Issue 6, 2014

Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

Abstract

The reactivity of a rhenium complex containing an NAD+ model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph3C+.

Graphical abstract: Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

Supplementary files

Article information

Article type
Communication
Submitted
07 Жов 2013
Accepted
05 Лис 2013
First published
06 Лис 2013

Chem. Commun., 2014,50, 728-730

Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

Y. Matsubara, S. E. Hightower, J. Chen, D. C. Grills, D. E. Polyansky, J. T. Muckerman, K. Tanaka and E. Fujita, Chem. Commun., 2014, 50, 728 DOI: 10.1039/C3CC47699E

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