Detection of hydroxyl and hydride functional groups in a ceria crystal under hydrogen reduction

Takeshi Matsukawa; Kazuki Iida; Mitsutaka Nakamura; Toru Ishigaki

doi:10.1039/D1CE00130B

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Detection of hydroxyl and hydride functional groups in a ceria crystal under hydrogen reduction†

Takeshi Matsukawa,

*^a Kazuki Iida,

^b Mitsutaka Nakamura

^c and Toru Ishigaki^a

Author affiliations

* Corresponding authors

^a Frontier Research Center for Applied Atomic Sciences, Ibaraki University, 162-1 Shirakata, Tokai, Ibaraki 319-1106, Japan
E-mail: takeshi.matsukawa.ifrc@vc.ibaraki.ac.jp
Fax: +81 29 287 7872
Tel: +81 29 352 3234

^b Neutron Science and Technology Center, Comprehensive Research Organization for Science and Society, 162-1 Shirakata, Tokai, Ibaraki 319-1106, Japan

^c J-PARC Center, Japan Atomic Energy Agency (JAEA), Tokai, Ibaraki 319-1195, Japan

Abstract

Neutron powder diffraction analysis revealed that ceria transformed into the oxyhydroxide structure by hydrogen treatment. Due to detection of the vibrational modes of both OH and CeH functional groups by inelastic neutron scattering measurements, the CeH functional group was revealed to possibly exist in ceria as an aperiodic structure.

This article is part of the themed collection: Crystal Engineering Techniques

Download options Please wait...

Supplementary files

Supplementary information PDF (328K)

Article information

DOI: https://doi.org/10.1039/D1CE00130B
Article type: Communication
Submitted: 28 Січ 2021
Accepted: 13 Бер 2021
First published: 17 Бер 2021

Download Citation

CrystEngComm, 2021,23, 2355-2359

Permissions

Request permissions

Detection of hydroxyl and hydride functional groups in a ceria crystal under hydrogen reduction

T. Matsukawa, K. Iida, M. Nakamura and T. Ishigaki, CrystEngComm, 2021, 23, 2355 DOI: 10.1039/D1CE00130B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

CrystEngComm

Detection of hydroxyl and hydride functional groups in a ceria crystal under hydrogen reduction†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Detection of hydroxyl and hydride functional groups in a ceria crystal under hydrogen reduction

Social activity

Search articles by author

Spotlight

Advertisements