Issue 6, 2022

Cooperative approaches in catalytic hydrogenation and dehydrogenation

Abstract

Metal–ligand cooperativity (MLC) is an established strategy for developing effective hydrogenation and dehydrogenation catalysts. Metal–metal cooperativity (MMC) in bimetallic complexes is not as well understood, and to date has had limited implementation in (de)hydrogenation. Herein we use (de)hydrogenation processes as a platform to examine modes of cooperativity, with a particular focus on catalytic mechanisms. We investigate how lessons learnt from the extensive development of metal–ligand cooperative catalysts can aid the ongoing development of metal–metal cooperative catalysts.

Graphical abstract: Cooperative approaches in catalytic hydrogenation and dehydrogenation

Article information

Article type
Tutorial Review
Submitted
22 Гру 2021
First published
01 Бер 2022

Chem. Soc. Rev., 2022,51, 1881-1898

Cooperative approaches in catalytic hydrogenation and dehydrogenation

M. A. Stevens and A. L. Colebatch, Chem. Soc. Rev., 2022, 51, 1881 DOI: 10.1039/D1CS01171E

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