Issue 9, 2022

Construction of a colorimetric sensor array based on the coupling reaction to identify phenols

Abstract

Phenols are harmful to the human body and the environment. Since there are a variety of phenols in actual samples, this requires a sensor which possesses the ability to simultaneously distinguish them. Herein, we report a colorimetric sensor array, which uses two nanozymes (Fe–N–C nanozymes and Cu–N–C nanozymes) as electronic tongues for fingerprint identification of six phenols (2,4,6-trichlorophenol (2,4,6-Tri), 4-nitrophenol (P-np), phenol (Phe), 3-chlorophenol (3-CP), 4-chlorophenol (4-CP), and o-nitrophenol (O-np)) in the environment. Nanozymes catalyzed the reaction of hydrogen peroxide, different phenols and 4-aminoantipyrine (4-AAP) to produce different color variations. These signal changes as fingerprints encouraged us to develop a pattern recognition method for the identification of phenols by linear discriminant analysis (LDA). The six phenols at 50 nM have their own response patterns, respectively. Surprisingly, this sensor array had distinguished the six phenols in actual samples successfully.

Graphical abstract: Construction of a colorimetric sensor array based on the coupling reaction to identify phenols

Supplementary files

Article information

Article type
Paper
Submitted
07 N’w 2021
Accepted
02 Sun 2022
First published
07 Sun 2022

Anal. Methods, 2022,14, 892-899

Construction of a colorimetric sensor array based on the coupling reaction to identify phenols

H. Zhong, Y. Xue, B. Liu, Z. Chen, K. Li and X. Zuo, Anal. Methods, 2022, 14, 892 DOI: 10.1039/D1AY02076E

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