Yulia Aleksandrova, Aldar Munkuev, Evgenii Mozhaitsev, Evgenii Suslov, Dmitry Tsypyshev, Kirill Chaprov, Roman Begunov, Konstantin Volcho, Nariman Salakhutdinov and Margarita Neganova

IJMS, 2023, 24, 9743
DOI: 10.3390/ijms24119743

Photoredox-Catalyzed Benzylic Esterification via Radical-Polar Crossover

Bumpei Maeda, Yota Sakakibara, Kei Murakami and Kenichiro Itami

Org. Lett., 2021, 23, 5113
DOI: 10.1021/acs.orglett.1c01645

Visible‐Light‐Promoted Aliphatic C−H Chlorination and Bromination Using Haloform as the Halogen Donor and Azidobenziodoxole as the Mediator

Qin He, Zehui Cao, Yangyang Zhang, Gong Chen and Yaxin Wang

Adv Synth Catal, 2023, 365, 2711
DOI: 10.1002/adsc.202300416

Synthesis of Nitrated N‐Alkyl Anilines Using N‐Nitroso Anilines as a Self‐Providing Nitro Group Source

Yuxian Zhang, Shuwei Zhang, Zheng Sun, Yu Yuan and Xiaodong Jia

Asian J Org Chem, 2019, 8, 2205
DOI: 10.1002/ajoc.201900664

Visible‐Light‐Initiated Air‐Oxygenation of Alkylarenes to Carbonyls Mediated by Carbon Tetrabromide in Water

Chunbo Bo, Min Li, Fei Chen, Jichang Liu, Bin Dai and Ning Liu

ChemSusChem, 2024, 17
DOI: 10.1002/cssc.202301015

Photoredox-Mediated Mono- and Difluorination of Remote Unactivated Methylene C(sp3)–H Bonds of N-Alkyl Sulfonamides

Zhiqiang Deng, Zhenxiang Zhao, Gang He and Gong Chen

Org. Lett., 2021, 23, 3631
DOI: 10.1021/acs.orglett.1c01020

Continuous Flow Electrochemistry Enables Practical and Site‐Selective C−H Oxidation

Tian‐Sheng Chen, Hao Long, Yuxing Gao and Hai‐Chao Xu

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202310138

Hypervalent Iodine‐Mediated Late‐Stage Peptide and Protein Functionalization

Emmanuelle M. D. Allouche, Elija Grinhagena and Jerome Waser

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202112287

Recent Advances in Rapid Synthesis of Non-proteinogenic Amino Acids from Proteinogenic Amino Acids Derivatives via Direct Photo-Mediated C–H Functionalization

Zhenbo Yuan, Xuanzhong Liu, Changmei Liu, Yan Zhang and Yijian Rao

Molecules, 2020, 25, 5270
DOI: 10.3390/molecules25225270

Photoredox-Mediated Minisci-type Alkylation of N-Heteroarenes with Alkanes with High Methylene Selectivity

Guo-Xing Li, Xiafei Hu, Gang He and Gong Chen

ACS Catal., 2018, 8, 11847
DOI: 10.1021/acscatal.8b04079

Practical Synthesis of 2-Iodosobenzoic Acid (IBA) without Contamination by Hazardous 2-Iodoxybenzoic Acid (IBX) under Mild Conditions

Hideyasu China, Nami Kageyama, Hotaka Yatabe, Naoko Takenaga and Toshifumi Dohi

Molecules, 2021, 26, 1897
DOI: 10.3390/molecules26071897

Radical‐Based Synthesis and Modification of Amino Acids

Francisco José Aguilar Troyano, Kay Merkens, Khadijah Anwar and Adrián Gómez‐Suárez

Angew Chem Int Ed, 2021, 60, 1098
DOI: 10.1002/anie.202010157

Strategic application of C–H oxidation in natural product total synthesis

Ian Bakanas, Robert F. Lusi, Stefan Wiesler, Jack Hayward Cooke and Richmond Sarpong

Nat Rev Chem, 2023, 7, 783
DOI: 10.1038/s41570-023-00534-6

Cobalt Catalyzed α-Hydroxylation of Arylacetic Acid Equivalents with Dioxygen

Rupali Dasharath Shinde, Anil Rajendra Paraskar, Jogendra Kumar, Eliza Ghosh, Tapan Kanti Paine and Sukalyan Bhadra

J. Org. Chem., 2024, 89, 9666
DOI: 10.1021/acs.joc.4c00708

Calcium(II)-Catalyzed Intra- and Intermolecular Hydroamidation of Unactivated Alkenes in Hexafluoroisopropanol

Chenxiao Qi, Felix Hasenmaile, Vincent Gandon and David Lebœuf

ACS Catal., 2018, 8, 1734
DOI: 10.1021/acscatal.7b04271

Use of Emerging C-H Functionalization Methods to Implement Strategies for the Divergent Total Syntheses of Bridged Polycyclic Natural Products

Goh Sennari and Richmond Sarpong

J. Synth. Org. Chem. Jpn., 2023, 81, 1028
DOI: 10.5059/yukigoseikyokaishi.81.1028

Hypervalent Iodine‐Mediated Late‐Stage Peptide and Protein Functionalization

Emmanuelle M. D. Allouche, Elija Grinhagena and Jerome Waser

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202112287

Late‐Stage Oxidation of C(sp3)─H Bonds with High Efficiency and Alkyl Group Dihydroxylation of Complex Molecules

Yi Cheng Kang, Dmitriy M. Volochnyuk, Serhiy V. Ryabukhin and John F. Hartwig

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202513418

Electrochemical Direct Hydroxylation of Benzylic C–H Bonds Assisted by HFIP

Cui Zhang, Haobo Tang, Xilin Zhao, Xianglin Shen and Youai Qiu

J. Am. Chem. Soc., 2025, 147, 23297
DOI: 10.1021/jacs.5c08109

A general strategy for C(sp3)–H functionalization with nucleophiles using methyl radical as a hydrogen atom abstractor

Isabelle Nathalie-Marie Leibler, Makeda A. Tekle-Smith and Abigail G. Doyle

Nat Commun, 2021, 12
DOI: 10.1038/s41467-021-27165-z

Ag-Catalyzed Remote Unactivated C(sp3)–H Heteroarylation of Free Alcohols in Water

Miao Wang, Changzhen Yin and Peng Hu

Org. Lett., 2021, 23, 722
DOI: 10.1021/acs.orglett.0c03944

O-Methyl-N-nitroisourea as a NCO Surrogate in Cu-Catalyzed Alkane C–H Amidination. A Masked Isocyanate Strategy

Jonathan Lusseau, Frédéric Robert and Yannick Landais

ACS Catal., 2023, 13, 14257
DOI: 10.1021/acscatal.3c03293

Computational investigation of the radical‐mediated mechanism of formation of difluoro methyl oxindoles: Elucidation of the reaction selectivity and yields

Thanachon Somnarin, Pacharaporn Krawmanee, Matthew Paul Gleeson and Duangkamol Gleeson

J Comput Chem, 2023, 44, 670
DOI: 10.1002/jcc.27031

Retracted: Combined Photoredox/Enzymatic C−H Benzylic Hydroxylations

Rick C. Betori, Catherine M. May and Karl A. Scheidt

Angewandte Chemie, 2019, 131, 16642
DOI: 10.1002/ange.201909426

HFIP in Organic Synthesis

Hashim F. Motiwala, Ahlam M. Armaly, Jackson G. Cacioppo, Thomas C. Coombs, Kimberly R. K. Koehn, Verrill M. Norwood and Jeffrey Aubé

Chem. Rev., 2022, 122, 12544
DOI: 10.1021/acs.chemrev.1c00749

Radical C(sp3)–H functionalization and cross-coupling reactions

Dung L. Golden, Sung-Eun Suh and Shannon S. Stahl

Nat Rev Chem, 2022, 6, 405
DOI: 10.1038/s41570-022-00388-4

Enantioselective Intermolecular Radical Amidation and Amination of Benzylic C−H Bonds via Dual Copper and Photocatalysis

Xuemeng Chen, Zhong Lian and Søren Kramer

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202217638

Biocatalytic stereoselective synthesis of methyl mandelates by engineering a cytochrome P450 hydroxylase

Lingzhi Xie, Yun Zhang, Ruyue Zhang, Haibo Cui, Baodong Cui, Wenyong Han, Nanwei Wan, Zhi Li and Yongzheng Chen

Green Synthesis and Catalysis, 2024, 5, 88
DOI: 10.1016/j.gresc.2023.01.005

Hydrogen Atom Transfer for C(sp3)−H Functionalization Enabled by Photoredox/Thianthrene/Methanol Synergistic Catalysis

Xiaoyi Zhang, Shen Ning, Yi Li, Yanjiao Xiong and Xuesong Wu

ChemCatChem, 2023, 15
DOI: 10.1002/cctc.202300311

Hydrogen Bonding Networks Enable Brønsted Acid‐Catalyzed Carbonyl‐Olefin Metathesis**

Tuong Anh To, Chao Pei, Rene M. Koenigs and Thanh Vinh Nguyen

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202117366

Continuous Flow Electrochemistry Enables Practical and Site‐Selective C−H Oxidation

Tian‐Sheng Chen, Hao Long, Yuxing Gao and Hai‐Chao Xu

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202310138

Photoredox‐Mediated Minisci Alkylation of N‐Heteroarenes using Carboxylic Acids and Hypervalent Iodine

Junhua Wang, Guo‐Xing Li, Gang He and Gong Chen

Asian J Org Chem, 2018, 7, 1307
DOI: 10.1002/ajoc.201800197

FeCl3/KI‐Catalyzed Tandem Oxidative Cyclization for Switchable Total Synthesis of Luotonin A, B and Derivatives

Ying‐Chun Song, Ming‐Xuan Wang, Yun‐Ying Yi, Yu‐Ting Liu, Wen‐Xin Zhang, Zi‐Yue Wang, Yuan‐Yuan Sun, An‐Xin Wu and Yan‐Ping Zhu

Adv Synth Catal, 2024, 366, 1348
DOI: 10.1002/adsc.202301322

Late‐Stage Oxygenation in Organic Synthesis: From Innate Reactivity to Directed Selectivity in Complex Settings

Kyriaki Gennaiou, Maria Kourgiantaki, Kalliopi Mazaraki, François Richard, Nicolas Fincias, Stellios Arseniyadis and Alexandros L. Zografos

Angew Chem Int Ed, 2026
DOI: 10.1002/anie.202521362

Tandem Oxidative Ritter Reaction/Hydration/Aldol Condensation of α-Arylketones with Propiolonitriles for the Construction of 3-Acyl-3-pyrrolin-2-ones

Meng-En Chen, Zhang-Yan Gan, Yue-Hong Hu and Fu-Min Zhang

J. Org. Chem., 2023, 88, 3954
DOI: 10.1021/acs.joc.2c02935

Cyclic Hypervalent Iodine Reagents as a Bifunctional Platform for Benzylic C–H Oxidation via Dual Oxidative Radical–Polar Crossover

Jiaxin He, Haofeng Shi, Jialiang Wu, Kaiyue Yang, Dan Xiao, Lingzhi Xu and Yunfei Du

Chin. J. Chem., 2025, 43, 3405
DOI: 10.1002/cjoc.70336

Azolation of Benzylic C–H Bonds via Photoredox-Catalyzed Carbocation Generation

Mrinmoy Das, Leila Zamani, Christopher Bratcher and Patricia Z. Musacchio

J. Am. Chem. Soc., 2023, 145, 3861
DOI: 10.1021/jacs.2c12850

Photocatalytic Late-Stage C–H Functionalization

Peter Bellotti, Huan-Ming Huang, Teresa Faber and Frank Glorius

Chem. Rev., 2023, 123, 4237
DOI: 10.1021/acs.chemrev.2c00478

Recent Advances in C-O Bond Construction via C-H Activation

Quan Zheng, Jie Chen and Guo-Wu Rao

Russ J Org Chem, 2019, 55, 569
DOI: 10.1134/S1070428019040249

Visible-Light-Induced Tertiary C(sp3)–H Sulfonylation: An Approach to Tertiary Sulfones

Sumedha Swarnkar, Mohd Yeshab Ansari and Atul Kumar

Org. Lett., 2021, 23, 1163
DOI: 10.1021/acs.orglett.0c03898

Selective functionalization of benzylic C(sp3)–H bonds to synthesize complex molecules

Yu Zhang, Tong Zhang and Shoubhik Das

Chem, 2022, 8, 3175
DOI: 10.1016/j.chempr.2022.10.005

Direct Solar Energy-Mediated Synthesis of Tertiary Benzylic Alcohols Using a Metal-Free Heterogeneous Photocatalyst

Yu Zhang, Shaowei Qin, Nathalie Claes, Waldemar Schilling, Prakash Kumar Sahoo, H. Y. Vincent Ching, Aleksander Jaworski, Filip Lemière, Adam Slabon, Sabine Van Doorslaer, Sara Bals and Shoubhik Das

ACS Sustainable Chem. Eng., 2022, 10, 530
DOI: 10.1021/acssuschemeng.1c07026

Radikal‐basierte Synthese und Modifikation von Aminosäuren

Francisco José Aguilar Troyano, Kay Merkens, Khadijah Anwar and Adrián Gómez‐Suárez

Angewandte Chemie, 2021, 133, 1112
DOI: 10.1002/ange.202010157

C–H Amination via Electrophotocatalytic Ritter-type Reaction

Tao Shen and Tristan H. Lambert

J. Am. Chem. Soc., 2021, 143, 8597
DOI: 10.1021/jacs.1c03718

Organocatalysis with carbon nitrides

Sujanya Maria Ruban, Kavitha Ramadass, Gurwinder Singh, Siddulu Naidu Talapaneni, Gunda Kamalakar, Chandrakanth Rajanna Gadipelly, Lakshmi Kantham Mannepalli, Yoshihiro Sugi and Ajayan Vinu

Science and Technology of Advanced Materials, 2023, 24
DOI: 10.1080/14686996.2023.2188879

Acyl Radicals from Benzothiazolines: Synthons for Alkylation, Alkenylation, and Alkynylation Reactions

Lei Li, Shan Guo, Qi Wang and Jin Zhu

Org. Lett., 2019, 21, 5462
DOI: 10.1021/acs.orglett.9b01717

Visible Light Mediated Chemoselective Hydroxylation of Benzylic Methylenes

Zhiyong Tan, Tingting Chen, Jinbin Zhu, Wenjun Luo, Daohong Yu and Wei Guo

J. Org. Chem., 2024, 89, 2656
DOI: 10.1021/acs.joc.3c02683

Mechanistic Investigation of the Iron-Catalyzed Azidation of Alkyl C(sp3)–H Bonds with Zhdankin’s λ3-Azidoiodane

Craig S. Day, Alexander Fawcett, Ruchira Chatterjee and John F. Hartwig

J. Am. Chem. Soc., 2021, 143, 16184
DOI: 10.1021/jacs.1c07330

Photoinduced Azidoamination of Styrenes Using Sodium Azide and (Diphenylmethylene)amino Benziodoxolone

Kensuke Kiyokawa, Koki Nakano, Daichi Okumatsu and Satoshi Minakata

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202401493

Enhanced electrocatalytic C H amination of toluene via tailored interfacial microenvironment

Zong-Xu Li, Sheng Tian, Qing Hu, Xin-Yi Huang, Hong-Yi Tan, Jun-Kang Guo and Shuang-Feng Yin

Journal of Colloid and Interface Science, 2025, 680, 578
DOI: 10.1016/j.jcis.2024.10.192

Late‐Stage Oxidation of C(sp3)─H Bonds with High Efficiency and Alkyl Group Dihydroxylation of Complex Molecules

Yi Cheng Kang, Dmitriy M. Volochnyuk, Serhiy V. Ryabukhin and John F. Hartwig

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202513418

Selective P−C(sp3) Bond Cleavage and Radical Alkynylation of α‐Phosphorus Alcohols by Photoredox Catalysis

Kunfang Jia, Junzhao Li and Yiyun Chen

Chemistry A European J, 2018, 24, 3174
DOI: 10.1002/chem.201800202

Ritter-type amination of C(sp3)-H bonds enabled by electrochemistry with SO42−

Ling Zhang, Youtian Fu, Yi Shen, Chengyu Liu, Maolin Sun, Ruihua Cheng, Weiping Zhu, Xuhong Qian, Yueyue Ma and Jinxing Ye

Nat Commun, 2022, 13
DOI: 10.1038/s41467-022-31813-3

Recent Synthetic Applications of the Hypervalent Iodine(III) Reagents in Visible-Light-Induced Photoredox Catalysis

Chaoyue Chen, Xin Wang and Tinghai Yang

Front. Chem., 2020, 8
DOI: 10.3389/fchem.2020.551159

Total Synthesis of (±)-Oxacyclododecindione

Kevin Seipp, Vincent Grölz, Hagen Glass, Elisabeth Quraishi, Nina Vierengel and Till Opatz

J. Org. Chem., 2024, 89, 5746
DOI: 10.1021/acs.joc.4c00333

Merging New and Old Concepts: Tandem Oxidative Radical‐Polar Crossover Ritter Amidation via Multicomponent Photo‐ and Electrochemical Processes

Mattia Lepori, Indrasish Dey, Cassie Pratley and Joshua P. Barham

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202400840

Viewing the Ritter reaction through single electron transfer lenses

Apurba Samanta, Saradindu Debnath, Palash Roy and Soumitra Maity

Tetrahedron, 2025, 187, 134907
DOI: 10.1016/j.tet.2025.134907

Site‐Selective C–H Bond Activation/Functionalization of Alpha‐Amino Acids and Peptide‐Like Derivatives

Tobias Brandhofer and Olga García Mancheño

Eur J Org Chem, 2018, 2018, 6050
DOI: 10.1002/ejoc.201800896

Late‐Stage Oxygenation in Organic Synthesis: From Innate Reactivity to Directed Selectivity in Complex Settings

Kyriaki Gennaiou, Maria Kourgiantaki, Kalliopi Mazaraki, François Richard, Nicolas Fincias, Stellios Arseniyadis and Alexandros L. Zografos

Angewandte Chemie, 2026
DOI: 10.1002/ange.202521362

Unified Total Syntheses of Benzenoid Cephalotane-Type Norditerpenoids: Cephanolides and Ceforalides

Goh Sennari, Kristen E. Gardner, Stefan Wiesler, Maximilian Haider, Alina Eggert and Richmond Sarpong

J. Am. Chem. Soc., 2022, 144, 19173
DOI: 10.1021/jacs.2c08803

Synthesis of Benzylic Alcohols by C–H Oxidation

Lalita Tanwar, Jonas Börgel and Tobias Ritter

J. Am. Chem. Soc., 2019, 141, 17983
DOI: 10.1021/jacs.9b09496

Copper‐Catalyzed Benzylic C—H Functionalization, Oxidation and Cyclization of Methylarenes: Direct Access to 2‐Arylbenzothiazoles

Wentao Yu, Wanqing Wu and Huanfeng Jiang

Chin. J. Chem., 2019, 37, 1158
DOI: 10.1002/cjoc.201900340