Issue 100, 2017
From the journal:

Chemical Communications

An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides†

Srobona Sena  and  François P. Gabbaï ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA
E-mail: francois@tamu.edu

Abstract

We describe the synthesis of an ambiphilic phosphine/H-bond donor ligand featuring a trifluoroacetamide functionality, its coordination to gold(I) chloride, and its application as a self-activating catalyst for the cyclization of propargylamides.

Graphical abstract: An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides

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Article information

DOI
https://doi.org/10.1039/C7CC06065C
Article type
Communication
Submitted
03 Mha 2017
Accepted
22 Huk 2017
First published
22 Huk 2017

Chem. Commun., 2017,53, 13356-13358

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An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides

S. Sen and F. P. Gabbaï, Chem. Commun., 2017, 53, 13356 DOI: 10.1039/C7CC06065C

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