Gustavo Ríos-Moreno, José G. Alvarado-Rodríguez, Sara A. Cortes-Llamas, Valentín Miranda-Soto, Gerardo Aguirre-Hernández, Sara Muro-Herrera, Guillermo Quiñones-Reyes, Ma.Guadalupe Félix-Flores and Leticia Lozada-Rodríguez

Inorganica Chimica Acta, 2025, 578, 122539
DOI: 10.1016/j.ica.2025.122539

A Copper‐Catalyzed Decarboxylative Amination/Hydroamination Sequence: Switchable Synthesis of Functionalized Indoles

Tian‐Ren Li, Bei‐Yi Cheng, Ya‐Ni Wang, Mao‐Mao Zhang, Liang‐Qiu Lu and Wen‐Jing Xiao

Angew Chem Int Ed, 2016, 55, 12422
DOI: 10.1002/anie.201605900

Ag(I)-Catalyzed Domino Cyclization–Addition Sequence with Simultaneous Carbonyl and Alkyne Activation as a Route to 2,2′-Disubstituted Bisindolylarylmethanes

Swastik Karmakar, Prasanta Das, Debjyoti Ray, Subhankar Ghosh and Shital K. Chattopadhyay

Org. Lett., 2016, 18, 5200
DOI: 10.1021/acs.orglett.6b02321

Palladium‐Catalyzed One‐Pot Three‐ or Four‐Component Coupling of Aryl Iodides, Alkynes, and Amines through CN Bond Cleavage: Efficient Synthesis of Indole Derivatives

Wei Hao, Weizhi Geng, Wen‐Xiong Zhang and Zhenfeng Xi

Chemistry A European J, 2014, 20, 2605
DOI: 10.1002/chem.201304215

Intramolecular Carbocupration of N-Aryl-ynamides: A Modular Indole Synthesis

Wafa Gati, François Couty, Taoufik Boubaker, Mohamed M. Rammah, Mohamed B. Rammah and Gwilherm Evano

Org. Lett., 2013, 15, 3122
DOI: 10.1021/ol4013298

Biosynthesis of BiFeO3 for BiFeO3@Ag-S-CH2-COOH as the nanocatalyst for one-pot synthesis of 2, 3-dihydroquinazolin-4(1H)-ones and their anti-blood cancer activity

Shankar Pralhadrao Phulwale, Shivaji Devrao Waghmare, Akshay Pandurang Gurav, Krishna Chaitanya Gunturu and Shankar Poshatti Hangirgekar

Journal of Molecular Structure, 2025, 1338, 142288
DOI: 10.1016/j.molstruc.2025.142288

Copper-Mediated Intramolecular Oxidative C–H/C–H Cross-Coupling of α-Oxo Ketene N,S-Acetals for Indole Synthesis

Fei Huang, Ping Wu, Liandi Wang, Jiping Chen, Chenglin Sun and Zhengkun Yu

J. Org. Chem., 2014, 79, 10553
DOI: 10.1021/jo5014542

Synthesis of Indoles via Electron-Catalyzed Intramolecular C–N Bond Formation

Dmitry I. Bugaenko, Anastasia A. Dubrovina, Marina A. Yurovskaya and Alexander V. Karchava

Org. Lett., 2018, 20, 7358
DOI: 10.1021/acs.orglett.8b02784

AlCl3-promoted three-component cascade reaction for rapid access to [1,2,3]triazolo[5,1-a]isoquinolines

Yangang Wu, Yonggang Meng, Zibo Liu, Mengge Zhang and Chuanjun Song

Tetrahedron Letters, 2019, 60, 151287
DOI: 10.1016/j.tetlet.2019.151287

Fe(OTf)3‐Catalyzed Aromatization of Substituted 3‐Methyleneindoline and Benzofuran Derivatives: A Selective Route to C‐3‐Alkylated Indoles and Benzofurans

Sandip Kundal, Swapnadeep Jalal, Kartick Paul and Umasish Jana

Eur J Org Chem, 2015, 2015, 5513
DOI: 10.1002/ejoc.201500540

Ligand‐Free Copper‐Catalyzed One‐Pot Synthesis of Indole‐2‐carboxylic Esters

Zhiqiang Zhu, Jiangjun Yuan, Yirong Zhou, Yang Qin, Jingshi Xu and Yiyuan Peng

Eur J Org Chem, 2014, 2014, 511
DOI: 10.1002/ejoc.201301607

Pd‐Catalyzed Regioselective Domino C−C Bond Formation to Access N‐Fused Benzimidazo‐Indolo‐Isoquinoline Heterocycles

Vijay Babu Pathi, Arindam Manna, Ravuri Srinath, Supriyo Adhikary and Biswadip Banerji

Eur J Org Chem, 2023, 26
DOI: 10.1002/ejoc.202300256

Recent Advances in the Synthesis of Thiophene Derivatives by Cyclization of Functionalized Alkynes

Raffaella Mancuso and Bartolo Gabriele

Molecules, 2014, 19, 15687
DOI: 10.3390/molecules191015687

Synthesis of 1,2-Bis(2-aryl-1H-indol-3-yl)ethynes via 5-exo-Digonal Double Cyclization Reactions of 1,4-Bis(2-isocyanophenyl)buta-1,3-diyne with Aryl Grignard Reagents

Rino Ishikawa, Ryosuke Iwasawa, Yuichiro Takiyama, Tomokazu Yamauchi, Tetsuo Iwanaga, Makoto Takezaki, Motonori Watanabe, Naozumi Teramoto, Toshiaki Shimasaki and Mitsuhiro Shibata

J. Org. Chem., 2017, 82, 652
DOI: 10.1021/acs.joc.6b02668

A General Protocol toward Synthesis of 3-Methylindoles Using Acenaphthoimidazolyidene-Ligated Oxazoline Palladacycle

Ruoqian Fan, Haili Wen, Zhen Chen, Yuanzhi Xia and Weiwei Fang

Org. Lett., 2024, 26, 22
DOI: 10.1021/acs.orglett.3c03438

Rhodium(I)‐Catalyzed Benzannulation of Heteroaryl Propargylic Esters: Synthesis of Indoles and Related Heterocycles

Xiaoxun Li, Haibo Xie, Xiaoning Fu, Ji‐tian Liu, Hao‐yuan Wang, Bao‐min Xi, Peng Liu, Xiufang Xu and Weiping Tang

Chemistry A European J, 2016, 22, 10410
DOI: 10.1002/chem.201602088

Synthesis of 3-Iminoindol-2-amines and Cyclic Enaminones via Palladium-Catalyzed Isocyanide Insertion-Cyclization

Yuan-Yuan Pan, Ya-Nan Wu, Zhen-Zhen Chen, Wen-Juan Hao, Guigen Li, Shu-Jiang Tu and Bo Jiang

J. Org. Chem., 2015, 80, 5764
DOI: 10.1021/acs.joc.5b00727

Synthesis of Pyrroles, Indoles, and Carbazoles through Transition‐Metal‐Catalyzed CH Functionalization

Naohiko Yoshikai and Ye Wei

Asian J Org Chem, 2013, 2, 466
DOI: 10.1002/ajoc.201300016

One‐Pot Tandem Coupling Method for the Short‐Step Formal Synthesis of Riccardin C

Miho Kobatake, Norikazu Miyoshi and Masaharu Ueno

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203805

Copper-Catalyzed Synthesis of Indol-3-yl α-(Difluoromethyl)-α-(trifluoromethyl)carbinols: Construction of Difluoromethylated sp3 Carbon Centers

Yunxiao Zhang, Weitao Yan, Yukang Wang and Zhiqiang Weng

Org. Lett., 2017, 19, 5478
DOI: 10.1021/acs.orglett.7b02828

Selective Synthesis of Indoles by Cobalt(III)-Catalyzed C–H/N–O Functionalization with Nitrones

Hui Wang, Marc Moselage, María J. González and Lutz Ackermann

ACS Catal., 2016, 6, 2705
DOI: 10.1021/acscatal.5b02937

Catalytic Synthesis of Substituted Indoles and Quinolines from the Dehydrative C–H Coupling of Arylamines with 1,2- and 1,3-Diols

Hanbin Lee and Chae S. Yi

Organometallics, 2016, 35, 1973
DOI: 10.1021/acs.organomet.6b00273

Mild and Efficient One-Pot Synthesis of 2-(Perfluoroalkyl)indoles by Means of Sequential Michael-Type Addition and Pd(II)-Catalyzed Cross-Dehydrogenative Coupling (CDC) Reaction

Dandan Shen, Jing Han, Jie Chen, Hongmei Deng, Min Shao, Hui Zhang and Weiguo Cao

Org. Lett., 2015, 17, 3283
DOI: 10.1021/acs.orglett.5b01479

An Efficient Approach to 2-CF3-Indoles Based on ortho-Nitrobenzaldehydes

Vasiliy M. Muzalevskiy, Zoia A. Sizova, Vladimir T. Abaev and Valentine G. Nenajdenko

Molecules, 2021, 26, 7365
DOI: 10.3390/molecules26237365

Synthesis of indole derivatives from the S 3 •− -mediated intramolecular cyclization of o -alkynylanilines

Zhaoxin Jing, Jiakai Wu, Shuyi Li, Ruijun Xie, Hailong Hong and Ning Zhu

Synthetic Communications, 2024, 54, 1147
DOI: 10.1080/00397911.2024.2373164

Synthesis of 3-(Organochalcogen) Chalcogenazolo Indoles via Cascade Cyclization of N-Alkynylindoles

Thaís Prochnow, Adriano Maroneze, Davi Fernando Back and Gilson Zeni

J. Org. Chem., 2019, 84, 2891
DOI: 10.1021/acs.joc.9b00052

Selective C−N Bond Cleavage of N‐Acylisatins: Towards High Performance Acylation/Arylation/Transamination Reagents

Li Xiong, Rong Deng, Tingting Liu, Zhongfeng Luo, Zijia Wang, Xiao‐Feng Zhu, Hui Wang and Zhuo Zeng

Adv Synth Catal, 2019, 361, 5383
DOI: 10.1002/adsc.201900819

Copper-Catalyzed Aerobic Oxidative Amination of Arylboronic Acid with Aminal under Base-Free Conditions

Yanping Zhou, Yinjun Xie, Lei Yang, Pan Xie and Hanmin Huang

Tetrahedron Letters, 2013, 54, 2713
DOI: 10.1016/j.tetlet.2013.03.058

Mild and efficient synthesis of isoindigo derivatives catalyzed by Lewis acid

Meilin Liu, Shaozhong Qiu, Yu Ye and Guodong Yin

Tetrahedron Letters, 2016, 57, 5856
DOI: 10.1016/j.tetlet.2016.11.053

Mehrkomponentenkaskade zur Synthese von Indolen, Pyrazolen und Pyridazinonen durch Funktionalisierung von Alkenen

Kiran Matcha and Andrey P. Antonchick

Angewandte Chemie, 2014, 126, 12154
DOI: 10.1002/ange.201406464

Ruthenium-Catalyzed Cycloisomerization of 2-Alkynylanilides: Synthesis of 3-Substituted Indoles by 1,2-Carbon Migration

Takuma Watanabe, Yuichiro Mutoh and Shinichi Saito

J. Am. Chem. Soc., 2017, 139, 7749
DOI: 10.1021/jacs.7b04564

Synthesis of Functionalized Indole-1-oxide Derivatives via Cascade Reactions of Allenynes and tBuONO

Yan He, Tian Feng and Xuesen Fan

Org. Lett., 2019, 21, 3918
DOI: 10.1021/acs.orglett.9b00968

Divergent Syntheses of Indoles and Quinolines Involving N1–C2–C3 Bond Formation through Two Distinct Pd Catalyses

Su San Jang, Young Ho Kim and So Won Youn

Org. Lett., 2020, 22, 9151
DOI: 10.1021/acs.orglett.0c02898

A review on selective production of value-added chemicals via catalytic pyrolysis of lignocellulosic biomass

Leilei Dai, Yunpu Wang, Yuhuan Liu, Chao He, Roger Ruan, Zhenting Yu, Lin Jiang, Zihong Zeng and Qiuhao Wu

Science of The Total Environment, 2020, 749, 142386
DOI: 10.1016/j.scitotenv.2020.142386

Synthesis of Indoles: Sulfur-Assisted Reaction of 2-Nitrostilbenes with Carbon Monoxide

Yutaka Nishiyama, Rui Umeda, Yuuta Nishimoto and Tsukasa Mashino

HETEROCYCLES, 2013, 87, 1241
DOI: 10.3987/COM-13-12708

Synthesis of Indole Derivatives from 2‐Alkynylanilines by Means of Gold Catalysis

Giorgio Abbiati, Fabio Marinelli, Elisabetta Rossi and Antonio Arcadi

Israel Journal of Chemistry, 2013, 53, 856
DOI: 10.1002/ijch.201300040

Regiospecific Synthesis of 7‐Hydroxyindoles from Pyrroles by Anionic Benzannulation

Bidyut Kumar Dinda, Shyam Basak and Dipakranjan Mal

Eur J Org Chem, 2014, 2014, 5521
DOI: 10.1002/ejoc.201402486

Direct Access to Functionalized Indoles via Single Electron Oxidation Induced Coupling of Diarylamines with 1,3-Dicarbonyl Compounds

Taoyuan Liang, He Zhao, Lingzhen Gong, Huanfeng Jiang and Min Zhang

Org. Lett., 2019, 21, 6736
DOI: 10.1021/acs.orglett.9b02349

One-Pot Gold-Catalyzed Aminofluorination of Unprotected 2-Alkynylanilines

Antonio Arcadi, Emanuela Pietropaolo, Antonello Alvino and Véronique Michelet

Org. Lett., 2013, 15, 2766
DOI: 10.1021/ol401098b

ChemInform Abstract: Progress in Palladium‐Based Catalytic Systems for the Sustainable Synthesis of Annulated Heterocycles: A Focus on Indole Backbones

Melanie Platon, Regine Amardeil, Laurent Djakovitch and Jean‐Cyrille Hierso

ChemInform, 2012, 43
DOI: 10.1002/chin.201231258

Silver(I)‐Mediated CH Amination of 2‐Alkenylanilines: Unique Solvent‐Dependent Migratory Aptitude

So Won Youn, Tae Yun Ko, Min Jung Jang and Su San Jang

Adv Synth Catal, 2015, 357, 227
DOI: 10.1002/adsc.201400759

Palladium-Catalyzed α-Arylation of Enones in the Synthesis of 2-Alkenylindoles and Carbazoles

Ajit Prabhakar Kale, Gangam Srikanth Kumar, Arun Raj Kizhakkayil Mangadan and Manmohan Kapur

Org. Lett., 2015, 17, 1324
DOI: 10.1021/acs.orglett.5b00324

C-H Functionalization of Indoles at the C7 Position

Miyuki Yamaguchi

J. Syn. Org. Chem., Jpn., 2017, 75, 671
DOI: 10.5059/yukigoseikyokaishi.75.671

Ruthenium-Catalyzed Heteroatom-Directed Regioselective C–H Arylation of Indoles Using a Removable Tether

Virendra Kumar Tiwari, Neha Kamal and Manmohan Kapur

Org. Lett., 2015, 17, 1766
DOI: 10.1021/acs.orglett.5b00535

Total Synthesis of Aaptamine, Demethyloxyaaptamine, and Their 3-Alkylamino Derivatives

Yuan Gao, Fan Yang, Fan Sun, Lei Liu, Bo Liu, Shu-Ping Wang, Chun-Wei Cheng, Hongze Liao and Hou-Wen Lin

Org. Lett., 2019, 21, 1430
DOI: 10.1021/acs.orglett.9b00183

An Efficient Synthesis of 2-CF3-3-Benzylindoles

Vasiliy M. Muzalevskiy, Zoia A. Sizova and Valentine G. Nenajdenko

Molecules, 2021, 26, 5084
DOI: 10.3390/molecules26165084

Pd-Catalyzed α-Arylation of Sulfones in a Three-Component Synthesis of 3-[2-(Phenyl/methylsulfonyl)ethyl]indoles

Daniel Solé, Ferran Pérez-Janer, Ester Zulaica, Javier F. Guastavino and Israel Fernández

ACS Catal., 2016, 6, 1691
DOI: 10.1021/acscatal.6b00027

Synthesis of Triazolo Isoquinolines and Isochromenes from 2-Alkynylbenzaldehyde via Domino Reactions under Transition-Metal-Free Conditions

Rajesh K. Arigela, Srinivas Samala, Rohit Mahar, Sanjeev K. Shukla and Bijoy Kundu

J. Org. Chem., 2013, 78, 10476
DOI: 10.1021/jo401929q

Intermolecular Domino Reaction of Two Aryl Iodides Involving Two CH Functionalizations

Marcel Sickert, Harald Weinstabl, Brendan Peters, Xiao Hou and Mark Lautens

Angew Chem Int Ed, 2014, 53, 5147
DOI: 10.1002/anie.201400807

Ligand-Controlled Selective Synthesis of Indoles and Benzofurans from Secondary Anilines

Chunchen Yuan, Changbo Jia, Wenlong Zhang, Yang’en You, Lei Zhu and Yongping Dong

Org. Lett., 2024, 26, 8798
DOI: 10.1021/acs.orglett.4c03173

Facile and efficient synthesis of [1,4]oxazino[3,2-b]indoles and 1H-pyrazino[2,3-b]indoles through gold-catalyzed cascade cyclization of (azido)ynamides

Cang-Hai Shen, Yuan Pan, Yong-Fei Yu, Ze-Shu Wang, Weimin He, Ting Li and Long-Wu Ye

Journal of Organometallic Chemistry, 2015, 795, 63
DOI: 10.1016/j.jorganchem.2015.01.029

Enantioselective synthesis of indoles through catalytic indolization

Bin-Miao Yang, Xiao Qian Ng and Yu Zhao

Chem Catalysis, 2022, 2, 3048
DOI: 10.1016/j.checat.2022.10.004

Synthesis of Chromeno[2,3-b]indol-11(6H)-one via PhI(OAc)2-Mediated Intramolecular Oxidative C(sp2)–N(H2) Bond Formation

Jiyun Sun, Daisy Zhang-Negrerie, Yunfei Du and Kang Zhao

J. Org. Chem., 2015, 80, 1200
DOI: 10.1021/jo502276b

One-pot Suzuki–Miyaura cross-coupling followed by reductive monoalkylation of the resulting nitro biaryl system utilizing Pd/C as catalyst

Lena Pedersen, Mohamed F. Mady and Magne O. Sydnes

Tetrahedron Letters, 2013, 54, 4772
DOI: 10.1016/j.tetlet.2013.06.128

Indole Synthesis through Sequential Electrophilic N−H and C−H Bond Activation Using Iodine(III) Reactivity

Laura Fra and Kilian Muñiz

Chemistry A European J, 2016, 22, 4351
DOI: 10.1002/chem.201504974

Strategies Employing Transition‐Metal Free Conditions for C−C Bond Formation in Indoles

Balaji M. Ghodake, Sayantan Paul and Asish K. Bhattacharya

ChemistrySelect, 2024, 9
DOI: 10.1002/slct.202403280

Synthesis of Indoles from o-Haloanilines

Assia Chebieb, Young Gyu Kim and Jin Kun Cha

J. Org. Chem., 2023, 88, 10164
DOI: 10.1021/acs.joc.3c01047

Novel and Efficient Heterogeneous 4-Methylbenzenesulfonic Acid-Based Ionic Liquid Supported on Silica Gel for Greener Fischer Indole Synthesis

Yu-Lin Hu, Dong Fang and Dong-Sheng Li

Catal Lett, 2016, 146, 968
DOI: 10.1007/s10562-016-1721-x

Intramolecular cyclization of N-propargyl anilines: a new synthetic entry into highly substituted indoles

Esmail Vessally, Akram Hosseinian, Ladan Edjlali, Ebrahim Ghorbani-Kalhor and Rahim Hosseinzadeh-Khanmiri

J IRAN CHEM SOC, 2017, 14, 2339
DOI: 10.1007/s13738-017-1170-5

Electrochemical [3+2] Cycloaddition of Anilines and 1,3‐Dicarbonyl Compounds: Construction of Multisubstituted Indoles

Xiaoqiang Chang, Xingyu Chen, Sixian Lu, Yifan Zhao, Yue Ma, Dong Zhang, Lan Yang and Peng Sun

Adv Synth Catal, 2022, 364, 2865
DOI: 10.1002/adsc.202200488

Recent Progress in Palladium Catalysed Sustainable Synthesis of Heterocycles

Debasree Saha and Chhanda Mukhopadhyay

COCAT, 2023, 10, 147
DOI: 10.2174/2213337210666221208142224

Palladium(II)-catalyzed oxidative annulation of alkenylindoles with alkynes initiated by C–H activation

Tao Su, Xiuling Han and Xiyan Lu

Tetrahedron Letters, 2014, 55, 27
DOI: 10.1016/j.tetlet.2013.10.079

Efficient Synthesis of Helical Tetrasubstituted Alkenes as Potential Molecular Switches: A Two‐Component Palladium‐Catalyzed Triple Domino Process

Lutz F. Tietze, Tim Hungerland, Christoph Eichhorst, Alexander Düfert, Christian Maaß and Dietmar Stalke

Angewandte Chemie, 2013, 125, 3756
DOI: 10.1002/ange.201209510

Direct Synthesis of Indoles from Azoarenes and Ketones with Bis(neopentylglycolato)diboron Using 4,4′-Bipyridyl as an Organocatalyst

Luis C. Misal Castro, Ibrahim Sultan, Kohei Nishi, Hayato Tsurugi and Kazushi Mashima

J. Org. Chem., 2021, 86, 3287
DOI: 10.1021/acs.joc.0c02661

Directing-Group-Free, Carbonyl Group-Promoted Catalytic C–H Arylation of Bio-Based Furans

Bogdan Ya. Karlinskii, Alexander Yu. Kostyukovich, Fedor A. Kucherov, Konstantin I. Galkin, Kirill S. Kozlov and Valentine P. Ananikov

ACS Catal., 2020, 10, 11466
DOI: 10.1021/acscatal.0c02143

Synthesis of Heterocycles through Denitrogenative Cyclization of Triazoles and Benzotriazoles

Wenbo Li and Junliang Zhang

Chemistry A European J, 2020, 26, 11931
DOI: 10.1002/chem.202000674

Chemospecific synthesis of 2-acetoxyindole-3-carbonitriles catalyzed by Cu(acac)2

Shanyan Mo, Jianzhuo Tu and Jiaxi Xu

Russ Chem Bull, 2016, 65, 1773
DOI: 10.1007/s11172-016-1509-6

A Domino Palladium-Catalyzed Cyclization: One-Pot Synthesis of 4b-Alkyl-10-phenyl-4b,5-dihydroindeno[2,1-a]indenes via Carbopalladation Followed by C–H Activation

Karu Ramesh and Gedu Satyanarayana

J. Org. Chem., 2017, 82, 4254
DOI: 10.1021/acs.joc.7b00254

Transition-metal-free synthesis of multisubstituted N-arylindoles via reaction of arynes and α-amino ketones

Lin He, Ji-Xin Pian, Jun-Feng Shi, Guang-Fen Du and Bin Dai

Tetrahedron, 2014, 70, 2400
DOI: 10.1016/j.tet.2014.02.028

Cascade Multicomponent Synthesis of Indoles, Pyrazoles, and Pyridazinones by Functionalization of Alkenes

Kiran Matcha and Andrey P. Antonchick

Angew Chem Int Ed, 2014, 53, 11960
DOI: 10.1002/anie.201406464

Photocatalytic Synthesis of Polycyclic Indolones

Tanguy Saget and Burkhard König

Chemistry A European J, 2020, 26, 7004
DOI: 10.1002/chem.202001324

Benzannulation via the Reaction of Ynamides and Vinylketenes. Application to the Synthesis of Highly Substituted Indoles

Tin Yiu Lam, Yu-Pu Wang and Rick L. Danheiser

J. Org. Chem., 2013, 78, 9396
DOI: 10.1021/jo401635c

Palladium-catalyzed formation of secondary and tertiary amines from aryl dihalides with air-stable ferrocenyl tri- and diphosphines: Synthesis and X-ray structure of efficient catalysts beyond [PdCl2(DPPF)]

Sophal Mom, Mélanie Platon, Hélène Cattey, Howard J. Spencer, Paul J. Low and Jean-Cyrille Hierso

Catalysis Communications, 2014, 51, 10
DOI: 10.1016/j.catcom.2014.03.012

Metal-Free C–H Amination for Indole Synthesis

Young Ho Jang and So Won Youn

Org. Lett., 2014, 16, 3720
DOI: 10.1021/ol5015398

A General Diversified Synthesis of Carbazoles and the First Synthesis of Karapinchamine A

Youai Qiu, Jing Zhou, Chunling Fu and Shengming Ma

Chemistry A European J, 2014, 20, 14589
DOI: 10.1002/chem.201404769

Palladium(II) tetrakis(4-N,N,N-trimethylammoniumphenylene)porphyrin supported on ion-exchange resins as efficient and reusable catalysts for C–C coupling reactions

Faranak Sadegh, Omid Bagheri, Majid Moghadam, Valiollah Mirkhani, Shahram Tangestaninejad and Iraj Mohammadpoor-Baltork

Journal of Organometallic Chemistry, 2014, 759, 46
DOI: 10.1016/j.jorganchem.2014.02.006

Facile synthesis of indoles by K 2 CO 3 catalyzed cyclization reaction of 2-ethynylanilines in water

Zhi Chen, Xiao-Xiao Shi, Dong-Qin Ge, Zhen-Zhen Jiang, Qi-Qi Jin, Hua-Jiang Jiang and Jia-Shou Wu

Chinese Chemical Letters, 2017, 28, 231
DOI: 10.1016/j.cclet.2016.07.022

Palladium‐Catalyzed C2−H Arylation of Unprotected (N−H)‐Indoles “On Water” Using Primary Diamantyl Phosphine Oxides as a Class of Primary Phosphine Oxide Ligands

Oana Moncea, Didier Poinsot, Andrey A. Fokin, Peter R. Schreiner and Jean‐Cyrille Hierso

ChemCatChem, 2018, 10, 2915
DOI: 10.1002/cctc.201800187

Palladium-catalyzed dual C–H or N–H functionalization of unfunctionalized indole derivatives with alkenes and arenes

Gianluigi Broggini, Egle M Beccalli, Andrea Fasana and Silvia Gazzola

Beilstein J. Org. Chem., 2012, 8, 1730
DOI: 10.3762/bjoc.8.198

Preparation of Functionalized Indoles and Azaindoles by the Intramolecular Copper‐Mediated Carbomagnesiation of Ynamides

Annette Frischmuth and Paul Knochel

Angew Chem Int Ed, 2013, 52, 10084
DOI: 10.1002/anie.201304380

Palladium-catalyzed synthesis of indoles via intramolecular Heck reaction

Hailong Yang, Peng Sun, Yan Zhu, Hong Yan, Linhua Lu, Defu Liu, Guangwei Rong and Jincheng Mao

Catalysis Communications, 2013, 38, 21
DOI: 10.1016/j.catcom.2013.04.001

Regioselective Access to 3-Aryl-1-aminoisoquinolines via Nickel(I)-Catalyzed C–C and C–N Cascade Coupling Reactions from the Substituted 2-(Cyanomethyl)benzonitriles

Xicheng Yang, Haihua Yu, Yulong Xu and Liming Shao

J. Org. Chem., 2018, 83, 9682
DOI: 10.1021/acs.joc.8b01159

Catalyst-Switchable Divergent Synthesis of Bis(indolyl)alkanes and 3-Alkylated Indoles from Styrene Oxides

Aparna Tyagi, Jabir Khan, Naveen Yadav, Rina Mahato and Chinmoy Kumar Hazra

J. Org. Chem., 2022, 87, 10229
DOI: 10.1021/acs.joc.2c01204

Efficient Synthesis of Helical Tetrasubstituted Alkenes as Potential Molecular Switches: A Two‐Component Palladium‐Catalyzed Triple Domino Process

Lutz F. Tietze, Tim Hungerland, Christoph Eichhorst, Alexander Düfert, Christian Maaß and Dietmar Stalke

Angew Chem Int Ed, 2013, 52, 3668
DOI: 10.1002/anie.201209510

A Joint Experimental–Computational Comparative Study of the Pd0‐Catalysed Reactions of Aryl Iodides and Aldehydes with N, O, and S Tethers

Daniel Solé, Francesco Mariani and Israel Fernández

Eur J Org Chem, 2015, 2015, 3935
DOI: 10.1002/ejoc.201500393

Unaromatized Tetrahydrobenzimidazole Synthesis from p‐Benzoquinone and N‐Arylamidines and their Cytotoxic Potential

Minh Quan Tran, Thanh Binh Nguyen, Wamtinga Richard Sawadogo, Ludmila Ermolenko, Sungmi Song, Pascal Retailleau, Marc Diederich and Ali Al‐Mourabit

Eur J Org Chem, 2018, 2018, 5878
DOI: 10.1002/ejoc.201801077

Synthesis of N‐Heteroaromatic Compounds through Cyclocarbonylative Sonogashira Reactions

Laura Antonella Aronica, Gianluigi Albano, Luca Giannotti and Elisa Meucci

Eur J Org Chem, 2017, 2017, 955
DOI: 10.1002/ejoc.201601392

Understanding the origin of reactivity, mechanism and regioselectivity of the [3+2] cycloaddition reaction between nitrile imine and pyrrolopyrazine

Houda Hamdaoui, Abdelmalek Khorief Nacereddine and Abdelhafid Djerourou

J of Physical Organic Chem, 2023, 36
DOI: 10.1002/poc.4462

Rhodium-Catalyzed Tandem Annulation and (5 + 1) Cycloaddition: 3-Hydroxy-1,4-enyne as the 5-Carbon Component

Xiaoxun Li, Wangze Song and Weiping Tang

J. Am. Chem. Soc., 2013, 135, 16797
DOI: 10.1021/ja408829y

Palladium on Carbon‐Catalyzed One‐Pot N‐Arylindole Synthesis: Intramolecular Aromatic Amination, Aromatization, and Intermolecular Aromatic Amination

Yasunari Monguchi, Takahisa Marumoto, Haruki Takamatsu, Yoshinari Sawama and Hironao Sajiki

Adv Synth Catal, 2014, 356, 1866
DOI: 10.1002/adsc.201301168

Catalytic α-Arylation of Imines Leading to N-Unprotected Indoles and Azaindoles

Enrico Marelli, Martin Corpet, Yury Minenkov, Rifahath M. Neyyappadath, Alessandro Bismuto, Giulia Buccolini, Massimiliano Curcio, Luigi Cavallo and Steven P. Nolan

ACS Catal., 2016, 6, 2930
DOI: 10.1021/acscatal.6b00040

Novel Non‐toxic and Non‐hazardous Solvent Systems for the Chemistry of Indoles: Use of a Sulfone‐containing Brønsted Acid Ionic Liquid Catalyst in Butyl Acetate

Ahmed El‐Harairy, Yiliqi, Meie Yue, Weigang Fan, Florence Popowycz, Yves Queneau, Minghao Li and Yanlong Gu

ChemCatChem, 2019, 11, 4403
DOI: 10.1002/cctc.201900784

Diazo Compounds as Electrophiles To React with 1,4-Dilithio-1,3-dienes: Efficient Synthesis of 1-Imino-pyrrole Derivatives

Ming Zhan, Shaoguang Zhang, Wen-Xiong Zhang and Zhenfeng Xi

Org. Lett., 2013, 15, 4182
DOI: 10.1021/ol401878q

Cascade synthesis of 3-aza-bicyclo[3.1.0]hex-2-ene derivatives from N-allyl enamines

Sheng-Xian Zhai, Hong-Ru Dong, Zi-Bao Chen, Yi-Ming Hu and Heng-Shan Dong

Tetrahedron, 2014, 70, 8405
DOI: 10.1016/j.tet.2014.08.043

Synthesis of N‐Heterocycles by Reductive Cyclization of Nitroalkenes Using Molybdenum Hexacarbonyl as Carbon Monoxide Surrogate

Zhiyou Su, Bo Liu, Hongze Liao and Hou‐Wen Lin

Eur J Org Chem, 2020, 2020, 4059
DOI: 10.1002/ejoc.202000580

Total Synthesis of Linoxepin through a Palladium‐Catalyzed Domino Reaction

Lutz F. Tietze, Svenia‐C. Duefert, Jérôme Clerc, Matthias Bischoff, Christian Maaß and Dietmar Stalke

Angewandte Chemie, 2013, 125, 3273
DOI: 10.1002/ange.201209868

Regioselective Synthesis of the Tetrahydrocarbazole Core of Akuammiline Alkaloids via Palladium-Catalyzed Intramolecular Arylation Reaction

Naga M. R. Vampugani, Ajay B. Shelke, Prashant B. Singh, Asrar Ahmad and Ajoy Kapat

J. Org. Chem., 2024, 89, 4461
DOI: 10.1021/acs.joc.3c02619

Metal‐Free Synthesis of Fluorinated Indoles Enabled by Oxidative Dearomatization

Edon Vitaku, David T. Smith and Jon T. Njardarson

Angew Chem Int Ed, 2016, 55, 2243
DOI: 10.1002/anie.201511149

Synthesis of Triazole, Indole, and Five or Six-Membered Saturated Heterocyclic Compounds

Hironao Sajiki, Yasunari Monguchi and Yoshinari Sawama

HETEROCYCLES, 2015, 91, 239
DOI: 10.3987/REV-14-811

Boron Trichloride‐Mediated Synthesis of Indoles via the Aminoboration of Alkynes

Jiahang Lv, Binlin Zhao, Li Liu, Ying Han, Yu Yuan and Zhuangzhi Shi

Adv Synth Catal, 2018, 360, 4054
DOI: 10.1002/adsc.201800509

Ligand and copper free Sonogashira coupling to achieve 2-alkynyl d-glucal derivatives: regioselective electrophile promoted nucleophilic 5-endo-dig cyclization

Anwar Shamim, Stanley N.S. Vasconcelos, Bakhat Ali, Lucas Sousa Madureira, J. Zukerman-Schpector and Hélio A. Stefani

Tetrahedron Letters, 2015, 56, 5836
DOI: 10.1016/j.tetlet.2015.08.052

Facile Synthesis of [1,2,3]Triazolo[5,1‐a]isoquinolines through a Copper‐Catalyzed Tandem Sonogashira Coupling/Cyclization Reaction

Mingzhu Fan, Yi Liu, Qinquan Hu, Lihui Jia and Yunfeng Chen

Eur J Org Chem, 2016, 2016, 5470
DOI: 10.1002/ejoc.201601188

Gold‐Catalyzed Cascade Cyclization of 2‐Alkynyl‐N‐Propargylanilines by Rearrangement of a Propargyl Group

Yusuke Tokimizu, Shinya Oishi, Nobutaka Fujii and Hiroaki Ohno

Angewandte Chemie, 2015, 127, 7973
DOI: 10.1002/ange.201502256

Aminofluorination of 2-alkynylanilines: a Au-catalyzed entry to fluorinated indoles

Antonio Arcadi, Emanuela Pietropaolo, Antonello Alvino and Véronique Michelet

Beilstein J. Org. Chem., 2014, 10, 449
DOI: 10.3762/bjoc.10.42

Divergent Reactivity of Rhodium(I) Carbenes Derived from Indole Annulations

Xiaoxun Li, Hui Li, Wangze Song, Po‐Sen Tseng, Lingyan Liu, Ilia A. Guzei and Weiping Tang

Angewandte Chemie, 2015, 127, 13097
DOI: 10.1002/ange.201505329

Er(OTf)3-catalyzed approach to 3-alkenylindoles through regioselective addition of ynamides and indoles

Yi-Wen Liu, Rui-Jun Ma, Qiao-E Wang, Chang-Mei Si and Bang-Guo Wei

Tetrahedron, 2020, 76, 131649
DOI: 10.1016/j.tet.2020.131649

An Eco‐Friendly Asymmetric Organocatalytic Conjugate Addition of Malonates to α,β‐Unsaturated Aldehydes: Application on the Synthesis of Chiral Indoles

Karla Santos Feu, Anna Maria Deobald, Senthil Narayanaperumal, Arlene G. Corrêa and Márcio Weber Paixão

Eur J Org Chem, 2013, 2013, 5917
DOI: 10.1002/ejoc.201300431

Catalytic C−H Functionalization of Unreactive Furan Cores in Bio‐Derived Platform Chemicals

Bogdan Y. Karlinskii and Valentine P. Ananikov

ChemSusChem, 2021, 14, 558
DOI: 10.1002/cssc.202002397

Synthesis of benzoheterocycles by palladium-catalyzed migratory cyclization through an unexpected reaction cascade

Wen-Cong Li, Lin Zhang, Shiming Bai, Jia-Hao Zhao, Guang-Rui Liu, Yu Lan, Shufeng Chen and Jialin Ming

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-58633-5

Precise Control of the Oriented Layered Double Hydroxide Nanosheets Growth on Graphene Oxides Leading to Efficient Catalysts for Cascade Reactions

Wei Zhang, Zelin Wang, Yufei Zhao, Haralampos N. Miras and Yu‐Fei Song

ChemCatChem, 2019, 11, 5466
DOI: 10.1002/cctc.201901208

Recent Advances in Transition Metal‐Catalyzed Domino‐Cyclization Strategies for Functionalized Heterocyclic/Carbocyclic Compounds

Rohit Kumar Maurya, Deepika Sharma, Suruchi Kumari, Rana Chatterjee, Mahender Khatravath and Rambabu Dandela

ChemistrySelect, 2022, 7
DOI: 10.1002/slct.202201408

Metal‐Catalyzed Synthesis of Substituted Indoles

So Won Youn and Tae Yun Ko

Asian J Org Chem, 2018, 7, 1467
DOI: 10.1002/ajoc.201800290

Cyclic Anti-Azacarboxylation of 2-Alkynylanilines with Carbon Dioxide

Bukeyan Miao, Suhua Li, Gen Li and Shengming Ma

Org. Lett., 2016, 18, 2556
DOI: 10.1021/acs.orglett.6b00884

A Streamlined Approach to Indoles, Pyrroles, and Benzimidazoles via Redox‐Neutral Aromatization and CO Reduction Mediated by Cs2CO3

Jingyi Bai, Tianbao Wu, Ben Dong, Jiawei Ma, Yong Liang, Minyan Wang and Zhuangzhi Shi

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202511725

Ruthenium-Catalyzed, Site-Selective C–H Allylation of Indoles with Allyl Alcohols as Coupling Partners

Gangam Srikanth Kumar and Manmohan Kapur

Org. Lett., 2016, 18, 1112
DOI: 10.1021/acs.orglett.6b00217

A Palladium-Catalyzed Domino Reaction To Access 3-Amino-2H-indazoles from Hydrazines and 2-Halobenzonitriles

Rana Alsalim, Peter Lindemann, María Pascual López-Alberca, Sandra Miksche, Werngard Czechtizky, Nis Halland and Marc Nazaré

Org. Lett., 2020, 22, 7393
DOI: 10.1021/acs.orglett.0c02766

Active and Recyclable Catalytic Synthesis of Indoles by Reductive Cyclization of 2-(2-Nitroaryl)acetonitriles in the Presence of Co–Rh Heterobimetallic Nanoparticles with Atmospheric Hydrogen under Mild Conditions

Isaac Choi, Hyunho Chung, Jang Won Park and Young Keun Chung

Org. Lett., 2016, 18, 5508
DOI: 10.1021/acs.orglett.6b02659

Organonitrogen Chemicals from Oxygen-Containing Feedstock over Heterogeneous Catalysts

Yunzhu Wang, Shinya Furukawa, Xinpu Fu and Ning Yan

ACS Catal., 2020, 10, 311
DOI: 10.1021/acscatal.9b03744

Cu(I)-Catalyzed Atropselective Heterobiaryl Coupling Employing Umpoled Indoles

Nguyen H. Nguyen, Sanghyup Seo, Jiwon Jang, Hyunwoo Kim and Seunghoon Shin

Org. Lett., 2024, 26, 7149
DOI: 10.1021/acs.orglett.4c02482

Palladium-Catalyzed Tandem Reaction of Three Aryl Iodides Involving Triple C–H Activation

Xiai Luo, Yankun Xu, Genhua Xiao, Wenjuan Liu, Cheng Qian, Guobo Deng, Jianxin Song, Yun Liang and Chunming Yang

Org. Lett., 2018, 20, 2997
DOI: 10.1021/acs.orglett.8b00982

General and efficient synthesis of polyfluorinated 2-aminotolans and 2-arylindoles

Larisa V. Politanskaya, Vitalij D. Shteingarts and Evgeny V. Tretyakov

Journal of Fluorine Chemistry, 2016, 188, 85
DOI: 10.1016/j.jfluchem.2016.06.010

Intermolecular Domino Reaction of Two Aryl Iodides Involving Two CH Functionalizations

Marcel Sickert, Harald Weinstabl, Brendan Peters, Xiao Hou and Mark Lautens

Angewandte Chemie, 2014, 126, 5247
DOI: 10.1002/ange.201400807

Divergent Reactivity of Rhodium(I) Carbenes Derived from Indole Annulations

Xiaoxun Li, Hui Li, Wangze Song, Po‐Sen Tseng, Lingyan Liu, Ilia A. Guzei and Weiping Tang

Angew Chem Int Ed, 2015, 54, 12905
DOI: 10.1002/anie.201505329

PdI2 as a Simple and Efficient Catalyst for the Hydroamination of Arylacetylenes with Anilines

Alessandra Casnati, Aleksandr Voronov, Damiano Giuseppe Ferrari, Raffaella Mancuso, Bartolo Gabriele, Elena Motti and Nicola Della Ca’

Catalysts, 2020, 10, 176
DOI: 10.3390/catal10020176

Recent advances in biocatalysis of nitrogen-containing heterocycles

Jing Feng, Wen-Chao Geng, Huifeng Jiang and Bian Wu

Biotechnology Advances, 2022, 54, 107813
DOI: 10.1016/j.biotechadv.2021.107813

Copper‐Catalyzed Sequential C(sp2)/C(sp3)−H Amination of 2‐Vinylanilines with N‐Fluorobenzenesulfonimide

Wen‐Bin Cao, Xiao‐Ping Xu and Shun‐Jun Ji

Adv Synth Catal, 2019, 361, 1771
DOI: 10.1002/adsc.201801710

Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation

M. Alexander Düfert, Kelvin L. Billingsley and Stephen L. Buchwald

J. Am. Chem. Soc., 2013, 135, 12877
DOI: 10.1021/ja4064469

Indole derivative XCR-5a alleviates LPS-induced inflammation in vitro and in vivo

Jiajing Zhao, Prasanta Roy, Haimei Tang, Xingyu Ma, Qianqian Di, Jiazheng Quan, Yonghong Guan, Xiaoli Li, Weilie Xiao and Weilin Chen

Immunopharmacology and Immunotoxicology, 2022, 44, 157
DOI: 10.1080/08923973.2021.2020284

Efficient synthesis of indoles from 2-alkynylaniline derivatives in water using a recyclable copper catalyst system

Senchuan Song, Manna Huang, Wenjun Li, Xinhai Zhu and Yiqian Wan

Tetrahedron, 2015, 71, 451
DOI: 10.1016/j.tet.2014.12.007

Nickel-Catalyzed Annulation of Alkynyl with Trifluoroacetimidoyl Chlorides and H2O: Facile Access to 2‑(Trifluoromethyl)indole Derivatives

Yu Sun, Yantao Zhu, Dong Zhang and Chunjie Ni

Chinese Journal of Organic Chemistry, 2026, 46, 1017
DOI: 10.6023/cjoc202508002

Computational study of Ru-catalyzed cycloisomerization of 2-alkynylanilides

Xinghui Zhang, Shanshan Li, Xiaoli Wei and Yun Lei

J Mol Model, 2018, 24
DOI: 10.1007/s00894-018-3707-7

Environmentally friendly and regioselective C3-alkylation of indoles with alcohols through a hydrogen autotransfer strategy

Rafael Cano, Miguel Yus and Diego J. Ramón

Tetrahedron Letters, 2013, 54, 3394
DOI: 10.1016/j.tetlet.2013.04.062

Carbon‐Carbon and Carbon‐Heteroatom Bond Formation Reactions Using Unsaturated Carbon Compounds

Shaista Sultan and Bhahwal Ali Shah

The Chemical Record, 2019, 19, 644
DOI: 10.1002/tcr.201800095

Cu-Mediated Tandem 2,3-Disubstituted Indole Synthesis from Simple Anilines and Internal Alkynes via C–H Annulation

Prafull A. Jagtap, Manjunath S. Lokolkar and Bhalchandra M. Bhanage

J. Org. Chem., 2023, 88, 10960
DOI: 10.1021/acs.joc.3c00954

Synthesis of 2-Sulfenylindoles via Palladium-Catalyzed Thiolative Annulation of Ynamides

Illia Lenko, Oumaima Mhadhbi, Jean-François Lohier, Carole Alayrac and Bernhard Witulski

Org. Lett., 2025, 27, 8781
DOI: 10.1021/acs.orglett.5c02770

Copper-catalyzed Conjugate Addition of Organoboronic Acids and Esters to Electron-Deficient Alkynes

Yoshihiko Yamamoto

J. Synth. Org. Chem. Jpn., 2013, 71, 296
DOI: 10.5059/yukigoseikyokaishi.71.296

Investigation and Application of Amphoteric α-Amino Aldehyde: An in Situ Generated Species Based on Heyns Rearrangement

Guangxun Li, Ling Tang, Hongxin Liu, Yingwei Wang, Gang Zhao and Zhuo Tang

Org. Lett., 2016, 18, 4526
DOI: 10.1021/acs.orglett.6b02133

Unexpected straightforward formation of trifluoromethylated pyrido[2,3- d ]pyrimidine derivatives via one-pot, MCRs

Yang Wang, Lu Zhou, Yingjun Zhu, Min Zhang, Liping Song and Hongmei Deng

Journal of Fluorine Chemistry, 2017, 200, 162
DOI: 10.1016/j.jfluchem.2017.06.016

One-Pot Synthesis of Indoles by a Sequential Ugi-3CR/Wittig Reaction Starting from Odorless Isocyanide-Substituted Phosphonium Salts

Yan-Mei Yan, Yong Rao and Ming-Wu Ding

J. Org. Chem., 2017, 82, 2772
DOI: 10.1021/acs.joc.7b00004

Cascade Synthesis of 3-Alkylidene Dihydrobenzofuran Derivatives via Rhodium(III)-Catalyzed Redox-Neutral C–H Functionalization/Cyclization

Zhi Zhou, Guixia Liu, Yan Chen and Xiyan Lu

Org. Lett., 2015, 17, 5874
DOI: 10.1021/acs.orglett.5b03060

Gold‐Catalyzed Cascade Cyclization of 2‐Alkynyl‐N‐Propargylanilines by Rearrangement of a Propargyl Group

Yusuke Tokimizu, Shinya Oishi, Nobutaka Fujii and Hiroaki Ohno

Angew Chem Int Ed, 2015, 54, 7862
DOI: 10.1002/anie.201502256

Microwave-assisted synthesis – Catalytic applications in aqueous media

Anuj K. Rathi, Manoj B. Gawande, Radek Zboril and Rajender S. Varma

Coordination Chemistry Reviews, 2015, 291, 68
DOI: 10.1016/j.ccr.2015.01.011

Enantioselective Synthesis of Indole-Fused Bicyclo[3.2.1]octanes via Palladium(II)-Catalyzed Cascade Reaction

Gang Wang, Jin-Chen Li, Yong-Gui Zhou and Zhi-Shi Ye

Org. Lett., 2021, 23, 802
DOI: 10.1021/acs.orglett.0c04030

Pd immobilized on EDTA-modified cellulose: synthesis, characterization, and catalytic application in inter- and intramolecular Heck reactions and Larock reactions

Zhian Xu, Jinxi Xu, Yuping Zhou, Yuling Huang and Yiqun Li

Res Chem Intermed, 2022, 48, 3475
DOI: 10.1007/s11164-022-04766-x

Iridium/Acid Cocatalyzed Direct Access to Fused Indoles via Transfer Hydrogenative Annulation of Quinolines and 1,2-Diketones

Guangpeng Lu, Feng Xie, Rong Xie, Huanfeng Jiang and Min Zhang

Org. Lett., 2020, 22, 2308
DOI: 10.1021/acs.orglett.0c00500

A theoretical investigation on palladium-catalyzed one-pot coupling of aryl iodides, alkynes, and amines through CN bond cleavage for the synthesis of indole derivatives

Nan Lu and Huatian Wang

Int. J. Quantum Chem., 2015, 115, 361
DOI: 10.1002/qua.24842

Rh-Catalyzed C–H Alkynylation of Indole Derivatives with Silver(I)-Controlled Regiodivergence

Yaokun Zhao, Xingchi Li, Pengfei Zhou, Xing Han, Chenjie Zhang, Taoyuan Liang, Shuangliang Zhao and Zhuan Zhang

Org. Lett., 2024, 26, 7285
DOI: 10.1021/acs.orglett.4c02151

Enantioselective Total Synthesis of (−)‐Blennolide A

Lutz F. Tietze, Ling Ma, Johannes R. Reiner, Stefan Jackenkroll and Sven Heidemann

Chemistry A European J, 2013, 19, 8610
DOI: 10.1002/chem.201300479

Indole synthesis through transition metal-catalyzed C–H activation

Tenglong Guo, Fei Huang, Likun Yu and Zhengkun Yu

Tetrahedron Letters, 2015, 56, 296
DOI: 10.1016/j.tetlet.2014.11.114

A new synthetic approach to pyrrolo[3,2- b ]indoles via regioselective formation of pyrrole and intramolecular C N coupling

Manjusha V. Karkhelikar, Vijay V. Rao, Sundar S. Shinde and Pravin R. Likhar

Tetrahedron Letters, 2016, 57, 4803
DOI: 10.1016/j.tetlet.2016.09.044

Rhodium-Catalyzed Regioselective Synthesis of N-Secondary Alkyl Indoles via Intermolecular Cyclization of N-Nitrosoanilines and Unsymmetrical Alkynes

Yiting Chang, Tingting Hou, Yi Dong and Heng Xu

Synthesis, 2023, 55, 3969
DOI: 10.1055/s-0041-1738453

Gold‐Catalyzed Functionalization Reactions of Indole

Valentina Pirovano

Eur J Org Chem, 2018, 2018, 1925
DOI: 10.1002/ejoc.201800125

Copper-Catalyzed (4+1) Cascade Annulation of Terminal Alkynes with 2-(Tosylmethyl)anilines: Synthesis of 2,3-Disubstituted Indoles

Xu Yan, Chun-Fang Liu, Xian-Tao An, Xiao-Min Ge, Qing Zhang, Lin-Han Pang, Xu Bao and Chun-An Fan

Org. Lett., 2021, 23, 8905
DOI: 10.1021/acs.orglett.1c03402

Elemental Sulfur‐Promoted [2+3+1] Annulation for Synthesis of Functionalized Thiochromeno[2,3‐b]indoles from Indole Derivatives

Jianming Liu, Zhixian Wang, Ke Wang, Dong Liu, Yan Yang, Junjun Fan, Kelei Zhuo and Yuanyuan Yue

Asian J Org Chem, 2020, 9, 929
DOI: 10.1002/ajoc.202000159

One-Pot Synthesis of Indole-3-acetic Acid Derivatives through the Cascade Tsuji–Trost Reaction and Heck Coupling

Dongsheng Chen, Yuanyuan Chen, Zhilong Ma, Lei Zou, Jianqi Li and Yu Liu

J. Org. Chem., 2018, 83, 6805
DOI: 10.1021/acs.joc.8b01056

A Mild Two-Step Synthesis of Structurally Valuable Indole-Fused Derivatives

Shanping Chen, Yi Xia, Shikai Jin, Hanwen Lei, Kuiyi You and Guo-Jun Deng

J. Org. Chem., 2022, 87, 3212
DOI: 10.1021/acs.joc.1c02927

A Domino Approach to the Enantioselective Total Syntheses of Blennolide C and Gonytolide C

Lutz F. Tietze, Stefan Jackenkroll, Judith Hierold, Ling Ma and Bernd Waldecker

Chemistry A European J, 2014, 20, 8628
DOI: 10.1002/chem.201402495

Synthesis and Reactions of 3-Halogenated 2-CF3-Indoles

Vasiliy M. Muzalevskiy, Zoia A. Sizova and Valentine G. Nenajdenko

Molecules, 2022, 27, 8822
DOI: 10.3390/molecules27248822

Copper-Catalyzed Three-Component Tandem Cyclization for One-Pot Synthesis of Indole-Benzofuran Bis-Heterocycles

Peng Ma, Yuhang Wang and Jianhui Wang

J. Org. Chem., 2024, 89, 17168
DOI: 10.1021/acs.joc.4c01680

Supported dual‐acidic 1,3‐disulfoimidazolium chlorozincate@HZSM‐5 as a promising heterogeneous catalyst for synthesis of indole derivatives

Susmita Saikia, Krishna Puri and Ruli Borah

Applied Organom Chemis, 2019, 33
DOI: 10.1002/aoc.4672

Application of Palladium Based Precatalytic Systems in the Suzuki‐Miyaura Cross‐Coupling Reactions of Chloro‐ Heterocycles

Savitha Bhaskaran, M. Syed Ali Padusha and Ayyiliath M Sajith

ChemistrySelect, 2020, 5, 9005
DOI: 10.1002/slct.202002357

Chemicals from Alkynes with Palladium Catalysts

Rafael Chinchilla and Carmen Nájera

Chem. Rev., 2014, 114, 1783
DOI: 10.1021/cr400133p

Synthesis of Fused Carbazoles by Gold-Catalyzed Tricyclization of Conjugated Diynes via Rearrangement of an N-Propargyl Group

Masamitsu Taguchi, Yusuke Tokimizu, Shinya Oishi, Nobutaka Fujii and Hiroaki Ohno

Org. Lett., 2015, 17, 6250
DOI: 10.1021/acs.orglett.5b03254

The Barbier‐Type Allylation/Lactamization Cascade Route to Isoindolinones and the Heck‐Type Annulation Route to Isoindolo[2,1‐a]quinolines

Chennakesava Reddy, Srinivasarao Arulananda Babu and Rayavarapu Padmavathi

ChemistrySelect, 2016, 1, 2952
DOI: 10.1002/slct.201600411

Platinum-Catalyzed Tandem Indole Annulation/Arylation for the Synthesis of Diindolylmethanes and Indolo[3,2-b]carbazoles

Dongxu Shu, Gabrielle N. Winston-McPherson, Wangze Song and Weiping Tang

Org. Lett., 2013, 15, 4162
DOI: 10.1021/ol4018408

Brønsted Acid-Promoted Multicomponent Reaction for the Construction of Pyrrolocoumarin Derivatives

Zhiwei Chen, Sunjia Ye and Xiongfei Zhang

HETEROCYCLES, 2018, 96, 501
DOI: 10.3987/COM-18-13867

Pd-Catalyzed Intramolecular Cyclization via Direct C–H Addition to Nitriles: Skeletal Diverse Synthesis of Fused Polycyclic Indoles

Ting-Ting Wang, Lang Zhao, Yan-Jing Zhang and Wei-Wei Liao

Org. Lett., 2016, 18, 5002
DOI: 10.1021/acs.orglett.6b02460

Modular and Regioselective Synthesis of Benzo-Fused Five-Membered Rings Enabled by Co/Ti Synergism

Xiao-Di Ma, Fang-Yuan Ma, Miao-Miao Jiao, Jun-Ting Li and Xin-Fang Duan

Org. Lett., 2024, 26, 6658
DOI: 10.1021/acs.orglett.4c02336

Total Synthesis of (−)-Herbindoles A, B, and C and (+)-trans-Herbindole A via a Convergent Benzannulation Strategy

Nathan H. Faialaga and Rick L. Danheiser

J. Org. Chem., 2025, 90, 6844
DOI: 10.1021/acs.joc.5c00653

2,2,2‐Trifluoroethanol‐mediated hydroarylation of fluorinated alkynes with indoles: Application to diindolylmethanes

Philipp Flury, Olga Eppler, Dieter Schollmeyer, Stefan Laufer and Thanigaimalai Pillaiyar

Archiv der Pharmazie, 2022, 355
DOI: 10.1002/ardp.202100488

Bicyclization of Isocyanides with Alkenoyl Bis(ketene dithioacetals): Access to 6,7-Dihydro-1H-indol-4(5H)-ones

Yifei Li, Xianxiu Xu, Hui Shi, Ling Pan and Qun Liu

J. Org. Chem., 2014, 79, 5929
DOI: 10.1021/jo500928c

Synthesis of Polycyclic Indolines by Utilizing a Reduction/Cyclization Cascade Reaction

Jingyu Zhang, Wei Xia, Meilin Qu, Saskia Huda, Jas S. Ward, Kari Rissanen and Markus Albrecht

Eur J Org Chem, 2021, 2021, 6097
DOI: 10.1002/ejoc.202101191

A Streamlined Approach to Indoles, Pyrroles, and Benzimidazoles via Redox‐Neutral Aromatization and CO Reduction Mediated by Cs2CO3

Jingyi Bai, Tianbao Wu, Ben Dong, Jiawei Ma, Yong Liang, Minyan Wang and Zhuangzhi Shi

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202511725

Recent Progress in the Transition Metal Catalyzed Synthesis of Indoles

Raffaella Mancuso and Renato Dalpozzo

Catalysts, 2018, 8, 458
DOI: 10.3390/catal8100458

From Alcohols to Indoles: A Tandem Ru Catalyzed Hydrogen-Transfer Fischer Indole Synthesis

Andrea Porcheddu, Manuel G. Mura, Lidia De Luca, Marianna Pizzetti and Maurizio Taddei

Org. Lett., 2012, 14, 6112
DOI: 10.1021/ol3030956

Rhodium-Catalyzed Selective Nucleophilic Cyclization/Cross-Coupling of Two ortho-Alkynylanilines Bearing Differential N-Substituents

Jin-Chen Li, Bing-Xia Yan, Gang Wang and Zhi-Shi Ye

Org. Lett., 2023, 25, 5890
DOI: 10.1021/acs.orglett.3c02180

Tandem One-Pot Synthesis of Polysubstituted NH-Pyrroles Involving the Palladium-Catalyzed Intramolecular Oxidative Amination of the Zinc Bromide Complex of β-Enamino Esters

Ju Hyun Kim, Suh Young Choi, Jean Bouffard and Sang-gi Lee

J. Org. Chem., 2014, 79, 9253
DOI: 10.1021/jo501672c

Palladium‐catalyzed cyclization of 2‐alkynyl‐N‐ethanoyl anilines to indoles: synthesis, structural, spectroscopic, and mechanistic study

Mohammad Mazharol Hoque, Mohammad A. Halim, Mohammed G. Sarwar and Md. Wahab Khan

J of Physical Organic Chem, 2015, 28, 732
DOI: 10.1002/poc.3477

Synthesis of N-aroyl-2-arylindoles using solid calcium carbide as an alkyne source instead of gaseous acetylene

Qian Wang and Zheng Li

Tetrahedron, 2023, 142, 133548
DOI: 10.1016/j.tet.2023.133548

A Copper‐Catalyzed Decarboxylative Amination/Hydroamination Sequence: Switchable Synthesis of Functionalized Indoles

Tian‐Ren Li, Bei‐Yi Cheng, Ya‐Ni Wang, Mao‐Mao Zhang, Liang‐Qiu Lu and Wen‐Jing Xiao

Angewandte Chemie, 2016, 128, 12610
DOI: 10.1002/ange.201605900

An Unprecedented Pd‐Catalyzed Carbonylative Route to Fused Furo[3,4‐b]indol‐1‐ones

Alessandra Acerbi, Carla Carfagna, Mirco Costa, Raffaella Mancuso, Bartolo Gabriele and Nicola Della Ca'

Chemistry A European J, 2018, 24, 4835
DOI: 10.1002/chem.201706067

Recent Advances in Stetter Reaction and Related Chemistry: An update

Majid M. Heravi, Vahideh Zadsirjan, Kosar Kafshdarzadeh and Zahra Amiri

Asian J Org Chem, 2020, 9, 1999
DOI: 10.1002/ajoc.202000378

Metal‐Free Synthesis of Fluorinated Indoles Enabled by Oxidative Dearomatization

Edon Vitaku, David T. Smith and Jon T. Njardarson

Angewandte Chemie, 2016, 128, 2283
DOI: 10.1002/ange.201511149

A Journey in the Chemistry of Ynamides: From Synthesis to Applications

Gwilherm Evano, Nicolas Blanchard, Guillaume Compain, Alexis Coste, Charles S. Demmer, Wafa Gati, Céline Guissart, Jérémy Heimburger, Nicolas Henry, Kévin Jouvin, Ganesan Karthikeyan, Anouar Laouiti, Morgan Lecomte, Agnès Martin-Mingot, Benoît Métayer, Bastien Michelet, Antoine Nitelet, Cédric Theunissen, Sébastien Thibaudeau, Jianjun Wang, Maxence Zarca and Chunyang Zhang

Chem. Lett., 2016, 45, 574
DOI: 10.1246/cl.160260

Application of the Palladium‐Catalysed Norbornene‐Assisted Catellani Reaction Towards the Total Synthesis of (+)‐Linoxepin and Isolinoxepin

Zafar Qureshi, Harald Weinstabl, Marcel Suhartono, Hongqiang Liu, Pierre Thesmar and Mark Lautens

Eur J Org Chem, 2014, 2014, 4053
DOI: 10.1002/ejoc.201402218

Total Synthesis of (+)‐Linoxepin by Utilizing the Catellani Reaction

Harald Weinstabl, Marcel Suhartono, Zafar Qureshi and Mark Lautens

Angewandte Chemie, 2013, 125, 5413
DOI: 10.1002/ange.201302327