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Abstract | Cited by

An Au4Ni2 nanocluster containing a square-planar [–PPh2–Au–S–Au–]2 ring and two nickel-pincer arms is reported here. Abundant intra- and inter-cluster noncovalent interactions promote the assembly of the nanocluster into a porous framework material. The assembly-dependent unique solubility and photoluminescence were also investigated.

Graphical abstract: Structure and assembly of a hexanuclear AuNi bimetallic nanocluster

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