Bidraha Bagh, Daniël L. J. Broere, Vivek Sinha, Petrus F. Kuijpers, Nicolaas P. van Leest, Bas de Bruin, Serhiy Demeshko, Maxime A. Siegler and Jarl Ivar van der Vlugt

J. Am. Chem. Soc., 2017, 139, 5117
DOI: 10.1021/jacs.7b00270

Vicinal Diamination of Alkenes under Rh-Catalysis

David E. Olson, Justin Y. Su, D. Allen Roberts and J. Du Bois

J. Am. Chem. Soc., 2014, 136, 13506
DOI: 10.1021/ja506532h

Cobalt(II)-Catalyzed C–H and N–H Functionalization of 1-Arylpyrazolidinones with Dioxazolones as Bifunctional Synthons

Xiliang Han, Chao Pi, Di Hu, Wei Hu, Yangjie Wu and Xiuling Cui

Org. Lett., 2022, 24, 4650
DOI: 10.1021/acs.orglett.2c01780

The Quest for Palladium‐Catalysed Alkyl–Nitrogen Bond Formation

Kilian Muñiz, Claudio Martínez and Álvaro Iglesias

The Chemical Record, 2016, 16, 2561
DOI: 10.1002/tcr.201600073

Pd-Catalyzed Regioselective Intramolecular Allylic C–H Amination of 1,1-Disubstituted Alkenyl Amines

Young Ho Kim, Dong Bin Kim, Su San Jang and So Won Youn

J. Org. Chem., 2022, 87, 7574
DOI: 10.1021/acs.joc.2c00781

Direct synthesis of α-ketothioamides from aryl methyl ketones and amines via I2-promoted sp3 C–H functionalization

Hong-Zheng Li, Wei-Jian Xue and An-Xin Wu

Tetrahedron, 2014, 70, 4645
DOI: 10.1016/j.tet.2014.05.045

Intermolecular C(sp3)−H Amination Promoted by Internal Oxidants: Synthesis of Trifluoroacetylated Hydrazones

Chuanle Zhu, Hao Zeng, Fulin Chen, Zhiyi Yang, Yingying Cai and Huanfeng Jiang

Angewandte Chemie, 2018, 130, 17461
DOI: 10.1002/ange.201810502

Formal Direct Cross‐Coupling of Phenols with Amines

Zhengwang Chen, Huiying Zeng, Simon A. Girard, Feng Wang, Ning Chen and Chao‐Jun Li

Angew Chem Int Ed, 2015, 54, 14487
DOI: 10.1002/anie.201506751

Palladiumkatalysierte intermolekulare C‐H‐Amidierung von C(sp3)‐Gruppen

Álvaro Iglesias, Rosana Álvarez, Ángel R. de Lera and Kilian Muñiz

Angewandte Chemie, 2012, 124, 2268
DOI: 10.1002/ange.201108351

Palladium catalyzed oxidative aminations and oxylations: where are we?

Mélanie M. Lorion, Julie Oble and Giovanni Poli

Pure and Applied Chemistry, 2016, 88, 381
DOI: 10.1515/pac-2015-1102

Formal Direct Cross‐Coupling of Phenols with Amines

Zhengwang Chen, Huiying Zeng, Simon A. Girard, Feng Wang, Ning Chen and Chao‐Jun Li

Angewandte Chemie, 2015, 127, 14695
DOI: 10.1002/ange.201506751

Sulfur-directed metal-free and regiospecific methyl C(sp 3 )–H imidation of thioanisoles

Zhanhui Yang, Shiyi Yang and Jiaxi Xu

Tetrahedron, 2017, 73, 3240
DOI: 10.1016/j.tet.2017.04.054

Photochemical C−H Amination of Ethers and Geminal Difunctionalization Reactions in One Pot

Daniel Hernández‐Guerra, Anna Hlavačková, Chiranan Pramthaisong, Ilaria Vespoli, Radek Pohl, Tomáš Slanina and Ullrich Jahn

Angewandte Chemie, 2019, 131, 12570
DOI: 10.1002/ange.201905209

Copper-Catalyzed sp3 C–H Aminative Cyclization of 2-Alkyl-N-arylbenzamides: An Approach for the Synthesis of N-Aryl-isoindolinones

Kanako Nozawa-Kumada, Jun Kadokawa, Takehiro Kameyama and Yoshinori Kondo

Org. Lett., 2015, 17, 4479
DOI: 10.1021/acs.orglett.5b02235

Boryl-Dictated Site-Selective Intermolecular Allylic and Propargylic C–H Amination

Yuan Liu, Zhi-Hao Chen, Yin Li, Jiasheng Qian, Qingjiang Li and Honggen Wang

J. Am. Chem. Soc., 2022, 144, 14380
DOI: 10.1021/jacs.2c06117

A Short Asymmetric Synthesis of Octahydroindole Derivatives by Application of Catalytic C(sp3)–H Amination Reaction

Marie Mazurais, Camille Lescot, Pascal Retailleau and Philippe Dauban

Eur J Org Chem, 2014, 2014, 66
DOI: 10.1002/ejoc.201301174

Terminal Imido Rhodium Complexes

Ana M. Geer, Cristina Tejel, José A. López and Miguel A. Ciriano

Angew Chem Int Ed, 2014, 53, 5614
DOI: 10.1002/anie.201400023

Rhenium‐Catalyzed Oxidative Cyanation of Tertiary Amines with TMSCN

Aijun Lin, Hao Peng, Ablimit Abdukader and Chengjian Zhu

Eur J Org Chem, 2013, 2013, 7286
DOI: 10.1002/ejoc.201301140

Domino C–N Bond Formation via a Palladacycle with Diaziridinone. An Approach to Indolo[3,2-b]indoles

Sudarshan Debnath, Lingli Liang, Mei Lu and Yian Shi

Org. Lett., 2021, 23, 3237
DOI: 10.1021/acs.orglett.1c00466

Photocatalytic Radical Sulfonamidation/Cyclization Cascade Towards Sulfonaminated Dihydrofurans and Dihydroisoxazoles

Zhichao Chen, Yuqiong Sheng, Qianwen Mou, Xiaolan Xie and Fengjiao Lv

Adv Synth Catal, 2025, 367
DOI: 10.1002/adsc.202401359

Regio‐ and Stereoselective Synthesis of Tetrasubstituted Alkenes via Ruthenium(II)‐Catalyzed C–H Alkenylation/Directing Group Migration

Hui Mao, Jing Chen, Xiaoning Zhang, Na Yu, Yangbin Lu and Fei Zhao

ChemistrySelect, 2022, 7
DOI: 10.1002/slct.202200292

Temperature‐Controlled Divergent Synthesis of Tetrasubstituted Alkenes and Pyrrolo[1,2‐a]indole Derivatives via Iridium Catalysis

Siyu Liu, Hui Mao, Jin Qiao, Xiaoning Zhang, Yangbin Lu, Xin Gong, Aiqiong Jia, Linghui Gu, Xiaowei Wu and Fei Zhao

Asian J Org Chem, 2021, 10, 3308
DOI: 10.1002/ajoc.202100476

Copper-Catalyzed Electrochemical C–H Amination of Arenes with Secondary Amines

Qi-Liang Yang, Xiang-Yang Wang, Jia-Yan Lu, Li-Pu Zhang, Ping Fang and Tian-Sheng Mei

J. Am. Chem. Soc., 2018, 140, 11487
DOI: 10.1021/jacs.8b07380

Iron‐Catalyzed Reductive Allylic C─H Amination of Olefin with Nitroarenes via Intermolecular Nitroso Ene Reaction

Shaolong Qi, Duren Yin, Lingfei Hu, Changqin Huang, Ruyu Xie, Gang Lu and Jianchun Wang

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202504750

Copper-Catalyzed Oxidative C–H Amination of Tetrahydrofuran with Indole/Carbazole Derivatives

Qingjing Yang, Pui Ying Choy, Wai Chung Fu, Baomin Fan and Fuk Yee Kwong

J. Org. Chem., 2015, 80, 11193
DOI: 10.1021/acs.joc.5b01990

Fe-Catalyzed C(sp3)–H Diversification toward γ-Functionalized Amides via Iron Nitrenoid: Mechanistic Insights and Applications

Yanjun Wan, Emmanuel Ramírez, Ayzia Ford, Vanessa Bustamante and Gang Li

ACS Catal., 2023, 13, 14023
DOI: 10.1021/acscatal.3c03679

Reactions in Water – A Greener Approach Using Ruthenium Catalysts

Sanchari Shome and Surya Prakash Singh

The Chemical Record, 2019, 19, 1935
DOI: 10.1002/tcr.201800142

Copper-Catalyzed Oxidative Amination of sp3C–H Bonds under Air: Synthesis of 1,3-Diarylated Imidazo[1,5-a]pyridines

Huiqiao Wang, Wentao Xu, Zhiqiang Wang, Lintao Yu and Kun Xu

J. Org. Chem., 2015, 80, 2431
DOI: 10.1021/jo5027723

Mechanistic Study of the Direct Intramolecular Allylic Amination Reaction Catalyzed by Palladium(II)

Filipe J. S. Duarte, Giovanni Poli and Maria José Calhorda

ACS Catal., 2016, 6, 1772
DOI: 10.1021/acscatal.5b02091

β-Diketiminato Nickel Imides in Catalytic Nitrene Transfer to Isocyanides

Stefan Wiese, Mae Joanne B. Aguila, Elzbieta Kogut and Timothy H. Warren

Organometallics, 2013, 32, 2300
DOI: 10.1021/om300909n

Mechanistic and Kinetic Studies of the Direct Alkylation of Benzylic Amines: A Formal C(sp3)–H Activation Proceeds Actually via a C(sp2)–H Activation Pathway

Robert Pollice, Navid Dastbaravardeh, Nada Marquise, Marko D. Mihovilovic and Michael Schnürch

ACS Catal., 2015, 5, 587
DOI: 10.1021/cs501924c

Auxiliary-Assisted Palladium-Catalyzed Direct C(sp3)–H Sulfonamidation To Afford 1,2-Amino Alcohol Derivatives

Yi Dong and Gang Liu

J. Org. Chem., 2017, 82, 3864
DOI: 10.1021/acs.joc.6b02975

Metalloradical approach for concurrent control in intermolecular radical allylic C−H amination

Pan Xu, Jingjing Xie, Duo-Sheng Wang and X. Peter Zhang

Nat. Chem., 2023, 15, 498
DOI: 10.1038/s41557-022-01119-4

Inverting Steric Effects: Using “Attractive” Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer

Minxue Huang, Tzuhsiung Yang, Jonathan D. Paretsky, John F. Berry and Jennifer M. Schomaker

J. Am. Chem. Soc., 2017, 139, 17376
DOI: 10.1021/jacs.7b07619

Redox-Neutral Rhodium(III)-Catalyzed Chemospecific and Regiospecific [4+1] Annulation between Indoles and Alkenes for the Synthesis of Functionalized Imidazo[1,5-a]indoles

Fei Zhao, Jin Qiao, Yangbin Lu, Xiaoning Zhang, Long Dai, Siyu Liu, Hangcheng Ni, Xiuwen Jia, Xiaowei Wu and Shiyao Lu

J. Org. Chem., 2021, 86, 10591
DOI: 10.1021/acs.joc.1c01256

Catalytic CH Amination with Aromatic Amines

Raymond T. Gephart, Daria L. Huang, Mae Joanne B. Aguila, Graham Schmidt, Andi Shahu and Timothy H. Warren

Angewandte Chemie, 2012, 124, 6594
DOI: 10.1002/ange.201201921

Palladium‐Catalyzed Branch‐ and Z‐Selective Allylic C−H Amination with Aromatic Amines

Rui Liu, Meng‐Lan Shen, Lian‐Feng Fan, Xiao‐Le Zhou, Pu‐Sheng Wang and Liu‐Zhu Gong

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202211631

Iron-Catalyzed Intramolecular C–H Amination of α-Azidyl Amides

Xiaopeng Zhao, Siyu Liang, Xing Fan, Tonghao Yang and Wei Yu

Org. Lett., 2019, 21, 1559
DOI: 10.1021/acs.orglett.8b03927

Rhodium-Catalyzed Intramolecular Nitrogen Atom Insertion into Arene Rings

Hang Li, Na Li, Jinghao Wu, Tianyang Yu, Ran Zhang, Li-Ping Xu and Hao Wei

J. Am. Chem. Soc., 2023, 145, 17570
DOI: 10.1021/jacs.3c07640

Catalytic Methods for Aromatic C–H Amination: An Ideal Strategy for Nitrogen-Based Functional Molecules

Jiao Jiao, Kei Murakami and Kenichiro Itami

ACS Catal., 2016, 6, 610
DOI: 10.1021/acscatal.5b02417

Metal-free remote oxidative benzylic C−H amination of 4-methylanilides with N -fluorobenzenesulfonimide

Yaocheng Yang, Yanting Yu, Yang Wang, Qian Zhang and Dong Li

Tetrahedron, 2018, 74, 1085
DOI: 10.1016/j.tet.2018.01.041

Catalytic Enantioselective Allylic Amination of Unactivated Terminal Olefins via an Ene Reaction/[2,3]-Rearrangement

Hongli Bao and Uttam K. Tambar

J. Am. Chem. Soc., 2012, 134, 18495
DOI: 10.1021/ja307851b

Iron-Catalyzed Oxidative Coupling of Indoline-2-ones with Aminobenzamides via Dual C–H Functionalization

Yi-Huan Lai, Run-Shi Wu, Jie Huang, Jun-Yu Huang and Da-Zhen Xu

Org. Lett., 2020, 22, 3825
DOI: 10.1021/acs.orglett.0c01066

Mechanistic Insights into the Origins of Selectivity in a Cu-Catalyzed C–H Amidation Reaction

Alistair J. Sterling, Nicodemo R. Ciccia, Yifan Guo, John F. Hartwig and Martin Head-Gordon

J. Am. Chem. Soc., 2024, 146, 6168
DOI: 10.1021/jacs.3c13822

Recent Advances in Iron‐Catalyzed C—H Bond Amination via Iron Imido Intermediate

Peng Wang and Liang Deng

Chin. J. Chem., 2018, 36, 1222
DOI: 10.1002/cjoc.201800427

Copper(II)-Photocatalyzed N–H Alkylation with Alkanes

Yi-Wen Zheng, Rok Narobe, Karsten Donabauer, Shahboz Yakubov and Burkhard König

ACS Catal., 2020, 10, 8582
DOI: 10.1021/acscatal.0c01924

Organoselenium-Catalyzed Oxidative Allylic Fluorination with Electrophilic N–F Reagent

Ruizhi Guo, Jiachen Huang and Xiaodan Zhao

ACS Catal., 2018, 8, 926
DOI: 10.1021/acscatal.7b03829

Facile Synthesis of Azaarene-Substituted 3-Hydroxy-2-oxindoles via Brønsted Acid Catalyzed sp3 C–H Functionalization

Rui Niu, Jian Xiao, Tao Liang and Xingwei Li

Org. Lett., 2012, 14, 676
DOI: 10.1021/ol2030982

Dual Role of Aryl Iodide in Cascade C–H Arylation/Amination: Arylation Reagent and Cocatalyst for C–N Formation

Deng-Yuan Li, Shuo Liu, Shuang Chen, An Wang, Xiao-Ping Zhu and Pei-Nian Liu

ACS Catal., 2018, 8, 6407
DOI: 10.1021/acscatal.8b01071

Copper(I)-catalysed amidation and successive oxidation of benzylic C(sp3)–H bond: synthesis of 1H-pyrrolo[3,4-b]quinoline-1,3(2H)-diones

Xiangqian Yan, Zhiguo Zhang, Guisheng Zhang, Nana Ma, Qingfeng Liu, Tongxin Liu and Lei Shi

Tetrahedron, 2016, 72, 4245
DOI: 10.1016/j.tet.2016.05.059

DDQ-promoted direct C–H amination of ethers with N-alkoxyamides under visible-light irradiation and metal-free conditions

Yan Zhang, Lei Wang, Zhiming Wang and Wei Chen

Tetrahedron, 2019, 75, 130516
DOI: 10.1016/j.tet.2019.130516

Intermolekulare, verzweigt‐selektive und redoxneutrale Cp*IrIII‐katalysierte allylische C‐H‐Amidierung

Tobias Knecht, Shobhan Mondal, Jian‐Heng Ye, Mowpriya Das and Frank Glorius

Angewandte Chemie, 2019, 131, 7191
DOI: 10.1002/ange.201901733

Metal- and Reagent-Free Intramolecular Oxidative Amination of Tri- and Tetrasubstituted Alkenes

Peng Xiong, He-Huan Xu and Hai-Chao Xu

J. Am. Chem. Soc., 2017, 139, 2956
DOI: 10.1021/jacs.7b01016

Organocatalytic regio- and enantioselective vinylogous aza-Morita-Baylis-Hillman reaction

Naruhiro Gondo, Koki Fujimura, Ryuichi Hyakutake, Yoshihiro Ueda and Takeo Kawabata

Tetrahedron Letters, 2023, 115, 154306
DOI: 10.1016/j.tetlet.2022.154306

Copper‐Catalyzed Stereoselective Direct Olefinic β‐C(sp2)−H Imidation of Acyclic Enamides with NFSI

Guisheng Chen, Xiaolan Li, Jie Liu, Haidong Liu and Haiqing Luo

Chin. J. Chem., 2025
DOI: 10.1002/cjoc.70118

Design and Exploration of Catalytic Activity of Two-Dimensional Surface-Engineered Graphene Oxide Nanosheets in the Transannulation of N-Heterocyclic Aldehydes or Ketones with Alkylamines

Rakesh K. Sharma, Aditi Sharma, Shivani Sharma, Sriparna Dutta, Sneha Yadav and Bhavya Arora

ACS Omega, 2019, 4, 3146
DOI: 10.1021/acsomega.8b02902

Ruthenium-Catalyzed Asymmetric N-Acyl Nitrene Transfer Reaction: Imidation of Sulfide

Masaki Yoshitake, Hiroki Hayashi and Tatsuya Uchida

Org. Lett., 2020, 22, 4021
DOI: 10.1021/acs.orglett.0c01373

Fe(III)-Based Tandem Catalysis for Amidomethylative Multiple Substitution Reactions of α-Substituted Styrene Derivatives

Xiaolin Qian, Hui Zhou, Hetti Handi Chaminda Lakmal, James Lucore, Xuesong Wang, Henry U. Valle, Bruno Donnadieu, Xue Xu and Xin Cui

ACS Catal., 2020, 10, 10627
DOI: 10.1021/acscatal.0c02676

Hypervalent Iodine(III) in Direct Oxidative Amination of Arenes with Heteroaromatic Amines

Srimanta Manna, Polina O. Serebrennikova, Irina A. Utepova, Andrey P. Antonchick and Oleg N. Chupakhin

Org. Lett., 2015, 17, 4588
DOI: 10.1021/acs.orglett.5b02320

Facile One-Pot Multi-Component Synthesis of Spirooxindoles and 3, 3’-Disubstituted Oxindoles via sp3 C-H Activation/Functionalization of Azaarenes

Mohsinkhan Y. Pathan, Santosh S. Chavan, Taufeekaslam M. Y. Shaikh, Shridhar H. Thorat, Rajesh G. Gonnade and Shafeek A. R. Mulla

ChemistrySelect, 2017, 2, 9147
DOI: 10.1002/slct.201701507

Bimetallic Palladium/Cobalt Catalysis for Enantioselective Allylic C−H Alkylation via a Transient Chiral Nucleophile Strategy

Hongkai Wang, Yang Xu, Fangqing Zhang, Yangbin Liu and Xiaoming Feng

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202115715

Iodine‐Mediated sp3 C−H Amination Reactions Forming α‐Amino Ketones/Esters and Fused Imidazoles

Kailu Li, Qianmin Li, Qinhao Shi, Yanmin He, Wenquan Yu and Junbiao Chang

Asian J Org Chem, 2022, 11
DOI: 10.1002/ajoc.202200268

Intermolecular Enantioselective Benzylic C(sp3)−H Amination by Cationic Copper Catalysis**

Ling Dai, Ying‐Ying Chen, Li‐Jun Xiao and Qi‐Lin Zhou

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202304427

Recent Advances in Radical-Initiated C(sp3)–H Bond Oxidative Functionalization of Alkyl Nitriles

Xue-Qiang Chu, Danhua Ge, Zhi-Liang Shen and Teck-Peng Loh

ACS Catal., 2018, 8, 258
DOI: 10.1021/acscatal.7b03334

Rh‐catalyzed Tandem Coupling of Sulfonamide with Isonitrile and Amine in Presence of Iodobenzene Diacetate: Direct Access to N‐Sulfonyl Guanidines

Pinakinee Phukan, Moitreyee Bhattacharjee and Prodeep Phukan

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202500176

Dual photoredox and cobalt catalysis enpowers site-selective allylic amination

Guoqing Li and Jiarong Chen

Green Synthesis and Catalysis, 2022, 3, 306
DOI: 10.1016/j.gresc.2022.10.004

(−)‐β‐Pinene‐based π‐Allylpalladium Complex‐Catalyzed Asymmetric Allylation of Bis‐Imines

Rodney A. Fernandes and Jothi L. Nallasivam

ChemistrySelect, 2020, 5, 8301
DOI: 10.1002/slct.202002599

Chiral Counteranion Strategy for Asymmetric Oxidative C(sp3)H/C(sp3)H Coupling: Enantioselective α‐Allylation of Aldehydes with Terminal Alkenes

Pu‐Sheng Wang, Hua‐Chen Lin, Yu‐Jia Zhai, Zhi‐Yong Han and Liu‐Zhu Gong

Angew Chem Int Ed, 2014, 53, 12218
DOI: 10.1002/anie.201408199

Palladium-Catalyzed C(sp2)–H Cyanation Using Tertiary Amine Derived Isocyanide as a Cyano Source

Jiangling Peng, Jiaji Zhao, Ziwei Hu, Dongdong Liang, Jinbo Huang and Qiang Zhu

Org. Lett., 2012, 14, 4966
DOI: 10.1021/ol302372p

Cobalt(III)-Catalyzed C–H Amidation of Arenes using Acetoxycarbamates as Convenient Amino Sources under Mild Conditions

Pitambar Patel and Sukbok Chang

ACS Catal., 2015, 5, 853
DOI: 10.1021/cs501860b

Electro-Oxidative C–N Bond Formation through Azolation of Indole Derivatives: An Access to 3-Substituent-2-(Azol-1-yl)indoles

Naifu Zhou, Junhao Zhao, Chengbo Sun, Yuqin Lai, Zhixiong Ruan and Pengju Feng

J. Org. Chem., 2021, 86, 16059
DOI: 10.1021/acs.joc.1c01271

Transition‐Metal‐Free Synthesis of Acridones via Base‐Mediated Intramolecular Oxidative C−H Amination

Wen‐Tao Wei, Jian‐Fei Sheng, Hui Miao, Xiang Luo, Xian‐Heng Song, Ming Yan and Yong Zou

Adv Synth Catal, 2018, 360, 2101
DOI: 10.1002/adsc.201701579

Rhodium(III)-Catalyzed Oxidative Allylic C–H Indolylation via Nucleophilic Cyclization

Jiaqiong Sun, Kuan Wang, Peiyuan Wang, Guangfan Zheng and Xingwei Li

Org. Lett., 2019, 21, 4662
DOI: 10.1021/acs.orglett.9b01553

Cp*RhIII‐Catalyzed Directed Amidation of Aldehydes with Anthranils

Suvankar Debbarma and Modhu Sudan Maji

Eur J Org Chem, 2017, 2017, 3699
DOI: 10.1002/ejoc.201700457

Der Entwurf einer homogenen Brom‐Redoxkatalyse zur selektiven aliphatischen CH‐Bindungsfunktionalisierung

Peter Becker, Thomas Duhamel, Claudio Martínez and Kilian Muñiz

Angewandte Chemie, 2018, 130, 5262
DOI: 10.1002/ange.201800375

α’‐Selective Selenium‐catalyzed Allylic C−H Amination of Enol Derivatives

Alexander F. Dohoda, Nicole Rishwain, Y‐Nhi Tran and Forrest E. Michael

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202408333

Rhodium‐Catalyzed Intramolecular C−H Bond Activation with Triazoles: Preparation of Stereodefined Pyrrolidines and Other Related Cyclic Compounds

Masato Senoo, Ayana Furukawa, Takeshi Hata and Hirokazu Urabe

Chemistry A European J, 2016, 22, 890
DOI: 10.1002/chem.201503823

Metal‐Free Allylic C−H Amination of Vinylsilanes and Vinylboronates using Silicon or Boron as a Regioselectivity Switch

T. Parker Maloney, Janna L. Berman and Forrest E. Michael

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202210109

Copper‐Catalyzed Oxidative C(sp3)−H/N−H Cross‐Coupling of Hydrocarbons with P(O)−NH Compounds: the Accelerating Effect Induced by Carboxylic Acid Coproduct

Jian Lei, Yincai Yang, Lingteng Peng, Lesong Wu, Ping Peng, Renhua Qiu, Yi Chen, Chak‐Tong Au and Shuang‐Feng Yin

Adv Synth Catal, 2019, 361, 1689
DOI: 10.1002/adsc.201801694

Directing‐Group‐Assisted Transition‐Metal‐Catalyzed Direct Intermolecular C−H Amidation and Amination of Arenes

Yirong Zhou, Jianjun Yuan, Qin Yang, Qiang Xiao and Yiyuan Peng

ChemCatChem, 2016, 8, 2178
DOI: 10.1002/cctc.201600079

Study of Sustainability and Scalability in the Cp*Rh(III)-Catalyzed Direct C–H Amidation with 1,4,2-Dioxazol-5-ones

Yoonsu Park, Soyeon Jee, Jeung Gon Kim and Sukbok Chang

Org. Process Res. Dev., 2015, 19, 1024
DOI: 10.1021/acs.oprd.5b00164

Catalytic Asymmetric Intermolecular Allylic Functionalization of Unactivated Internal Alkenes

Liela Bayeh and Uttam K. Tambar

ACS Catal., 2017, 7, 8533
DOI: 10.1021/acscatal.7b03081

1,6-Aza-Michael addition of para-quinone methides with N-heterocycles catalyzed by Zn(OTf)2: A regioselective approach to N-diarylmethyl-substituted heterocycles

Soumitra Guin, Hemonta K. Saha, Ashvani K. Patel, Santosh K. Gudimella, Subhankar Biswas and Sampak Samanta

Tetrahedron, 2020, 76, 131338
DOI: 10.1016/j.tet.2020.131338

Visible-Light-Induced C(sp3)–H Oxidative Arylation with Heteroarenes

Xing-An Liang, Linbin Niu, Shengchun Wang, Jiamei Liu and Aiwen Lei

Org. Lett., 2019, 21, 2441
DOI: 10.1021/acs.orglett.9b00744

Theoretical Studies on the Mechanism of the C–H Amination of Silyl Cyclopropenes by Azodicarboxylates

Genping Huang, Yuanzhi Xia, Chunrui Sun, Jingwei Li and Daesung Lee

J. Org. Chem., 2013, 78, 988
DOI: 10.1021/jo302466z

Iron-catalysed nitrene transfer reaction to form C N bonds

Hillol Khatua, Subrata Das, Sima Patra, Souvik Nandi and Buddhadeb Chattopadhyay

Tetrahedron Letters, 2024, 144, 155136
DOI: 10.1016/j.tetlet.2024.155136

Transition-metal-free direct amination of simple arenes with sulfonyl azides

Lianggui Wang, Arun Jyoti Borah and Guobing Yan

Tetrahedron Letters, 2015, 56, 1353
DOI: 10.1016/j.tetlet.2015.02.009

Catalytic Metal-free Allylic C–H Amination of Terpenoids

Wei Pin Teh, Derek C. Obenschain, Blaise M. Black and Forrest E. Michael

J. Am. Chem. Soc., 2020, 142, 16716
DOI: 10.1021/jacs.0c06997

Palladium‐Catalyzed Intermolecular C(sp3)H Amidation

Álvaro Iglesias, Rosana Álvarez, Ángel R. de Lera and Kilian Muñiz

Angew Chem Int Ed, 2012, 51, 2225
DOI: 10.1002/anie.201108351

Ruthenium Pincer Complexes: Synthesis and Catalytic Applications

Hussein A. Younus, Wei Su, Nazir Ahmad, Si Chen and Francis Verpoort

Adv Synth Catal, 2015, 357, 283
DOI: 10.1002/adsc.201400777

Direct Transformation of Alkylarenes into N‐(Pyridine‐2‐yl)amides by C(sp3)–C(sp3) Bond Cleavage

Haipin Zhou, Yanpeng Liu, Haidong Xia, Jinyi Xu, Tingfang Wang and Shengtao Xu

Eur J Org Chem, 2020, 2020, 6468
DOI: 10.1002/ejoc.202001137

Iridium-Catalyzed Intermolecular Amidation of sp3 C–H Bonds: Late-Stage Functionalization of an Unactivated Methyl Group

Taek Kang, Youngchan Kim, Donggun Lee, Zhen Wang and Sukbok Chang

J. Am. Chem. Soc., 2014, 136, 4141
DOI: 10.1021/ja501014b

Carbonyl-Assisted Iridium-Catalyzed C–H Amination Using 2,2,2-Trichloroethoxycarbonyl Azide

Xunqing Dong, Mingzhou Shang, Shuguang Chen, Tao Zhang, Hitesh B. Jalani and Hongjian Lu

J. Org. Chem., 2022, 87, 13990
DOI: 10.1021/acs.joc.2c01636

Metal-Free Intermolecular Allylic C–H Amination of Alkenes Using Primary Carbamates

Derek C. Obenschain, John R. Tabor and Forrest E. Michael

ACS Catal., 2023, 13, 4369
DOI: 10.1021/acscatal.3c00807

Intermolecular Enantioselective Benzylic C(sp3)−H Amination by Cationic Copper Catalysis**

Ling Dai, Ying‐Ying Chen, Li‐Jun Xiao and Qi‐Lin Zhou

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202304427

Reactivity Profiles of Diazo Amides, Esters, and Ketones in Transition-Metal-Free C–H Insertion Reactions

Sarah E. Cleary, Xin Li, Li-Cheng Yang, K. N. Houk, Xin Hong and Matthias Brewer

J. Am. Chem. Soc., 2019, 141, 3558
DOI: 10.1021/jacs.8b12420

Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp3)−H and C(sp2)−H under Rhodium(III) Catalysis

Songjie Yu, Guodong Tang, Yingzi Li, Xukai Zhou, Yu Lan and Xingwei Li

Angew Chem Int Ed, 2016, 55, 8696
DOI: 10.1002/anie.201602224

Enantioselective Organocatalytic Amine-Isocyanate Capture-Cyclization: Regioselective Alkene Iodoamination for the Synthesis of Chiral Cyclic Ureas

Thomas J. Struble, Hannah M. Lankswert, Maren Pink and Jeffrey N. Johnston

ACS Catal., 2018, 8, 11926
DOI: 10.1021/acscatal.8b03708

Photoredox α-Vinylation of α-Amino Acids and N-Aryl Amines

Adam Noble and David W. C. MacMillan

J. Am. Chem. Soc., 2014, 136, 11602
DOI: 10.1021/ja506094d

Copper-Catalyzed sp3 C–H Amination

Raymond T. Gephart and Timothy H. Warren

Organometallics, 2012, 31, 7728
DOI: 10.1021/om300840z

Chelation‐promoted Efficient C−H/N−H Cross Dehydrogenative Coupling between Picolinamides and Simple Ethers under Copper Catalysis

Qiang Yue, Zhen Xiao, Zhengkun Kuang, Zhengding Su, Qian Zhang and Dong Li

Adv Synth Catal, 2018, 360, 1193
DOI: 10.1002/adsc.201701508

Tandem Protocol for the Synthesis of 3‐Acyl Benzothiadiazine 1,1‐Dioxides

Pratima A. Sathe, Kamlesh S. Vadagaonkar, Mahendra V. Vhatkar, Lucio Melone and Atul C. Chaskar

ChemistrySelect, 2018, 3, 277
DOI: 10.1002/slct.201702378

Nitration‐Oximization of Styrene Derivatives with tert‐Butyl Nitrite: Synthesis of α‐Nitrooximes

Napasawan Chumnanvej, Praewpan Katrun, Manat Pohmakotr, Vichai Reutrakul, Darunee Soorukram and Chutima Kuhakarn

Chin. J. Chem., 2016, 34, 830
DOI: 10.1002/cjoc.201600167

Iridium-Catalyzed Phosphoramidation of Arene C–H Bonds with Phosphoryl Azide

Changduo Pan, Ning Jin, Honglin Zhang, Jie Han and Chengjian Zhu

J. Org. Chem., 2014, 79, 9427
DOI: 10.1021/jo5018052

Cp*Rh(III)/Bicyclic Olefin Cocatalyzed C–H Bond Amidation by Intramolecular Amide Transfer

Xiaoming Wang, Tobias Gensch, Andreas Lerchen, Constantin G. Daniliuc and Frank Glorius

J. Am. Chem. Soc., 2017, 139, 6506
DOI: 10.1021/jacs.7b02725

NiCl2-catalyzed radical cross decarboxylative coupling between arylpropiolic acids and cyclic ethers

Zi-juan Wan, Jin-yuan Wang and Jun Luo

Tetrahedron Letters, 2019, 60, 613
DOI: 10.1016/j.tetlet.2019.01.039

Iron‐Catalyzed Reductive Allylic C─H Amination of Olefin with Nitroarenes via Intermolecular Nitroso Ene Reaction

Shaolong Qi, Duren Yin, Lingfei Hu, Changqin Huang, Ruyu Xie, Gang Lu and Jianchun Wang

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202504750

Functionalization of the C−H Bond of N‐Heteroaromatics Assisted by Early Transition‐Metal Complexes

Haruki Nagae, Abhinanda Kundu, Mariko Inoue, Hayato Tsurugi and Kazushi Mashima

Asian J Org Chem, 2018, 7, 1256
DOI: 10.1002/ajoc.201800201

Platinum nanoparticles as recyclable heterogeneous catalyst for selective methylation of amines and imines with formic acid: Indirect utilization of CO2

Weishuang Li, Feng Yan, Shuang Cai, Liang Ding, Bojie Li, Bingqing Zhang, Yaoyao Zhang and Lei Zhu

Journal of Saudi Chemical Society, 2022, 26, 101421
DOI: 10.1016/j.jscs.2022.101421

Ruthenium‐Catalyzed C7 Amidation of Indoline CH Bonds with Sulfonyl Azides

Changduo Pan, Ablimit Abdukader, Jie Han, Yixiang Cheng and Chengjian Zhu

Chemistry A European J, 2014, 20, 3606
DOI: 10.1002/chem.201304236

Palladium‐Catalyzed Branch‐ and Z‐Selective Allylic C−H Amination with Aromatic Amines

Rui Liu, Meng‐Lan Shen, Lian‐Feng Fan, Xiao‐Le Zhou, Pu‐Sheng Wang and Liu‐Zhu Gong

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202211631

Allylic Amination of Alkenyl Alcohols: Simultaneous Control of Chemoselectivity and Enantioselectivity in Nitrene Transfer Using Ion-Paired Catalysts

Hannah K. Adams, Alexander Fanourakis, Amit Dahiya, Ioana Băltăreţu and Robert J. Phipps

ACS Catal., 2025, 14639
DOI: 10.1021/acscatal.5c04140

Palladium-Catalyzed Regio- and Stereoselective γ-Arylation of Tertiary Allylic Amines: Identification of Potent Adenylyl Cyclase Inhibitors

Zhishi Ye, Tarsis F. Brust, Val J. Watts and Mingji Dai

Org. Lett., 2015, 17, 892
DOI: 10.1021/ol503748t

Rhodium(III)‐catalyzed Intermolecular Unactivated Secondary C(sp3)−H Bond Amidation Directed by 3,5‐dimethylpyrazole

Yanwei Wang, Hongxin Liu, Bin Li and Baiquan Wang

Adv Synth Catal, 2019, 361, 1564
DOI: 10.1002/adsc.201801592

Highly Robust Iron Catalyst System for Intramolecular C(sp3)−H Amidation Leading to γ‐Lactams

Jeonguk Kweon and Sukbok Chang

Angew Chem Int Ed, 2021, 60, 2909
DOI: 10.1002/anie.202013499

The Development of Radical/Palladium Relay Catalysis for C–H Carbonylation

Yongzheng Ding and Hanmin Huang

Synlett, 2025, 36, 749
DOI: 10.1055/a-2413-0458

Iron-catalyzed cross-dehydrogenative C N coupling of thiohydantoins with various amines

Sulochana S. Mudaliar, Anuj P. Patel, Janki J. Patel and Kishor H. Chikhalia

Tetrahedron Letters, 2018, 59, 734
DOI: 10.1016/j.tetlet.2018.01.024

Cr-doped magnetite for the catalytic radical amination of C(sp3)–H in toluene with NH3 and H2O2

Chuan-Jun Yue, Xu-Dong Hu, Li-Ping Gu and Bao-Liang Liu

Monatsh Chem, 2018, 149, 1161
DOI: 10.1007/s00706-018-2140-z

Iron‐Catalyzed Synthesis of Dihydronaphthalenones from Aromatic Oxime Esters

Youcan Zhang, Zhiping Yin and Xiao‐Feng Wu

Adv Synth Catal, 2019, 361, 3223
DOI: 10.1002/adsc.201900283

Selective Dealkenylative Functionalization of Styrenes via C-C Bond Cleavage

Jianzhong Liu, Jun Pan, Xiao Luo, Xu Qiu, Cheng Zhang and Ning Jiao

Research, 2020, 2020
DOI: 10.34133/2020/7947029

Palladium(0)‐Catalyzed Heck Reaction/CH Activation/Amination Sequence with Diaziridinone: A Facile Approach to Indolines

Huaiji Zheng, Yingguang Zhu and Yian Shi

Angewandte Chemie, 2014, 126, 11462
DOI: 10.1002/ange.201405365

Organoselenium-Catalyzed, Hydroxy-Controlled Regio- and Stereoselective Amination of Terminal Alkenes: Efficient Synthesis of 3-Amino Allylic Alcohols

Zhimin Deng, Jialiang Wei, Lihao Liao, Haiyan Huang and Xiaodan Zhao

Org. Lett., 2015, 17, 1834
DOI: 10.1021/acs.orglett.5b00213

Chemo‐ and Regioselective Catalyst‐Controlled Carbocyclization of Alkynyl Ketones: Rapid Synthesis of 1‐Indanones and 1‐Naphthols

Liangliang Song, Guilong Tian and Erik V. Van der Eycken

Chemistry A European J, 2019, 25, 7645
DOI: 10.1002/chem.201901860

A Conjugate Addition Approach to Diazo‐Containing Scaffolds with β Quaternary Centers

Jian Fang, Evan M. Howard and Matthias Brewer

Angewandte Chemie, 2020, 132, 12927
DOI: 10.1002/ange.202004557

Synthesis of Quinazolinones, Imidazo[1,2‐c]quinazolines and Imidazo[4,5‐c]quinolines through Tandem Reductive Amination of Aryl Halides and Oxidative Amination of C(sp3)–H Bonds

Nitesh Kumar Nandwana, Shiv Dhiman, Hitesh Kumar Saini, Indresh Kumar and Anil Kumar

Eur J Org Chem, 2017, 2017, 514
DOI: 10.1002/ejoc.201601329

The Cs2CO3–Catalyzed Reaction of 2-Oxindoles with Enones for the Preparation of Indolin-3-Ones and Their Further Transformation

Ying Shao, Yu-Mei Zeng, Jie-Ying Ji, Xiao-Qiang Sun, Hai-Tao Yang and Chun-Bao Miao

J. Org. Chem., 2016, 81, 12443
DOI: 10.1021/acs.joc.6b01993

Copper(II)-Catalyzed Direct Amination of 1-Naphthylamines at the C8 Site

Conghui Zu, Tingfang Zhang, Fan Yang, Yusheng Wu and Yangjie Wu

J. Org. Chem., 2020, 85, 12777
DOI: 10.1021/acs.joc.0c01672

DFT Mechanistic Account for the Site Selectivity of Electron-Rich C(sp3)–H Bond in the Manganese-Catalyzed Aminations

Zheyuan Liu, Yu Lu, Jiandong Guo, Wenping Hu, Yanfeng Dang and Zhi-Xiang Wang

Org. Lett., 2020, 22, 453
DOI: 10.1021/acs.orglett.9b04215

Controlling the Site-Selectivity in C(sp³)-H Activation Reaction

Koji Kasamatsu

J. Syn. Org. Chem., Jpn., 2016, 74, 71
DOI: 10.5059/yukigoseikyokaishi.74.71

Iron(II) Chloride‐Catalyzed Nitrene Transfer Reaction for Dearomative Amination of β‐Naphthols with Aryl Azides

Dun‐Qi Wu, Zhen‐Yu Guan, Yi Peng, Jian Sun, Cheng Zhong and Qing‐Hai Deng

Adv Synth Catal, 2018, 360, 4720
DOI: 10.1002/adsc.201800810

Catalytic allylic oxidation of internal alkenes to a multifunctional chiral building block

Liela Bayeh, Phong Q. Le and Uttam K. Tambar

Nature, 2017, 547, 196
DOI: 10.1038/nature22805

Chemo‐ and Regioselective Synthesis of Functionalized 1H‐imidazo[1,5‐a]indol‐3(2H)‐ones via a Redox‐Neutral Rhodium(III)‐Catalyzed [4+1] Annulation between Indoles and Alkynes

Fei Zhao, Jing Chen, Jin Qiao, Yangbin Lu, Xiaoning Zhang, Hui Mao, Shiyao Lu, Xin Gong, Siyu Liu, Xiaowei Wu and Long Dai

Adv Synth Catal, 2021, 363, 4380
DOI: 10.1002/adsc.202100555

RuV‐Acylimido Intermediate in [RuIV(Por)Cl2]‐Catalyzed C–N Bond Formation: Spectroscopic Characterization, Reactivity, and Catalytic Reactions

Dan‐Yan Hong, Yungen Liu, Liangliang Wu, Vanessa Kar‐Yan Lo, Patrick H. Toy, Siu‐Man Law, Jie‐Sheng Huang and Chi‐Ming Che

Angew Chem Int Ed, 2021, 60, 18619
DOI: 10.1002/anie.202100668

Copper-Catalyzed Allylic Amination of Alkenes Using O-Acylhydroxylamines: A Direct Entry to Diverse N-Alkyl Allylamines

Eric J. McLaren, Guangshou Feng, Noah H. Watkins and Qiu Wang

ACS Catal., 2025, 15, 7441
DOI: 10.1021/acscatal.5c01859

Site-selective amination towards tertiary aliphatic allylamines

Shengchun Wang, Yiming Gao, Zhao Liu, Demin Ren, He Sun, Linbin Niu, Dali Yang, Dongchao Zhang, Xing’an Liang, Renyi Shi, Xiaotian Qi and Aiwen Lei

Nat Catal, 2022, 5, 642
DOI: 10.1038/s41929-022-00818-y

A diastereoselective synthesis of functionalized bis-spirorhodanine-linked cyclopentanes via C(sp 3 )–H activation

Issa Yavari, Maryam Naeimabadi and Mohammad R. Halvagar

Tetrahedron, 2018, 74, 4145
DOI: 10.1016/j.tet.2018.06.029

C–H Amination via Electrophotocatalytic Ritter-type Reaction

Tao Shen and Tristan H. Lambert

J. Am. Chem. Soc., 2021, 143, 8597
DOI: 10.1021/jacs.1c03718

Iron‐Catalyzed Allylic C–H Amination of Substituted 1,3‐Dienes

Siva Murru and Radhey S. Srivastava

Eur J Org Chem, 2014, 2014, 2174
DOI: 10.1002/ejoc.201301914

Density Functional Theory Calculations on Oxidative CC Bond Cleavage and NO Bond Formation of [RuII(bpy)2(diamine)]2+ via Reactive Ruthenium Imide Intermediates

Xiangguo Guan, Siu‐Man Law, Chun‐Wai Tse, Jie‐Sheng Huang and Chi‐Ming Che

Chemistry A European J, 2014, 20, 15122
DOI: 10.1002/chem.201402517

Potassium Iodide-Promoted One-Pot Synthesis of Fluoroalkylated Quinoxalines via a Tandem Michael Addition/Azidation/Cycloamination Approach

Jun Wu, Hui Zhang, Xiao Ding, Xuefei Tan, Jie Chen, Weimin He, Hongmei Deng, Liping Song, Hong C. Shen and Weiguo Cao

J. Org. Chem., 2018, 83, 9422
DOI: 10.1021/acs.joc.8b01030

Chemo-, Regio-, and Stereoselective Assembly of Polysubstituted Furan-2(5H)-ones Enabled by Rh(III)-Catalyzed Domino C–H Alkenylation/Directing Group Migration/Lactonization: A Combined Experimental and Computational Study

Fei Zhao, Zhi Zhou, Yangbin Lu, Jin Qiao, Xiaoning Zhang, Xin Gong, Siyu Liu, Shuang Lin, Xiaowei Wu and Wei Yi

ACS Catal., 2021, 11, 13921
DOI: 10.1021/acscatal.1c03846

Direct synthesis of branched amines enabled by dual-catalyzed allylic C─H amination of alkenes with amines

Yu-Feng Ren, Bi-Hong Chen, Xiao-Yi Chen, Hai-Wu Du, Yu-Long Li and Wei Shu

Sci. Adv., 2024, 10
DOI: 10.1126/sciadv.adn1272

RuV‐Acylimido Intermediate in [RuIV(Por)Cl2]‐Catalyzed C–N Bond Formation: Spectroscopic Characterization, Reactivity, and Catalytic Reactions

Dan‐Yan Hong, Yungen Liu, Liangliang Wu, Vanessa Kar‐Yan Lo, Patrick H. Toy, Siu‐Man Law, Jie‐Sheng Huang and Chi‐Ming Che

Angewandte Chemie, 2021, 133, 18767
DOI: 10.1002/ange.202100668

Copper(II) Anilides in sp3 C-H Amination

Eun Sil Jang, Claire L. McMullin, Martina Käß, Karsten Meyer, Thomas R. Cundari and Timothy H. Warren

J. Am. Chem. Soc., 2014, 136, 10930
DOI: 10.1021/ja5026547

Electrophilic amination of Cu(I) catalyzed phenylmagnesium bromide with N,O-bis(trimethylsilyl)hydroxylamine in THF:N-donor solvent. Control of C–N and C–O chemoselectivity

Didem Kahya and Fatma Eroğlu

Journal of Organometallic Chemistry, 2019, 899, 120884
DOI: 10.1016/j.jorganchem.2019.120884

Bis(sulfonylimide)ruthenium(VI) Porphyrins: X‐ray Crystal Structure and Mechanism of CH Bond Amination by Density Functional Theory Calculations

Zhen Guo, Xiangguo Guan, Jie‐Sheng Huang, Wai‐Man Tsui, Zhenyang Lin and Chi‐Ming Che

Chemistry A European J, 2013, 19, 11320
DOI: 10.1002/chem.201300021

Transition Metal‐Controlled Direct Regioselective Intermolecular Amidation of C−H Bonds with Azodicarboxylates: Scope, Mechanistic Studies, and Applications

He‐Yuan Bai, Xin Fu, Jin‐Long Pan, Hai‐Qian Ma, Zhi‐Min Chen, Tong‐Mei Ding and Shu‐Yu Zhang

Adv Synth Catal, 2018, 360, 4205
DOI: 10.1002/adsc.201800623

Controllable Intramolecular Unactivated C(sp3)-H Amination and Oxygenation of Carbamates

Qihang Guo, Xiang Ren and Zhan Lu

Org. Lett., 2019, 21, 880
DOI: 10.1021/acs.orglett.8b03299

Metal‐Free Oxidative CC Bond Formation through CH Bond Functionalization

Rishikesh Narayan, Kiran Matcha and Andrey P. Antonchick

Chemistry A European J, 2015, 21, 14678
DOI: 10.1002/chem.201502005

Asymmetric Electrophilic Amination and Hydrazination of Acyclic α-Branched Ketones for the Formation of α-Tertiary Amines and Hydrazines

Barry M. Trost, Jacob S. Tracy and Eric Y. Lin

ACS Catal., 2019, 9, 11082
DOI: 10.1021/acscatal.9b04246

Iron- and Ruthenium-Catalyzed C–N Bond Formation Reactions. Reactive Metal Imido/Nitrene Intermediates

Yungen Liu, Ka-Pan Shing, Vanessa Kar-Yan Lo and Chi-Ming Che

ACS Catal., 2023, 13, 1103
DOI: 10.1021/acscatal.2c04830

Palladium‐Catalyzed Aerobic Oxidative Synthesis of 3‐Phenylquinoline with Azides and Aldehydes

Xin‐Liang Luo, Xing‐Xing Liu, Jing‐Hong Pu, Wan‐Fa Tian, Xiao‐Qiang Zhou, Dai‐Dong Wei and Guo‐Sheng Huang

ChemistrySelect, 2017, 2, 8658
DOI: 10.1002/slct.201701312

Palladium‐Catalyzed Synthesis of Indolines from Aroyloxycarbamates through a Tandem Decarboxylative Amination/Heck/Annulation Reaction

Zheng Wang, Peihe Li, Hui Fu, Qipu Dai and Changwen Hu

Adv Synth Catal, 2019, 361, 192
DOI: 10.1002/adsc.201800919

Copper-Catalyzed Direct Amination of Quinoline N-Oxides via C–H Bond Activation under Mild Conditions

Chongwei Zhu, Meiling Yi, Donghui Wei, Xuan Chen, Yangjie Wu and Xiuling Cui

Org. Lett., 2014, 16, 1840
DOI: 10.1021/ol500183w

Recent Advances of Oxidative Radical Cross‐Coupling Reactions: Direct α‐C(sp3)–H Bond Functionalization of Ethers and Alcohols

Sheng‐rong Guo, Pailla Santhosh Kumar and Minghua Yang

Adv Synth Catal, 2017, 359, 2
DOI: 10.1002/adsc.201600467

Merging “Anti-Baldwin” 3-Exo-Dig Cyclization with 1,2-Alkynyl Migration for Radical Alkylalkynylation of Unactivated Olefins

Qi Zhao, Xiao-Shuang Ji, Yi-Yun Gao, Wen-Juan Hao, Ke-Ying Zhang, Shu-Jiang Tu and Bo Jiang

Org. Lett., 2018, 20, 3596
DOI: 10.1021/acs.orglett.8b01382

Intermolecular Hydroaminoalkylation of Alkynes

Tobias Kaper, Malte Fischer, Hermann Thye, Dennis Geik, Marc Schmidtmann, Ruediger Beckhaus and Sven Doye

Chemistry A European J, 2021, 27, 6899
DOI: 10.1002/chem.202100238

Palladium-Catalyzed Branch-Selective Allylic C–H Amination Enabled by Nucleophile Coordination

Zhong-Sheng Nong, Pu-Sheng Wang, Qi-Lin Zhou and Liu-Zhu Gong

Org. Lett., 2024, 26, 8481
DOI: 10.1021/acs.orglett.4c02935

DDQ-Mediated Oxidative Coupling: An Approach to 2,3-Dicyanofuran (Thiophene)

Zheng-Lin Wang, Hong-Liang Li, Li-Shi Ge, Xing-Lan An, Zi-Gang Zhang, Xiaoyan Luo, John S. Fossey and Wei-Ping Deng

J. Org. Chem., 2014, 79, 1156
DOI: 10.1021/jo4026034

Palladium-Catalyzed Direct Intermolecular Amination of Unactivated Methylene C(sp3)–H Bonds with Azodiformates via Bidentate-Chelation Assistance

He-Yuan Bai, Zhi-Gang Ma, Min Yi, Jun-Bing Lin and Shu-Yu Zhang

ACS Catal., 2017, 7, 2042
DOI: 10.1021/acscatal.6b03621

Recent advances in transition metal (Pd, Ni)-catalyzed C(sp 3 ) H bond activation with bidentate directing groups

Xinglin Yang, Gang Shan, Liguo Wang and Yu Rao

Tetrahedron Letters, 2016, 57, 819
DOI: 10.1016/j.tetlet.2016.01.009

Copper-Catalyzed Denitrogenative Transannulation Reaction of Pyridotriazoles: Synthesis of Imidazo[1,5-a]pyridines with Amines and Amino Acids

Abhisek Joshi, Darapaneni Chandra Mohan and Subbarayappa Adimurthy

Org. Lett., 2016, 18, 464
DOI: 10.1021/acs.orglett.5b03509

Catalytic CH Amination with Aromatic Amines

Raymond T. Gephart, Daria L. Huang, Mae Joanne B. Aguila, Graham Schmidt, Andi Shahu and Timothy H. Warren

Angew Chem Int Ed, 2012, 51, 6488
DOI: 10.1002/anie.201201921

Mechanistic study on silver-catalyzed direct amination of unactivated C H bond

Xiang Zhang

Journal of Organometallic Chemistry, 2017, 832, 1
DOI: 10.1016/j.jorganchem.2017.01.006

Highly Regioselective Radical Amination of Allenes: Direct Synthesis of Allenamides and Tetrasubstituted Alkenes

Ge Zhang, Tao Xiong, Zining Wang, Guoxing Xu, Xuedan Wang and Qian Zhang

Angew Chem Int Ed, 2015, 54, 12649
DOI: 10.1002/anie.201506066

Funktionalisierung von C‐H‐Bindungen: neue Synthesemethoden für Naturstoffe und Pharmazeutika

Junichiro Yamaguchi, Atsushi D. Yamaguchi and Kenichiro Itami

Angewandte Chemie, 2012, 124, 9092
DOI: 10.1002/ange.201201666

Fluoro Nitrenoid Complexes FN=MF2 (M=Co, Rh, Ir): Electronic Structure Dichotomy and Formation of Nitrido Fluorides N≡MF3

Tony Stüker, Thomas Hohmann, Helmut Beckers and Sebastian Riedel

Angew Chem Int Ed, 2020, 59, 23174
DOI: 10.1002/anie.202010950

Copper-Catalyzed Aerobic Aliphatic C–H Oxygenation Directed by an Amidine Moiety

Yi-Feng Wang, Hui Chen, Xu Zhu and Shunsuke Chiba

J. Am. Chem. Soc., 2012, 134, 11980
DOI: 10.1021/ja305833a

Synthesis of Biologically Relevant Compounds by Ruthenium Porphyrin Catalyzed Amination of Benzylic C–H Bonds

Paolo Zardi, Alessandro Caselli, Piero Macchi, Francesco Ferretti and Emma Gallo

Organometallics, 2014, 33, 2210
DOI: 10.1021/om500064d

Csp3–H Bond Functionalization of α-Bromo Ketones for the Synthesis of α-Keto Thioamides Using Elemental Sulfur

Haiying Tian, Fang Guo and Xiuling Chen

Russ J Org Chem, 2022, 58, 1260
DOI: 10.1134/S107042802209010X

(Diacetoxyiodo)benzene‐Mediated Oxygenation of Benzylic C(sp3)–H Bonds with N‐Hydroxyamides at Room Temperature

Peng‐Cheng Qian, Yu Liu, Ren‐Jie Song, Ming Hu, Xu‐Heng Yang, Jian‐Nan Xiang and Jin‐Heng Li

Eur J Org Chem, 2015, 2015, 1680
DOI: 10.1002/ejoc.201403616

Amination of Bridging Vinyliminium Ligands in Diiron Complexes: C–N Bond Forming Reactions for Amidine-Alkylidene Species

Fabio Marchetti, Stefano Zacchini and Valerio Zanotti

Organometallics, 2018, 37, 107
DOI: 10.1021/acs.organomet.7b00762

A Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C–H Amidation of N-Pivaloylindoles with Organic Azides

Youyoung Kim, Juhyeon Park and Sukbok Chang

Org. Lett., 2016, 18, 1892
DOI: 10.1021/acs.orglett.6b00662

Copper(I)-catalyzed domino allylic C(sp3)–H aminative cyclization/oxidative reaction and its application toward pyrrolo[3,4-d]pyrimidinones

Zhiguo Zhang, Xiangqian Yan, Guisheng Zhang, Qingfeng Liu, Nana Ma, Tongxin Liu and Lei Shi

Tetrahedron, 2016, 72, 3077
DOI: 10.1016/j.tet.2016.04.031

Iridium(III)-Catalyzed Regioselective C7-Amination of N-Pivaloylindoles with Sulfonoazides

Lanting Xu, Lushi Tan and Dawei Ma

J. Org. Chem., 2016, 81, 10476
DOI: 10.1021/acs.joc.6b01856

New Synthetic Methods Using Interaction between Functionalized C-C Multiple Bonds and Iron Reagent

Takeshi Hata

J. Synth. Org. Chem. Jpn., 2014, 72, 972
DOI: 10.5059/yukigoseikyokaishi.72.972

Transition Metal Free Intermolecular Direct Oxidative C–N Bond Formation to Polysubstituted Pyrimidines Using Molecular Oxygen as the Sole Oxidant

Wei Guo, Chunsheng Li, Jianhua Liao, Fanghua Ji, Dongqing Liu, Wanqing Wu and Huanfeng Jiang

J. Org. Chem., 2016, 81, 5538
DOI: 10.1021/acs.joc.6b00867

Synthesis of Indene Frameworks via Rhodium-Catalyzed Cascade Cyclization of Aromatic Ketone and Unsaturated Carbonyl Compounds

Xian-Ying Shi and Chao-Jun Li

Org. Lett., 2013, 15, 1476
DOI: 10.1021/ol400198q

Allylic Amination of Highly Substituted Alkenes Enabled by Photoredox Catalysis and Cu(II)-Mediated Radical–Polar Crossover

Grace A. Lutovsky, Ellie F. Plachinski, Nicholas L. Reed and Tehshik P. Yoon

Org. Lett., 2023, 25, 4750
DOI: 10.1021/acs.orglett.3c01774

Copper-Catalyzed Carboxamide-Directed Ortho Amination of Anilines with Alkylamines at Room Temperature

Qiong Li, Shu-Yu Zhang, Gang He, Zhaoyan Ai, William A. Nack and Gong Chen

Org. Lett., 2014, 16, 1764
DOI: 10.1021/ol500464x

Intermolecular C(sp3)−H Amination Promoted by Internal Oxidants: Synthesis of Trifluoroacetylated Hydrazones

Chuanle Zhu, Hao Zeng, Fulin Chen, Zhiyi Yang, Yingying Cai and Huanfeng Jiang

Angew Chem Int Ed, 2018, 57, 17215
DOI: 10.1002/anie.201810502

Regioselektive katalytische C(sp2)‐H‐Azidierungen

Weifeng Song, Sergei I. Kozhushkov and Lutz Ackermann

Angewandte Chemie, 2013, 125, 6706
DOI: 10.1002/ange.201302015

I2-Catalyzed Oxidative Cross-Coupling of Methyl Ketones and Benzamidines Hydrochloride: A Facile Access to α-Ketoimides

Xia Wu, Qinghe Gao, Shan Liu and Anxin Wu

Org. Lett., 2014, 16, 2888
DOI: 10.1021/ol501029w

Domino Oxidative Cyclization of 2‐Aminoacetophenones for the One‐Pot Synthesis of Tryptanthrin Derivatives

B. V. Subba Reddy, D. Maheswara Reddy, G. Niranjan Reddy, M. Ramana Reddy and V. Krishna Reddy

Eur J Org Chem, 2015, 2015, 8018
DOI: 10.1002/ejoc.201501079

Iron oxide-silver magnetic nanoparticles as simple heterogeneous catalysts for the direct inter/intramolecular nucleophilic substitution of π-activated alcohols with electron-deficient amines

Xingzhu Xu, Haibo Wu, Zhengyi Li, Xiaoqiang Sun and Zhiming Wang

Tetrahedron, 2015, 71, 5254
DOI: 10.1016/j.tet.2015.06.028

Synthesis of medicinally relevant oxalylamines via copper/Lewis acid synergistic catalysis

Ziying Wu, Miao Hu, Yangbin Jin, Jianxiao Li, Wanqing Wu and Huanfeng Jiang

Sci. Adv., 2021, 7
DOI: 10.1126/sciadv.abh4088

Synthesis of tert‐Butyl Peroxyacetals from Benzyl, Allyl, or Propargyl Ethers via Iron‐Promoted CH Bond Functionalization

Satoshi Iwata, Takeshi Hata and Hirokazu Urabe

Adv Synth Catal, 2012, 354, 3480
DOI: 10.1002/adsc.201200410

Density Functional Theory Mechanistic Study of Boron‐Catalyzed N‐Alkylation of Amines with Formic Acid: Formic Acid Activation by Silylation Reaction

Pan Du and Jiyang Zhao

Chemistry An Asian Journal, 2018, 13, 701
DOI: 10.1002/asia.201701607

Catalytic C–H amination of alkanes with sulfonimidamides: silver(I)-scorpionates vs. dirhodium(II) carboxylates

Álvaro Beltrán, Camille Lescot, M. Mar Díaz-Requejo, Pedro J. Pérez and Philippe Dauban

Tetrahedron, 2013, 69, 4488
DOI: 10.1016/j.tet.2013.02.005

Palladium-Catalyzed Regioselective C8–H Amination of 1-Naphthylamine Derivatives with Aliphatic Amines

Zexian Li, Suyan Sun, Huijie Qiao, Fan Yang, Yu Zhu, Jianxun Kang, Yusheng Wu and Yangjie Wu

Org. Lett., 2016, 18, 4594
DOI: 10.1021/acs.orglett.6b02243

Chiral Allylic Amine Synthesis Enabled by the Enantioselective CpXRh(III)-Catalyzed Carboaminations of 1,3-Dienes

Liexin Wu, Huiying Xu, Hui Gao, Liping Li, Weijie Chen, Zhi Zhou and Wei Yi

ACS Catal., 2021, 11, 2279
DOI: 10.1021/acscatal.0c04777

Photochemical C−H Amination of Ethers and Geminal Difunctionalization Reactions in One Pot

Daniel Hernández‐Guerra, Anna Hlavačková, Chiranan Pramthaisong, Ilaria Vespoli, Radek Pohl, Tomáš Slanina and Ullrich Jahn

Angew Chem Int Ed, 2019, 58, 12440
DOI: 10.1002/anie.201905209

Ruthenium-Catalyzed γ-Selective Intermolecular Amidation of Nonactivated Distal Methylene C–H Bonds of Terminal Alkenes via Olefin Chain-Walking Isomerization

Yiu-Wai Yeung, Sing-Fung Hung, Chi-Ming Au, Marco Chan, Chun-Ming Chan and Wing-Yiu Yu

ACS Catal., 2025, 15, 3980
DOI: 10.1021/acscatal.4c06639

Site‐Selective Catalytic C(sp2)H Bond Azidations

Weifeng Song, Sergei I. Kozhushkov and Lutz Ackermann

Angew Chem Int Ed, 2013, 52, 6576
DOI: 10.1002/anie.201302015

Cobalt-catalysed site-selective intra- and intermolecular dehydrogenative amination of unactivated sp3 carbons

Xuesong Wu, Ke Yang, Yan Zhao, Hao Sun, Guigen Li and Haibo Ge

Nat Commun, 2015, 6
DOI: 10.1038/ncomms7462

Tandem sp3 C–H Functionlization/Decarboxylation of 2-Alkylazaarenes with Coumarin-3-carboxylic Acids

Lubin Xu, Zhuzhou Shao, Liang Wang and Jian Xiao

Org. Lett., 2014, 16, 796
DOI: 10.1021/ol403541g

Synthesis of Amines from Alcohols in a Nonepimerizing One‐Pot Sequence – Synthesis of Bioactive Compounds: Cinacalcet and Dexoxadrol

Claire Guérin, Véronique Bellosta, Gérard Guillamot and Janine Cossy

Eur J Org Chem, 2012, 2012, 2990
DOI: 10.1002/ejoc.201200171

Distinctive Activation and Functionalization of Hydrocarbon C–H Bonds Initiated by Cp*W(NO)(η3-allyl)(CH2CMe3) Complexes

Rhett A. Baillie and Peter Legzdins

Acc. Chem. Res., 2014, 47, 330
DOI: 10.1021/ar400108p

SeO2 Mediated Synthesis of Selected Heterocycles by Oxidative C−C Bond Cleavage of AcetophenoneDerivatives

Danish Khan, Naseem Ahmed, Meshari A. Alsharif, Mohammed Issa Alahmdi and Sayeed Mukhtar

ChemistrySelect, 2019, 4, 7585
DOI: 10.1002/slct.201901216

Diethylenetriamine-Mediated Direct Cleavage of Unactivated Carbamates and Ureas

Megumi Noshita, Yuhei Shimizu, Hiroyuki Morimoto and Takashi Ohshima

Org. Lett., 2016, 18, 6062
DOI: 10.1021/acs.orglett.6b03016

Recent Advances in C−H Functionalization with Electrochemistry and Various Iodine‐Containing Reagents

Peng Qian, Zhenggen Zha and Zhiyong Wang

ChemElectroChem, 2020, 7, 2527
DOI: 10.1002/celc.202000252

Copper-Catalyzed Intramolecular Amination of C(sp3)–H Bond of Secondary Amines to Access Azacycles

Ruo-Xing Jin, Jing-Cheng Dai, Yan Li and Xi-Sheng Wang

Org. Lett., 2021, 23, 421
DOI: 10.1021/acs.orglett.0c03934

Iridium(III)‐Catalyzed Direct CH Sulfonamidation of 2‐Aryl‐1,2,3‐triazole N‐Oxides with Sulfonyl Azides

Bingfeng Zhu, Xiuling Cui, Chao Pi, Dong Chen and Yangjie Wu

Adv Synth Catal, 2016, 358, 326
DOI: 10.1002/adsc.201501036

Rhodium(III)‐Catalyzed CH Activation of Arenes Using a Versatile and Removable Triazene Directing Group

Chengming Wang, Hu Chen, Zhaofeng Wang, Jiean Chen and Yong Huang

Angew Chem Int Ed, 2012, 51, 7242
DOI: 10.1002/anie.201203230

Iodoarene-Catalyzed Stereospecific Intramolecular sp3 C–H Amination: Reaction Development and Mechanistic Insights

Chendan Zhu, Yong Liang, Xin Hong, Heqing Sun, Wei-Yin Sun, K. N. Houk and Zhuangzhi Shi

J. Am. Chem. Soc., 2015, 137, 7564
DOI: 10.1021/jacs.5b03488

Ligand-Accelerated Palladium(II)-Catalyzed Enantioselective Amination of C(sp2)–H Bonds

Xiu-Fen Cheng, Fan Fei, Yan Li, Yi-Ming Hou, Xin Zhou and Xi-Sheng Wang

Org. Lett., 2020, 22, 6394
DOI: 10.1021/acs.orglett.0c02216

Palladium-Catalyzed C–H Amination of C(sp2) and C(sp3)–H Bonds: Mechanism and Scope for N-Based Molecule Synthesis

Yam N. Timsina, B. Frank Gupton and Keith C. Ellis

ACS Catal., 2018, 8, 5732
DOI: 10.1021/acscatal.8b01168

A Cu-Promoted C–N Coupling of Boron Esters and Diaziridinone: An Approach to Aryl Ureas

Jing Li, Xiaoyu Wang, Zhanwei Wang and Yian Shi

Org. Lett., 2021, 23, 8958
DOI: 10.1021/acs.orglett.1c03468

Palladium‐Catalyzed Intramolecular C–H Amination in Water

Lizheng Yang, Hao Li, Haifei Zhang and Hongjian Lu

Eur J Org Chem, 2016, 2016, 5611
DOI: 10.1002/ejoc.201601043

Electrochemical Synthesis of Allylic Amines from Terminal Alkenes and Secondary Amines

Diana J. Wang, Karina Targos and Zachary K. Wickens

J. Am. Chem. Soc., 2021, 143, 21503
DOI: 10.1021/jacs.1c11763

Transition‐Metal‐Catalyzed Electrophilic Amination: Application of O‐Benzoylhydroxylamines in the Construction of the C−N Bond

Xu Dong, Qing Liu, Yunhui Dong and Hui Liu

Chemistry A European J, 2017, 23, 2481
DOI: 10.1002/chem.201601607

Recent Development on Cp*Ir(III)‐Catalyzed C−H Bond Functionalization

Xianwei Li, Wensen Ouyang, Jianhong Nie, Shaomin Ji, Qian Chen and Yanping Huo

ChemCatChem, 2020, 12, 2358
DOI: 10.1002/cctc.201902150

Thermal Activation of Ammonia by Transition‐Metal Hydroxide Cations

Robert Kretschmer, Maria Schlangen and Helmut Schwarz

ChemPlusChem, 2013, 78, 952
DOI: 10.1002/cplu.201300138

Enantioselective Functionalization of Allylic C–H Bonds Following a Strategy of Functionalization and Diversification

Ankit Sharma and John F. Hartwig

J. Am. Chem. Soc., 2013, 135, 17983
DOI: 10.1021/ja409995w

Opening the Way to Catalytic Aminopalladation/Proxicyclic Dehydropalladation: Access to Methylidene γ-Lactams

Mélanie M. Lorion, Filipe J. S. Duarte, Maria José Calhorda, Julie Oble and Giovanni Poli

Org. Lett., 2016, 18, 1020
DOI: 10.1021/acs.orglett.6b00143

Practical Pd(TFA)2-Catalyzed Aerobic [4+1] Annulation for the Synthesis of Pyrroles via “One-Pot” Cascade Reactions

Yang Yu, Zhiguo Mang, Wei Yang, Hao Li and Wei Wang

Catalysts, 2016, 6, 169
DOI: 10.3390/catal6110169

[Fe(F20TPP)Cl]‐Catalyzed Amination with Arylamines and {[Fe(F20TPP)(NAr)](PhINAr)} Intermediate Assessed by High‐Resolution ESI‐MS and DFT Calculations

Yungen Liu, Guo‐Qiang Chen, Chun‐Wai Tse, Xianguo Guan, Zheng‐Jiang Xu, Jie‐Sheng Huang and Chi‐Ming Che

Chemistry An Asian Journal, 2015, 10, 100
DOI: 10.1002/asia.201402580

Cu/Fe Catalyzed Intermolecular Oxidative Amination of Benzylic C−H Bonds

Cong Liu, Qi Zhang, Hongbo Li, Shuangxi Guo, Bin Xiao, Wei Deng, Lei Liu and Wei He

Chemistry A European J, 2016, 22, 6208
DOI: 10.1002/chem.201600107

Chemoselective Cleavage of C(CO)−C Bond: Molecular Iodine‐Catalyzed Synthesis of Quinazolines through sp3 C−H Bond Functionalization of Aryl Methyl Ketones

Abhishek R. Tiwari and Bhalchandra M. Bhanage

Asian J Org Chem, 2017, 6, 831
DOI: 10.1002/ajoc.201700217

Rhodium(III)-Catalyzed Direct Oxidative Cross Coupling at the C5 Position of Chromones with Alkenes

Rajarshi Samanta, Rishikesh Narayan and Andrey P. Antonchick

Org. Lett., 2012, 14, 6108
DOI: 10.1021/ol303067f

Enantioselective Cycloisomerization of 1,6-Enynes to Bicyclo[3.1.0]hexanes Catalyzed by Rhodium and Benzoic Acid

Koji Masutomi, Keiichi Noguchi and Ken Tanaka

J. Am. Chem. Soc., 2014, 136, 7627
DOI: 10.1021/ja504048u

Allylic Amination andN-Arylation-Based Domino Reactions Providing Rapid Three-Component Strategies to Fused Pyrroles with Different Substituted Patterns

Bo Jiang, Ying Li, Man-Su Tu, Shu-Liang Wang, Shu-Jiang Tu and Guigen Li

J. Org. Chem., 2012, 77, 7497
DOI: 10.1021/jo301323r

Terminal Imido Rhodium Complexes

Ana M. Geer, Cristina Tejel, José A. López and Miguel A. Ciriano

Angewandte Chemie, 2014, 126, 5720
DOI: 10.1002/ange.201400023

Pd(0)-Catalyzed Sequential C–N Bond Formation via Allylic and Aromatic C–H Amination of α-Methylstyrenes with Diaziridinone

Thomas A. Ramirez, Qian Wang, Yingguang Zhu, Huaiji Zheng, Xingao Peng, Richard G. Cornwall and Yian Shi

Org. Lett., 2013, 15, 4210
DOI: 10.1021/ol401935c

Construction of N-Heterocyclic Systems Containing a Fully Substituted Allylic Carbon by Palladium/Phosphine Catalysis

Yohei Ogiwara, Yui Suzuki, Kazuya Sato and Norio Sakai

Org. Lett., 2018, 20, 6965
DOI: 10.1021/acs.orglett.8b03127

A Domino Azidation/C–H Amination Approach toward Trifluoromethyl Substituted Imidazoles

Haichao Ma, Xiaoyan Zhang, Liangliang Chen and Wei Yu

J. Org. Chem., 2017, 82, 11841
DOI: 10.1021/acs.joc.7b01361

Microwave assisted catalyst-free synthesis of azaarene-substituted 3-hydroxy-2-oxindoles by the functionalization of sp3 C–H bond in methyl pyridine

H.M. Meshram, N. Nageswara Rao, L. Chandrasekhara Rao and N. Satish Kumar

Tetrahedron Letters, 2012, 53, 3963
DOI: 10.1016/j.tetlet.2012.05.077

Rhodium(III)‐Catalyzed Amidation of Unactivated C(sp3)H Bonds

He Wang, Guodong Tang and Xingwei Li

Angewandte Chemie, 2015, 127, 13241
DOI: 10.1002/ange.201506323

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

Junichiro Yamaguchi, Atsushi D. Yamaguchi and Kenichiro Itami

Angew Chem Int Ed, 2012, 51, 8960
DOI: 10.1002/anie.201201666

Electrochemical Oxidative Coupling Between Benzylic C(sp3)–H and N–H of Secondary Amines: Rapid Synthesis of α-Amino α-Aryl Esters

Yadav Kacharu Nagare, Imtiyaz Ahmad Shah, Jyothi Yadav, Amol Prakash Pawar, Rahul Choudhary, Pankaj Chauhan and Indresh Kumar

J. Org. Chem., 2021, 86, 9682
DOI: 10.1021/acs.joc.1c00944

N-Bromoimide/DBU Combination as a New Strategy for Intermolecular Allylic Amination

Ying Wei, Fushun Liang and Xintong Zhang

Org. Lett., 2013, 15, 5186
DOI: 10.1021/ol402287n

Recent Advances in Transition Metal‐Catalyzed Methylation Reactions

Guobing Yan, Arun Jyoti Borah, Lianggui Wang and Minghua Yang

Adv Synth Catal, 2015, 357, 1333
DOI: 10.1002/adsc.201400984

Metal‐Free Allylic C−H Amination of Vinylsilanes and Vinylboronates using Silicon or Boron as a Regioselectivity Switch

T. Parker Maloney, Janna L. Berman and Forrest E. Michael

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202210109

Iron-catalyzed aerobic oxidative cross-coupling amidation of N,N-dimethylanilines

Abudureheman Wusiman and Ruzeahong Hudabaierdi

Tetrahedron Letters, 2019, 60, 681
DOI: 10.1016/j.tetlet.2019.01.058

Tandem Oxidative C−H Amination and Iodization to Synthesize Difunctional Atropoisomeric P‐Stereogenic Phosphinamides

Yan‐Na Ma, Xi Zhang and Shang‐dong Yang

Chemistry A European J, 2017, 23, 3007
DOI: 10.1002/chem.201700218

Studies on AlkylNitrogen Bond Formation via Reductive Elimination from Monomeric Palladium Complexes in High Oxidation State

Álvaro Iglesias and Kilian Muñiz

Helvetica Chimica Acta, 2012, 95, 2007
DOI: 10.1002/hlca.201200430

Stereocontrolled concise synthesis of (±)-halosaline through intramolecular C-H amination

Chun-Yan Meng, Xiao Liang, Hongbin Zhang, Kun Wei and Yu-Rong Yang

Tetrahedron Letters, 2019, 60, 1781
DOI: 10.1016/j.tetlet.2019.05.068

Enantioselective Synthesis of Chiral 2‐Nitroallylic Amines via Cooperative Cation‐Binding Catalysis

Jin Hyun Park, Pintu Maity, Sushovan Paladhi, Han Yong Bae and Choong Eui Song

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301787

Preparation of Hetero‐π‐Conjugated Compounds by Double Nucleophilic Addition to Haloalkynes and C−H Cyclization

Takeshi Hata, Yuta Tatsumi, Yuki Kanai, Naoto Takahashi, Masayuki Shigeta and Hirokazu Urabe

Adv Synth Catal, 2024, 366, 2136
DOI: 10.1002/adsc.202301510

Designing Homogeneous Bromine Redox Catalysis for Selective Aliphatic C−H Bond Functionalization

Peter Becker, Thomas Duhamel, Claudio Martínez and Kilian Muñiz

Angew Chem Int Ed, 2018, 57, 5166
DOI: 10.1002/anie.201800375

A Conjugate Addition Approach to Diazo‐Containing Scaffolds with β Quaternary Centers

Jian Fang, Evan M. Howard and Matthias Brewer

Angew Chem Int Ed, 2020, 59, 12827
DOI: 10.1002/anie.202004557

Advances in the Intermolecular Asymmetric Allylic Functionalization of Unreactive Acyclic Alkenes

Mingyue Zhang, Mengmeng Zhang, Changsheng Li, Wenyang Wang, Guohui Shi, Shipeng Luo, Liang-An Chen and Qiang Dai

Synlett, 2025, 36, 311
DOI: 10.1055/a-2375-7634

Cobalt-Catalyzed Allylation of Amides with Styrenes Using DMSO as Both the Solvent and the α-Methylene Source

Xu Zhang, Zhi Zhou, Huiying Xu, Xuefeng Xu, Xiyong Yu and Wei Yi

Org. Lett., 2019, 21, 7248
DOI: 10.1021/acs.orglett.9b02462

β-Silicon Effect Enables Metal-Free Site-Selective Intermolecular Allylic C–H Amination

Shuang Lin, Yuan Liu, Kun-Yu Gao, Zhi-Hao Chen, Jiasheng Qian, Xiao-Bin Liu, Qingjiang Li and Honggen Wang

ACS Catal., 2024, 14, 8865
DOI: 10.1021/acscatal.4c02393

Merging Photoredox and Nickel Catalysis: A Ligand-Free Cross-Coupling of Vinyl Halides and α-Silylamines toward Tertiary Allylic Alkylamines

Fu Ye, Shiming Tong and Weiming Yuan

ACS Catal., 2024, 14, 9655
DOI: 10.1021/acscatal.4c02602

Three-Component Cycloaddition To Synthesize Aziridines and 1,2,3-Triazolines

Shuqi Chen, Yongqi Yao, Wen Yang, Qifu Lin, Lin Wang, Huanyong Li, Donghan Chen, Yun Tan and Dingqiao Yang

J. Org. Chem., 2019, 84, 11863
DOI: 10.1021/acs.joc.9b01713

Metal‐Free Oxidative Carbon‐Heteroatom Bond Formation Through C–H Bond Functionalization

Rajarshi Samanta, Kiran Matcha and Andrey P. Antonchick

Eur J Org Chem, 2013, 2013, 5769
DOI: 10.1002/ejoc.201300286