Issue 41, 2017

Evidence of single electron transfer from the enolate anion of an N,N′-dialkyldiketopiperazine additive in BHAS coupling reactions

Abstract

A designed N,N′-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.

Graphical abstract: Evidence of single electron transfer from the enolate anion of an N,N′-dialkyldiketopiperazine additive in BHAS coupling reactions

Supplementary files

Article information

Article type
Paper
Submitted
02 Ndz 2017
Accepted
05 Nhl 2017
First published
05 Nhl 2017

Org. Biomol. Chem., 2017,15, 8810-8819

Evidence of single electron transfer from the enolate anion of an N,N′-dialkyldiketopiperazine additive in BHAS coupling reactions

K. J. Emery, T. Tuttle and J. A. Murphy, Org. Biomol. Chem., 2017, 15, 8810 DOI: 10.1039/C7OB02209C

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