Issue 37, 2009

Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C–H bonds

Abstract

Iridium trisboryl complexes containing bisphosphine and bipyridine ligands and pinacolate and catecholate substituents on boron are reported. A large difference in reactivity towards the borylation of C–H bonds is observed for this series of trisboryl complexes, and this difference is attributed to the electron-donating properties of the pinacolate vs.catecholate groups, and the steric and electronic properties of bipyridinevs.bisphosphine ligands.

Graphical abstract: Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C–H bonds

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
14 Maw 2009
Accepted
07 Mha 2009
First published
20 Mha 2009

Chem. Commun., 2009, 5603-5605

Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C–H bonds

C. W. Liskey, C. S. Wei, D. R. Pahls and J. F. Hartwig, Chem. Commun., 2009, 5603 DOI: 10.1039/B913949D

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