Development of highly efficient and selective palladium catalysts for telomerization of 1,3-butadiene with alcohols

Edson Leonardo Scarpa de Souza; Sebastian Ahrens; Anke Spannenberg; Helfried Neumann; Kathrin Junge; Carlos Roque Duarte Correia; Ralf Jackstell; Matthias Beller

doi:10.1039/D5CC01036E

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Development of highly efficient and selective palladium catalysts for telomerization of 1,3-butadiene with alcohols†

Edson Leonardo Scarpa de Souza,‡^a Sebastian Ahrens,

‡^a Anke Spannenberg,^a Helfried Neumann,

^a Kathrin Junge,

^a Carlos Roque Duarte Correia,

^b Ralf Jackstell*^a and Matthias Beller

*^a

Author affiliations

* Corresponding authors

^a Leibniz-Institut für Katalyse e.V., Albert-Einstein-Str. 29a, 18059 Rostock, Germany
E-mail: matthias.beller@catalysis.de

^b Department of Organic Chemistry, Institute of Chemistry, University of Campinas, Rua Josué de Castro, 10384-612, Campinas, São Paulo, Brazil

Abstract

Novel phosphine ligands based on (benzo)furylphosphines, enable the efficient palladium-catalyzed telomerization of 1,3-butadiene with methanol. The synthesis of industrially relevant 1-methoxy-2,7-octadiene (1-MODE) occurs in quantitative yields and excellent productivity (TON = 95.000), even at ambient temperatures.

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DOI: https://doi.org/10.1039/D5CC01036E
Article type: Communication
Submitted: 26 Yan 2025
Accepted: 02 Dzi 2025
First published: 02 Mud 2025
This article is Open Access

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Chem. Commun., 2025,61, 9083-9086

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Development of highly efficient and selective palladium catalysts for telomerization of 1,3-butadiene with alcohols

E. L. S. D. Souza, S. Ahrens, A. Spannenberg, H. Neumann, K. Junge, C. R. D. Correia, R. Jackstell and M. Beller, Chem. Commun., 2025, 61, 9083 DOI: 10.1039/D5CC01036E

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Chemical Communications

Development of highly efficient and selective palladium catalysts for telomerization of 1,3-butadiene with alcohols†

Abstract

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Development of highly efficient and selective palladium catalysts for telomerization of 1,3-butadiene with alcohols

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