Issue 50, 2012
From the journal:

Chemical Communications

Meta-B-entacenes: new polycyclic aromatics incorporating two fused borepin rings†‡

David R. Levine,a   Anthony Caruso, Jr.,a   Maxime A. Sieglera  and  John D. Tovar*a  

* Corresponding authors

a Department of Chemistry, Department of Materials Science and Engineering, Johns Hopkins University, 3400 North Charles Street (NCB 316), Baltimore, USA
E-mail: tovar@jhu.edu
Fax: (+1)410-516-7044

Abstract

The synthesis of new boron-containing acenes (meta-B-entacenes) is reported. These compounds exhibit slightly non-planar core geometries with blue-shifted spectral properties and more negative electrochemical reduction potentials relative to known para isomers. Polarizable π-extended architectures were realized via cross-coupling procedures with chloro-functionalized precursors.

Graphical abstract: Meta-B-entacenes: new polycyclic aromatics incorporating two fused borepin rings

  • This article is part of the themed collection: Aromaticity
About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC32500D
Article type
Communication
Submitted
06 Dzi 2012
Accepted
23 Dzi 2012
First published
24 Dzi 2012

Chem. Commun., 2012,48, 6256-6258

Permissions

Request permissions

Meta-B-entacenes: new polycyclic aromatics incorporating two fused borepin rings

D. R. Levine, A. Caruso, M. A. Siegler and J. D. Tovar, Chem. Commun., 2012, 48, 6256 DOI: 10.1039/C2CC32500D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements