Issue 71, 2014

Massive conformational changes during thermally induced self-metalation of 2H-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin on Cu(111)

Abstract

Based on a combined scanning tunnelling microscopy and X-ray photoelectron spectroscopy study we present detailed insights into pronounced changes of long-range order and intramolecular conformation during the self-metalation of 2H-5,10,15,20-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin (2HTTBPP) to CuTTBPP on Cu(111). Upon metalation, the porphyrin literally “pops up” from the surface, due to a drastically reduced molecule–substrate interaction.

Graphical abstract: Massive conformational changes during thermally induced self-metalation of 2H-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin on Cu(111)

Supplementary files

Article information

Article type
Communication
Submitted
15 Тра 2014
Accepted
13 Лип 2014
First published
14 Лип 2014

Chem. Commun., 2014,50, 10225-10228

Author version available

Massive conformational changes during thermally induced self-metalation of 2H-tetrakis-(3,5-di-tert-butyl)-phenylporphyrin on Cu(111)

M. Stark, S. Ditze, M. Lepper, L. Zhang, H. Schlott, F. Buchner, M. Röckert, M. Chen, O. Lytken, H.-P. Steinrück and H. Marbach, Chem. Commun., 2014, 50, 10225 DOI: 10.1039/C4CC03708A

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