Issue 9, 2024

Optimization strategies for key interfaces of LLZO-based solid-state lithium metal batteries

Abstract

Solid-state lithium metal batteries (SSLMBs) are believed to be next-generation energy storage systems owing to their superior safety performance and higher energy density compared with state-of-the-art lithium-ion batteries. Solid-state electrolytes (SSEs), as the most critical component of solid-state batteries (SSBs), determine the performance of the batteries to a large extent. Among different types of SSEs, the garnet-type Li7La3Zr2O12 (LLZO) has an exceptionally high ionic conductivity (10−3 to 10−4 S cm−1) and good chemical stability against lithium metal, providing a fantastic possibility for use in SSLMBs. However, developing usable, accessible LLZO-based SSLMBs is still a difficult task owing to the interfacial issues. This review concentrates on the key interfaces of LLZO-based SSLMBs, including lithium metal/LLZO interfaces, LLZO/cathode interfaces, and internal interfaces of LLZO-based SSEs. The main challenges and corresponding strategies for interface optimization are thoroughly covered. Comprehensive research models and advanced characterization tools deployed and developed to study the aforementioned issues are also outlined. Additionally, effective solutions from the perspective of engineering applications are highlighted. Finally, perspectives for future research are provided to guide the development of LLZO-based SSLMBs.

Graphical abstract: Optimization strategies for key interfaces of LLZO-based solid-state lithium metal batteries

Article information

Article type
Review Article
Submitted
13 Nhl 2023
Accepted
08 Sun 2024
First published
14 Yan 2024

Mater. Chem. Front., 2024,8, 2109-2134

Optimization strategies for key interfaces of LLZO-based solid-state lithium metal batteries

J. Chu, Z. Li, J. Wang, G. Huang and X. Zhang, Mater. Chem. Front., 2024, 8, 2109 DOI: 10.1039/D3QM01111A

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