бер 2009
Accepted
24 Кві 2009
First published
19 Тра 2009

Chem. Commun., 2009, 4815-4817

Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

K. Okamoto, T. Hayashi and V. H. Rawal, Chem. Commun., 2009, 4815 DOI: 10.1039/B904624K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements