Issue 25, 2019

The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

Abstract

A stable 1,4-disilabenzene was generated from the reaction of a stable disilyne with 3-hexyne. Its photochemical isomerization afforded the corresponding disilabenzvalene, which was structurally characterized by a single-crystal X-ray diffraction analysis.

Graphical abstract: The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

Supplementary files

Article information

Article type
Communication
Submitted
28 Kul 2019
Accepted
17 Mud 2019
First published
17 Mud 2019

Dalton Trans., 2019,48, 9053-9056

The formation of a 1,4-disilabenzene and its isomerization into a disilabenzvalene derivative

T. Sugahara, T. Sasamori and N. Tokitoh, Dalton Trans., 2019, 48, 9053 DOI: 10.1039/C9DT01322A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements