Activation of gaseous PH3 with low coordinate diaryltetrylene compounds

Jonathan W. Dube; Zachary D. Brown; Christine A. Caputo; Philip P. Power; Paul J. Ragogna

doi:10.1039/C3CC48933G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Activation of gaseous PH₃ with low coordinate diaryltetrylene compounds†

Jonathan W. Dube,^a Zachary D. Brown,^b Christine A. Caputo,^b Philip P. Power^b and Paul J. Ragogna*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Center for Advanced Materials and Biomaterials Research (CAMBR), The University of Western Ontario, 1151 Richmond St., London, Ontario, Canada
E-mail: pragogna@uwo.ca

^b Department of Chemistry, The University of California, 1 Shields Ave, Davis, California, USA

Abstract

The reaction of phosphine gas with a low coordinate diaryl germylene or diarylstannylene results in both oxidative addition and arene elimination at the group 14 atom. The products were characterised by ³¹P NMR spectroscopy and X-ray crystallography, and represent the first P–H bond activation by a heavy group 14 element compound.

This article is part of the themed collection: Metal-Mediated Transformations of Small Molecules

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C3CC48933G
Article type: Communication
Submitted: 22 Лис 2013
Accepted: 09 Гру 2013
First published: 09 Гру 2013

Download Citation

Chem. Commun., 2014,50, 1944-1946

Author version available

Download author version (PDF)

Permissions

Request permissions

Activation of gaseous PH₃ with low coordinate diaryltetrylene compounds

J. W. Dube, Z. D. Brown, C. A. Caputo, P. P. Power and P. J. Ragogna, Chem. Commun., 2014, 50, 1944 DOI: 10.1039/C3CC48933G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications