All poly(ionic liquid) block copolymer nanoparticles from antagonistic isomeric macromolecular blocks via aqueous RAFT polymerization-induced self-assembly

Jérémy Depoorter; Xibo Yan; Biao Zhang; Guillaume Sudre; Aurélia Charlot; Etienne Fleury; Julien Bernard

doi:10.1039/D0PY00698J

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All poly(ionic liquid) block copolymer nanoparticles from antagonistic isomeric macromolecular blocks via aqueous RAFT polymerization-induced self-assembly†

Jérémy Depoorter,^a Xibo Yan,

^ab Biao Zhang,

^ac Guillaume Sudre,

^d Aurélia Charlot,^a Etienne Fleury^a and Julien Bernard

*^a

Author affiliations

* Corresponding authors

^a Univ Lyon, INSA Lyon, CNRS, IMP UMR 5223, Villeurbanne, France
E-mail: julien.bernard@insa-lyon.fr

^b School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

^c Frontiers Science Center for Flexible Electronics (FSCFE), Shaanxi Institute of Flexible Electronics (SIFE) & Shaanxi Institute of Biomedical Materials and Engineering (SIBME), Northwestern Polytechnical University (NPU), Xi'an, 710072 Shaanxi, China

^d Univ Lyon, Université Claude Bernard Lyon 1, CNRS, IMP UMR 5223, Villeurbanne, France

Abstract

We describe herein a straightforward methodology for designing all-poly(ionic liquid) block copolymer nanoparticles with various morphologies by aqueous RAFT polymerization-induced self-assembly relying on the use of a couple of isomeric ionic liquid monomers giving rise to macromolecular building blocks with antagonistic solution behavior in water.

This article is part of the themed collection: Polymerization-Induced Self-Assembly (PISA)

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Article information

DOI: https://doi.org/10.1039/D0PY00698J
Article type: Paper
Submitted: 13 Mud 2020
Accepted: 06 Maw 2020
First published: 06 Maw 2020

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Polym. Chem., 2021,12, 82-91

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All poly(ionic liquid) block copolymer nanoparticles from antagonistic isomeric macromolecular blocks via aqueous RAFT polymerization-induced self-assembly

J. Depoorter, X. Yan, B. Zhang, G. Sudre, A. Charlot, E. Fleury and J. Bernard, Polym. Chem., 2021, 12, 82 DOI: 10.1039/D0PY00698J

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Polymer Chemistry

All poly(ionic liquid) block copolymer nanoparticles from antagonistic isomeric macromolecular blocks via aqueous RAFT polymerization-induced self-assembly†

Abstract

Supplementary files

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All poly(ionic liquid) block copolymer nanoparticles from antagonistic isomeric macromolecular blocks via aqueous RAFT polymerization-induced self-assembly

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