Wenbo
Huang‡
abc,
Juanwen
Chen‡
abc,
Qingshan
Ma
abcd,
Linxiao
Xing
e,
Guiling
Wang
*e,
Jiwen
Cen
abc,
Zhibin
Li
abcf,
Ang
Li
abcd and
Fangming
Jiang
*abcd
aLaboratory of Advanced Energy Systems, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences (CAS), Guangzhou 510640, China. E-mail: jiangfm@ms.giec.ac.cn
bCAS Key Laboratory of Renewable Energy, Guangzhou 510640, China
cGuangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
dSchool of Energy Science and Engineering, University of Science and Technology of China, Hefei 230026, China
eInstitute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Sciences, Shijiazhuang 050061, China. E-mail: wangguiling@mail.cgs.gov.cn
fUniversity of Chinese Academy of Sciences, Beijing 100049, China
First published on 14th May 2024
At medium-deep and deep parts of the Earth's crust lay vast and so far mostly untapped reserves of geothermal energy. This energy source has the potential to meet humanity's needs for energy for thousands of years. However, the large-scale deployment has been hindered by a lack of effective and dependable exploitation technologies. Gravity heat pipes have recently garnered significant attention due to their exceptional heat transfer capability and their ability to harness geothermal heat without water-mining. Nevertheless, it is a persistent challenge to extend gravity heat pipes to depths that are sufficient to exploit deep geothermal energy. In this study, we introduce an innovative ladder-structure inner pipe design to overcome this shortcoming. This design incorporates a series of stepped ladders and small condensate guiding pipes, allowing for the development of super-long gravity heat pipes (SLGHPs). Combined with an optimal working fluid, this novel structure enables kilometers-long gravity heat pipes. As a direct outcome of this innovation, a 4149-meter-long SLGHP was constructed and installed in a geothermal well using ammonia as the working fluid. The SLGHP geothermal system demonstrated the ability of continuous heat output exceeding 1 MW, with a heat flux across the radial section of the SLGHP reaching 4 × 107 W m−2. Furthermore, an ammonia vapor-driven power generator was developed and integrated with the SLGHP system. During a 72-hour test, this generator successfully produced electricity at a steady rate of approximately 7 kW. The breakthrough design of the SLGHPs holds the potential to unlock Earth's deep geothermal energy reserves, providing a sustainable and reliable energy source for generations to come.
Broader contextThe super-long gravity heat pipe (SLGHP) is a novel and promising technological advancement to exploit medium-deep to deep geothermal energy. We present an innovative design that enables the successful development of a kilometers-long gravity heat pipe to access earth-deep geothermal energy. The SLGHP geothermal system built here is in Xiong’an, China; this heat pipe is the longest in the world with a length of 4149 m. The SLGHP uses ammonia as the working fluid, and the integrated power generator is driven by ammonia vapor generated by the SLGHP. The SLGHP geothermal system can continuously produce more than 1 MW of heat, and the heat flux across the radial cross-section of the heat pipe amounts to 4 × 107 W m−2, surpassing the heat dissipation flux of modern electronic components, which attests to the exceptional heat transfer capability of the developed SLGHP. The world's first SLGHP pilot power generator steadily generated electricity at ∼7 kW rate in a 72 h test. The SLGHP system is expected to be widely deployed for geothermal energy exploitation (power generation and space heating) and for other industrial utilizations, such as underground coal fire control and heavy oil mining. |
Heat pipes are known for their exceptional heat transfer capabilities,21–23 and thus, they have been successfully applied in almost all thermal engineering domains, such as solar collectors,24,25 electronics cooling,26 energy recovery systems,22 as well as geothermal energy exploitation.27,28 They have emerged as a potential solution for deep geothermal energy extraction. The super-long gravity-assisted heat pipe (SLGHP) is an innovative variant of heat pipes to extract geothermal energy from significant depths,29 and it relies on gravity to return the condensed working fluid, eliminating the need for a wick30,31 (Fig. S2, ESI†). Geothermal systems with the SLGHP are straightforward and do not require pumping mechanisms, making them an attractive alternative to multi-well extraction and reinjection systems, such as the EGS. Moreover, the enclosed and isolated working fluid within the heat pipe minimizes technical challenges associated with traditional methods. In its operation, the working fluid absorbs heat in the evaporation section, vaporizes and rises towards the condensation section, where it condenses and releases heat. The condensate returns to the evaporation section under the action of gravity, sustaining a continuous cycle. As the working fluid primarily absorbs heat in the form of latent heat, the fluid temperature within the heat pipe remains almost unchanged. This feature allows for maximized temperature differences between the heat pipe and surrounding geothermal formation, leading to optimized heat harvesting. Moreover, the SLGHP system minimizes the potential risks of scale/corrosion and loss of the working fluid, resulting in reduced maintenance demands and a diminished environmental footprint. SLGHP systems offer the unique advantage of direct steam production, which can be harnessed for heat pump space heating or steam turbine power generation, eliminating the requirement of supplementary equipment, such as a steam separator or flash evaporator.32–34 This enhances the SLGHP efficiency and system performance as compared to conventional geothermal systems.33
Despite its wide-spectrum applications, heat pipe technology has almost been stagnant in the last two decades.35 In particular, there have been no innovative breakthroughs in the development of sufficiently long gravity heat pipes that could meet requirements for earth-deep geothermal (e.g. HDR) heat extraction; the length of heat pipes rarely surpasses the 100-meter level.36 Gravity heat pipes exceeding this length have been primarily confined to experimental stages and have not demonstrated the consistent performance required for widespread industrial and field use.32,37,38 The effectiveness of heat pipes depends on efficient evaporation and condensation in the evaporator and condenser, as well as minimal resistance to vapor flow. The extra-long configuration of the SLGHP, probably spanning a few kilometers, introduces critical limitations.39 Issues, such as undesirable in-pipe flow patterns and substantial pressure drop, arise.40 Long-distance vapor/liquid countercurrent flow can cause interphase entrainment and enhanced vapor drag, resulting in ill performance and even failure of the system. The accumulation of liquid, extending to a deep liquid pool, creates obstacles, such as high static hydraulic pressure that inhibits evaporation, leading to startup failures or reduced performance.40 Moreover, the pressure drop in the flow of the rising vapor due to frictional and gravitational resistances is negligible in typical “short” heat pipes, but it is notably large and exerts a detrimental impact on the operation of the SLGHPs with lengths of several kilometers.41 Addressing these challenges necessitates the development of a tailored configuration, which distinctly departs from conventional heat pipe designs, to control in-pipe flow patterns, along with a systematic selection of the working fluid.42
Herein, we present an innovative structural design, which enables the effective performance of kilometers-long SLGHPs. This novel design (Fig. 1) incorporates a set of in-pipe functional modules that couple the stepped reflux configuration with liquid–vapor separation design to achieve highly efficient evaporation and prevent the entrainment of long-distance liquid/vapor counter-flow. A 4149-m-long heat pipe was developed in-house; this is the longest ever reported pipe, which was installed in a geothermal well in Xiong’an New Area, Hebei Province, China. The SLGHP was charged with ammonia as the working fluid; an ammonia vapor-driven power generator was developed and assembled with the SLGHP system. In operation, the SLGHP geothermal system can continuously produce more than 1 MW of heat, and the heat flux through the radial cross-section of the heat pipe amounts to 4 × 107 W m−2, surpassing the typical heat dissipation fluxes of modern electronic components.43 The world's first SLGHP pilot power plant steadily generated electricity at ∼7 kW rate in a 72-hour test. As global energy demands continue to rise, the development of advanced technologies, such as the SLGHPs, will be essential in harnessing the full potential of geothermal energy. By providing a sustainable and efficient means of geothermal energy extraction, the SLGHPs can play a pivotal role in meeting the world's energy needs while mitigating environmental impacts.
Once filled with an appropriate amount of working fluid, the liquid primarily resides within stepped annular containers, with minimal accumulation at the bottom of the SLGHP. During operation, the working fluid evaporates and enters the central passage, where the vapor flows upwards, and the liquid condensate is directed downwards within the annular space. Liquid accumulation is maintained at an optimal level in the annular containers to ensure complete wetting of the SLGHP evaporation section. Liquid accumulation in the annular containers is not very high, but it is sufficient to keep all SLGHP evaporation sections fully wetted. This novel structure effectively helps address common issues encountered in extra-long gravity heat pipes, such as vapor/liquid entrainment and boiling suppression caused by stagnant liquid pools. The innovative design facilitates highly efficient evaporation and boiling of the working fluid while segregating the flow of liquid and vapor components; this mitigates the long-range vapor/liquid countercurrent interference. One remaining challenge that may affect SLGHP performance is the resistance imposed on the vapor flow. Long-distance vapor flow can suffer from substantial resistance due to gravity and viscous forces. To counteract the effects of large vapor flow resistance, it is essential to select an optimal working fluid for the SLGHP.
Previous research40 proposed that a temperature gradient of the working fluid should be applied along the SLGHP axis (dT/dy) and should be used as a selection criterion. Smaller dT/dy values indicate a better working fluid. It was found that dT/dy remains relatively insensitive to changes in heat pipe diameter and geothermal source temperature, when ammonia is used as the working fluid. However, dT/dy increases significantly for small pipe diameters and low source temperatures with water. Further studies44 have revealed the unique phenomenological mechanisms of the SLGHPs by comparing them with normal-sized gravity heat pipes (NSGHPs). Operational characteristics were analysed in these studies by taking into consideration their distinctive geometric features. While thermal resistance caused by vapor flow is negligible in the NSGHPs, it dominates the overall thermal resistance of the SLGHPs. Both studies40,44 concluded that an ideal SLGHP working fluid should possess following properties: (i) high latent heat of vaporization and (ii) a strong dependence of saturated vapor pressure on temperature. A comprehensive analysis has indicated that ammonia is an optimal working fluid for most geothermal applications (Fig. S3, ESI†).
The D34 well was drilled by the China geological survey; its borehole featured three distinct sections with progressively smaller diameters as it reached downward; each section was reinforced with a casing. The first section is at a depth from 0 to 1012 meters with a casing diameter of 339.7 mm; the second extends from a depth of 1012 to 3433 meters with a casing diameter of 244.5 mm; the third is between the depths of 3433 and 4507 meters with a casing diameter of 177.8 mm. An SLGHP developed in-house with a length of 4149 meters was installed inside the wellbore (Fig. 2b). The SLGHP also consists of three sections with different outside diameters: (1) from 0 to 752 meters in depth, the diameter is 244.5 mm; (2) from 752 to 3105 meters, the diameter is 177.8 mm; and (3) from 3105 to 4149 meters, the diameter is 127.0 mm. Each section of the SLGHP is slightly smaller in diameter than the corresponding borehole casing. To eliminate the thermal contact resistance between the SLGHP and geothermal formations, the annular space between the SLGHP and casing was filled with water. It should be mentioned the SLGHP is about 350 meters shorter than the well depth, which helps protect the SLGHP and wellbore from potential damage.
The pilot SLGHP geothermal system is schematically presented in Fig. 2(a). It was designed to serve two sets of tests: heat extraction test and power generation test. For the heat extraction test, valves 1 and 4 are turned on, while valves 2, 3, 5, and 6 are turned off. This arrangement allows the vapor of the working fluid to leave the SLGHP and flow directly into the condenser, releasing latent heat into cooling water. Subsequently, the condensed fluid, after returning to the SLGHP, flows into it by the force of gravity. The heated cooling water goes to the cooling tower and releases heat to the ambient atmosphere. For the power generation test, valves 2, 3, 5, and 6 are turned on, while valves 1 and 4 are turned off. In this setup, the vapor of the working fluid coming from the top of the SLGHP flows into a double-stage turbine and later into the condenser. The condenser is cooled by circulating water; as a result, the pressure of the working fluid in the condenser is significantly lower than the pressure of the vapor leaving the SLGHP and entering the condenser. This pressure difference causes the working fluid vapor to expand, while going through the turbine, which drives the generator to produce electricity. The condensed fluid in the condenser is collected in a tank, and subsequently, re-introduced into the SLGHP by a booster pump. For both tests, cooling water circulates first through the condenser and is then sent to the cooling tower to lower its temperature to the required level before entering the condenser. The performance of the cooling tower is adjusted by controlling the operation of two air fans positioned at its top. Adjusting the speed of these fans can create various cooling conditions for the tests.
Considering the geothermal conditions and size of the SLGHP, ammonia was selected as the working fluid for the heat pipe42 (Fig. S3, ESI†). Before charging with ammonia, the SLGHP was vacuumed to a vacuum level lower than 0.8 kPa. The SLGHP was charged (or discharged) many times with ammonia; each time, while charging or discharging, about 200–500 kg of ammonia was used, and the pressure in the SLGHP condenser was recorded 24 hours after each charge (or discharge). We checked the pressure in the SLGHP condenser to examine the response of the SLGHP to the charge (or discharge) with ammonia to verify proper operation.
Fig. 3a demonstrates the pressure in the SLGHP condenser as a function of the amount of ammonia in the SLGHP, and Fig. 3b schematically presents the calculated ammonia distribution in the SLGHP at different stages. Regardless of the amount of ammonia used for charge or discharge, qualitatively, the pressure in the condenser increases with increasing amounts of ammonia in the SLGHP, while the ammonia distribution shows three distinct stages: I. Vapor only; II. Partially wetted; and III. Fully wetted.
Fig. 3 Response of the SLGHP to charge and discharge with ammonia. (a) Pressure in the SLGHP condenser as a function of the ammonia quantity; (b) schematic distribution of ammonia in the SLGHP. |
In the vapor-only stage, all the ammonia in the SLGHP is in the vapor phase. Once charged ammonia, which turns into vapor immediately, is sufficient to fill all the space in the SLGHP, liquid ammonia starts to accumulate at the uppermost ladder module. In Fig. 3a, it can be noted the vapor-only stage ends at a condenser pressure of 1.2 MPa with charging using approximately 0.45 tons of ammonia. 1.2 MPa pressure corresponds to the saturation vapor pressure of ammonia at the geothermal formation's original temperature (31 °C) at the location of the upper first ladder. The increase in ammonia charged into the SLGHP leads to the filling of the upper ladder modules with liquid ammonia, while the pressure in the condenser increases. Inside the SLGHP, the temperature is almost uniform; the operation of the partially-wetted SLGHP flattens the geothermal formation temperature of the wet section. In Fig. 3a, it is worth noting that the partially-wetted stage occurs for an ammonia quantity of 4.68 tons, at which point liquid ammonia reaches the position of approximately 2000 m underground. By further increasing the amount of ammonia charged, the wet section progressively extends deeper. As the average formation temperature across the wet section increases, the temperature in the SLGHP, and the pressure in the condenser also increases. When all ladder modules in the SLGHP are filled with liquid ammonia, the temperature and pressure in the SLGHP reach the highest values; the highest recorded pressure in the condenser is 3.97 MPa with 7.70 tons of ammonia charged, as illustrated in Fig. 3a. The SLGHP system was charged with ammonia one more time, amounting to a total of 7.93 tons of ammonia. It is observed that the pressure decreases, which occurs because too much liquid ammonia accumulates and floods the SLGHP bottom section, hindering the evaporation of ammonia.45 The pressure for the ammonia discharge process (Fig. 3a) is always above that for the charging process, which is due to substantially more heat uptake from the deeper high-temperature geothermal formation during the discharge process. For 0.45 tons of ammonia, no liquid ammonia remains in the SLGHP, and the pressure for the charge and discharge process coincide.
The above-described charge/discharge tests corroborate that the SLGHP can properly work according to its design, and it is found that the SLGHP needs 7.70 tons of ammonia for its optimum filling.
Under test conditions I, II and III, 40-day average production temperatures are 36.8 °C, 52.8 °C, and 59.3 °C, respectively. The corresponding average heat extraction rates over the 40-day test are 1049 kW, 596 kW, and 442 kW, respectively. In terms of the diameter of the middle section of the heat pipe, 177.8 mm, considering the 1049 kW heat extraction rate, the heat flux through a radial cross-section of the SLGHP is more than 4 × 107 W m−2, attesting its exceptional heat transfer capability. The simulated heat extraction rates (at each production temperature, 40-day averaged), along with the data of the three tests are reported in Fig. 4b. The simulation model employed (Fig. S5, ESI†) is detailed in the ESI,† which has already been validated by practical field test data47 and was further validated by underground temperatures measured in the present work (extended data Fig. 3). Close observation of Fig. 4b has evidence that simulation results, and test data agree well with each other. The simulation model is based on the assumption that the SLGHP operates under ideal conditions, in particular, by assuming that liquid/vapor entrainment, stagnant liquid at the SLGHP bottom, and local dry-outs do not occur. Therefore, the good agreement between the test data and simulation results indicates the SLGHP design is very successful as it leads to a system performing close to an ideal system.
In addition to condenser temperatures, Fig. 4c reports SLGHP temperatures measured at three underground monitoring points, i.e., at 235 m, 470 m, and 940 m subsurface, respectively, under the conditions of test II. As the heat extraction process proceeds, the temperature of the SLGHP decreases as a result of the decrease in the temperature of the surrounding geothermal formation. The temperature of the upward flow in the SLGHP, from underground to surface, decreases but, generally, the decrease is relatively minor – about 5 °C for a distance of approximately 1000 m. Inside the SLGHP, the ammonia vapor and liquid are thermodynamically in a quasi-equilibrium state; therefore, the temperature and pressure are related to each other (Fig. S6, ESI†), i.e. the temperature decrease is essentially associated with the drop in vapor pressure. The measured drop in temperature indicates that the SLGHP is performing very well; furthermore, observations in Fig. 4a lead to the conclusion that control of the temperature in the condenser is an effective measure to adjust the heat extraction rate of the SLGHP. Extended data Fig. 4 reports the results under the test conditions of I and III.
After the heat extraction tests of the SLGHP system were completed, the geothermal formation was allowed to recover for 16 days. During this time, the power generation test was conducted for 72 hours in total. The primary aim of the test is to verify the feasibility of saturated vapor produced by the SLGHP system to drive the steam turbine of the power generation system, which operates as a Rankine cycle. The operation is started by keeping the cooling tower and water circulation loop in an idle state; valves 2, 3, 4, 5, and 6 are then turned on, while valve 1 is turned off. Therefore, pressures before and after the turbine are equal, both in equilibrium with the SLGHP output vapor. By turning off valve 4 and turning on the water pump to start the cooling tower and water circulation loop, the pressure in the condenser decreases, leading to the development of a pressure difference between the two ends of the turbine, which drives the turbine and coaxial electrical generator to produce electricity.
The performance of the SLGHP power generation system is reported in Fig. 5 of extended data; this shows the heat extraction rate, power generation rate, turbine inlet temperature, turbine outlet temperature and ambient temperature as a function of the operation time. In addition, it includes an exergy flow chart, which was calculated in terms of the average values obtained from the 72-hour experiment. A two-stage turbine designed in-house (Fig. 5e) was used for the test. The first and second stages of the turbine share a common shaft with an electrical generator, while they are set with a reverse exhaust direction to counterbalance the axial force. The designed turbine inlet temperature and outlet temperature are 50.6 °C and 37 °C, respectively. During the 72-hour test, the turbine inlet temperature was kept below the designed value, and the average value was only 46.53 °C (Fig. 5c). Nevertheless, it can be noted the power generation system steadily generates electricity at ∼7 kW rate during the test (Fig. 5b). The power generation trend indicates two relevant characteristics: the first is that the power generation increases with an increase in heat extraction rate, although the increase is not obvious due to reduced turbine efficiency (extended data Fig. 6b); the second is that power generation slowly decreases with the operation time, which is similar to the temporal behavior of the heat extraction rate.
Fig. 5 Power generation performance of the SLGHP system. (a) Heat extraction rate, (b) power generation, (c) temperatures, (d) exergy flow chart, and (e) turbine structure. |
The exergy flow chart in Fig. 5d indicates that the total exergy production from the underground geothermal formation was 108.48 kW in the 72-hour test (extended data Fig. 6a). This demonstrates the good potential of the SLGHP power generation system. The largest exergy destruction occurs during the condensation process, which accounts for 73.70% of the total exergy produced. This large exergy destruction is mainly caused by the cooling capacity of the cooling tower, which cannot further reduce the temperature difference between condensation and ambient temperatures. However, this large portion of energy loss can be recovered through cascade utilization systems with different types of output, such as space heating. Moreover, as the ammonia-driven turbine is operating at off-design conditions, its low efficiency (extended data Fig. 6b) is also an important reason causing the low exergy efficiency of the SLGHP power generation system (extended data Fig. 6c).
Using SLGHP facilitates heat transport from deep into the earth to the ground; the tests conducted to evaluate the SLGHP geothermal system have demonstrated the exceptional heat transfer capability of the SLGHP. However, the low thermal conductivity of the geothermal formation can limit the overall heat extraction performance of SLGHP geothermal systems.48 The augmentation of the SLGHP heat production is a challenge, which must be addressed. The creation of near-well artificial reservoirs, in combination with heat transfer enhancement, can offer a potential solution. Previous studies29,48 indicate that near-well heat transfer enhancement within a ∼10-meter radius around the SLGHP can effectively augment its performance.
The SLGHP geothermal systems have the unique advantage of direct vapor production, which can be used to drive heat pump systems for space heating or steam turbines for power generation, simplifying the surface-level systems for geothermal utilization. At the same time, it enhances the energy utilization efficiency. Testing of the SLGHP ammonia vapor-driven power generation system demonstrates the feasibility of this technological route; however, it should be accepted that there is still much research work to be done in the future, such as optimization and adaptation of the design of the surface equipment and steam turbine.
For large-scale commercial deployment, we may first consider the geothermal energy exploitation from numerous abandoned oil/gas wells to save the well-drilling cost, which can be the largest initial investment in the SLGHP geothermal systems.49,50 The SLGHP is essentially a highly efficient heat transport device, which can be also used in industrial scenarios, other than geothermal energy production, for instance, underground coal fire control51 and heavy oil mining.52,53
Footnotes |
† Electronic supplementary information (ESI) available. See DOI: https://doi.org/10.1039/d4ee01235f |
‡ These authors contributed equally to this work and should be considered as co-first authors. |
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