Issue 46, 2021

From ferrocene to 1,2,3,4,5-pentafluoroferrocene: halogen effect on the properties of metallocene

Abstract

The sequentially fluorinated ferrocenes (1-, 1,2-di, 1,2,3-tri, 1,2,3,4-tetra and 1,2,3,4,5-pentafluoroferrocene) have been synthesized from ferrocene. Rather than a ‘perfluoro’ effect, experimental and computational analysis of the complete series robustly demonstrates a linear additive effect of fluorine on the electrochemical and spectroscopic properties of ferrocene.

Graphical abstract: From ferrocene to 1,2,3,4,5-pentafluoroferrocene: halogen effect on the properties of metallocene

Supplementary files

Article information

Article type
Communication
Submitted
11 Nhl 2021
Accepted
05 Huk 2021
First published
05 Huk 2021

Dalton Trans., 2021,50, 16933-16938

From ferrocene to 1,2,3,4,5-pentafluoroferrocene: halogen effect on the properties of metallocene

W. Erb, N. Richy, J. Hurvois, P. J. Low and F. Mongin, Dalton Trans., 2021, 50, 16933 DOI: 10.1039/D1DT03430H

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