Hajar Baguia, Jérôme Beaudelot, Cécile Moucheron and Gwilherm Evano
Chem. Commun., 2022,58, 9080-9083
DOI:
10.1039/D2CC02146C,
Communication
An efficient and general process is reported for the photoinduced, copper-catalysed direct perfluoroalkylation of C–H bonds in a broad range of heteroarenes with commercially available perfluoroalkyl iodides. This redox neutral process is simply based on the use of [Cu(bcp)DPEPhos]PF6 as the photoredox catalyst in the presence of potassium acetate and smoothly operates at room temperature.