Issue 74, 2017

Photoinduced reversible spin-state switching of an FeIII complex assisted by a halogen-bonded supramolecular network

Abstract

The organization of a molecular FeIII complex embedded in a halogen-bonded 2D network is chemically tuned to trigger temperature- and light-induced spin-state switching. We attribute the associated magnetic properties and the unprecedented photoswitching effect to the optimized structural confinement provided by the presence of the supramolecular host framework.

Graphical abstract: Photoinduced reversible spin-state switching of an FeIII complex assisted by a halogen-bonded supramolecular network

Supplementary files

Article information

Article type
Communication
Submitted
16 Mud 2017
Accepted
24 Mha 2017
First published
24 Mha 2017

Chem. Commun., 2017,53, 10283-10286

Photoinduced reversible spin-state switching of an FeIII complex assisted by a halogen-bonded supramolecular network

I. Jeon, C. Mathonière, R. Clérac, M. Rouzières, O. Jeannin, E. Trzop, E. Collet and M. Fourmigué, Chem. Commun., 2017, 53, 10283 DOI: 10.1039/C7CC03797J

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