Issue 39, 2019

Palladium-mediated intramolecular dearomatization of ligated dialkylterphenyl phosphines

Abstract

Aryl–Pd(II) chlorides stabilized by dialkylterphenyl phosphine ligands undergo a thermal isomerization process, leading to the formation of allyl–Pd(II)-chloride species. The transformation involves the intramolecular functionalization of a C–H bond of the terphenyl group mediated by the Pd(II) center.

Graphical abstract: Palladium-mediated intramolecular dearomatization of ligated dialkylterphenyl phosphines

Supplementary files

Article information

Article type
Communication
Submitted
06 Mha 2019
Accepted
28 Mha 2019
First published
28 Mha 2019

Dalton Trans., 2019,48, 14575-14579

Palladium-mediated intramolecular dearomatization of ligated dialkylterphenyl phosphines

R. J. Rama, C. Maya and M. C. Nicasio, Dalton Trans., 2019, 48, 14575 DOI: 10.1039/C9DT03201K

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