Issue 43, 2012

Diborane(4)–metal bonding: between hydrogen bridges and frustrated oxidative addition

Abstract

The metal complexes [M{HB(hpp)}2(CO)4] (M = Cr, Mo or W) and [M(cod){HB(hpp)}2Cl] (M = Rh or Ir) of the doubly-base stabilized diborane(4) ligand [HB(hpp)]2 were fully characterized and their bonding nature was investigated in detail. While bonding in the group 6 complexes predominantly occurs through the hydrogen atoms, the metal–ligand interaction in the group 9 complexes can be regarded as an early stage oxidative addition of the boron–boron bond leading to diboryl compounds.

Graphical abstract: Diborane(4)–metal bonding: between hydrogen bridges and frustrated oxidative addition

Supplementary files

Article information

Article type
Communication
Submitted
06 Kul 2012
Accepted
03 Dzi 2012
First published
04 Dzi 2012

Chem. Commun., 2012,48, 5277-5279

Diborane(4)–metal bonding: between hydrogen bridges and frustrated oxidative addition

A. Wagner, E. Kaifer and H. Himmel, Chem. Commun., 2012, 48, 5277 DOI: 10.1039/C2CC31671D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements