Issue 21, 2017

Ultrasmall PbS quantum dots: a facile and greener synthetic route and their high performance in luminescent solar concentrators

Abstract

Synthesis of quantum dots (QDs) with widely size-tunable optical absorption and high photoluminescence quantum yield (PL QY) via a facile route is highly desired. By introducing tributylphosphine (TBP) into a relatively green synthesis method based on the use of S, PbCl2 and oleylamine (OLA), we conveniently synthesized ultrasmall PbS QDs with the first excitonic absorption peak wavelength as short as 705 nm, without using a glove box, which cannot be achieved by previously reported approaches, without involving smelly S precursors (such as bis(trimethylsilyl) sulfide). Such synthesized PbS QDs show narrow size distributions without any aggregation and demonstrate high PL QY in the range of 60–90%, depending on the QD size. Based on nuclear magnetic resonance spectroscopy and X-ray diffraction investigations, TBP was found to act as the passivation ligand on the surface of QDs while simultaneously assisting the transformation of PbCl2–OLA into more reactive Pb(OH)Cl that can directly participate the nucleation process, yielding ultrasmall PbS QDs. This new finding renders Pb(OH)Cl a very promising, new lead precursor for convenient synthesis of PbS and other lead-based QDs. We also demonstrate that the process can be readily scaled up. After synthesizing a thin CdS shell (∼0.1 nm), ultrasmall core/shell QDs with a large Stokes shift (0.36 eV) and good stability were employed for fabricating near infrared (NIR) luminescent solar concentrators, which led to a record-high optical efficiency of ∼1.2% at a geometric factor of ∼50 (10 cm in length). The TBP route developed herein is very promising for synthesizing high quality ultrasmall QDs that have high potential in NIR-related applications.

Graphical abstract: Ultrasmall PbS quantum dots: a facile and greener synthetic route and their high performance in luminescent solar concentrators

Supplementary files

Article information

Article type
Paper
Submitted
13 Yan 2017
Accepted
02 Mud 2017
First published
02 Mud 2017

J. Mater. Chem. A, 2017,5, 10250-10260

Ultrasmall PbS quantum dots: a facile and greener synthetic route and their high performance in luminescent solar concentrators

L. Tan, Y. Zhou, F. Ren, D. Benetti, F. Yang, H. Zhao, F. Rosei, M. Chaker and D. Ma, J. Mater. Chem. A, 2017, 5, 10250 DOI: 10.1039/C7TA01372H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements