Issue 66, 2022

Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO2 reduction

Abstract

A series of Ir complexes has been developed as multifunctional photocatalysts for CO2 reduction to give HCO2H selectively. The catalytic activities and photophysical properties vary widely across the series, and the bulky group insertion resulted in the formation of HCO2H and CO with the catalyst turnover number of >10 400.

Graphical abstract: Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO2 reduction

Supplementary files

Article information

Article type
Communication
Submitted
25 Kul 2022
Accepted
15 Maw 2022
First published
15 Maw 2022

Chem. Commun., 2022,58, 9218-9221

Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO2 reduction

K. Kamada, J. Jung, Y. Kametani, T. Wakabayashi, Y. Shiota, K. Yoshizawa, S. H. Bae, M. Muraki, M. Naruto, K. Sekizawa, S. Sato, T. Morikawa and S. Saito, Chem. Commun., 2022, 58, 9218 DOI: 10.1039/D2CC01701F

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