Issue 18, 2023

Facile separation of cyclic aliphatic and aromatic vapors using crystalline thiacalixarene assemblies with preorganized channels

Abstract

Conventional distillation methods cannot separate compounds with similar boiling points, molecular sizes, and volumes, such as cyclohexane and benzene or methylcyclohexane and toluene, effectively. The corresponding cyclic aliphatic and aromatic hydrocarbons cannot be separated effectively using the same type of sorption material. We report that crystalline thiacalixarene assemblies featuring preorganized channel-like adsorption sites are capable of both separations.

Graphical abstract: Facile separation of cyclic aliphatic and aromatic vapors using crystalline thiacalixarene assemblies with preorganized channels

Supplementary files

Article information

Article type
Communication
Submitted
18 Nhl 2022
Accepted
30 Sun 2023
First published
30 Sun 2023

Chem. Commun., 2023,59, 2604-2607

Facile separation of cyclic aliphatic and aromatic vapors using crystalline thiacalixarene assemblies with preorganized channels

M. Yamada, R. Yoshizaki, F. Uemura, H. Katagiri, S. Kato, K. Akimoto and F. Hamada, Chem. Commun., 2023, 59, 2604 DOI: 10.1039/D2CC05647J

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