Competing hydrogen-bonding interactions in a high-Tc organic molecular-ionic crystal with evident nonlinear optical response

Wen-Tao Xu; Jun-Chao Liu; Yu-Ling Zeng; Hua Zhang; Zhong-Xia Wang

doi:10.1039/D0CE01875A

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Competing hydrogen-bonding interactions in a high-T_c organic molecular-ionic crystal with evident nonlinear optical response†

Wen-Tao Xu,^a Jun-Chao Liu,^a Yu-Ling Zeng,^a Hua Zhang^a and Zhong-Xia Wang

*^a

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* Corresponding authors

^a Ordered Matter Science Research Center, Nanchang University, Nanchang 330031, People's Republic of China
E-mail: zhongxiawang@ncu.edu.cn

Abstract

A molecular-ionic crystal of bis(triphenylhydroxyphosphonium) sulfate, (TPPO–H)₂SO₄, exhibits high-T_c phase transition induced by the competing hydrogen-bonding interactions and evident nonlinear optical (NLO) response.

This article is part of the themed collection: Crystal Growth

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Article information

DOI: https://doi.org/10.1039/D0CE01875A
Article type: Communication
Submitted: 27 N’w 2020
Accepted: 06 Kul 2021
First published: 08 Kul 2021

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CrystEngComm, 2021,23, 2509-2512

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Competing hydrogen-bonding interactions in a high-T_c organic molecular-ionic crystal with evident nonlinear optical response

W. Xu, J. Liu, Y. Zeng, H. Zhang and Z. Wang, CrystEngComm, 2021, 23, 2509 DOI: 10.1039/D0CE01875A

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