Issue 38, 2021
From the journal:

CrystEngComm

Novel TCNQ-stacking motifs in (12-crown-4)-complexes of alkali metal TCNQ salts†

Bingjia Yan, ORCID logo ‡a   Peter N. Horton, ORCID logo a   Simon C. Weston, ORCID logo §a   Andrea E. Russell ORCID logo a  and  Martin C. Grossel ORCID logo *a  

* Corresponding authors

a School of Chemistry, University of Southampton, Highfield, Southampton, UK
E-mail: M.C.Grossel@soton.ac.uk
Fax: +44 (0)23 8059 3781
Tel: +44 (0)23 8059 3153

Abstract

An investigation of the solid-state behaviour of five 12-crown-4 alkali metal TCNQ complexes, (12-crown-4)2LiTCNQ (1), (12-crown-4)2NaTCNQ (2), (12-crown-4)2Li(TCNQ)2 (3), (12-crown-4)2Na(TCNQ)2 (4), and (12-crown-4)2K(TCNQ)2 (5), reveals an unusual “cross-stitch” packing motif with the extended face-to-face π-stacked TCNQ˙− columns present in complexes 1 and 2. The effect of the presence of additional neutral TCNQ0 has also been explored.

Graphical abstract: Novel TCNQ-stacking motifs in (12-crown-4)-complexes of alkali metal TCNQ salts

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D1CE01075A
Article type
Paper
Submitted
11 Mha 2021
Accepted
30 Mha 2021
First published
31 Mha 2021
This article is Open Access
Creative Commons BY-NC license

CrystEngComm, 2021,23, 6755-6760

Permissions

Request permissions

Novel TCNQ-stacking motifs in (12-crown-4)-complexes of alkali metal TCNQ salts

B. Yan, P. N. Horton, S. C. Weston, A. E. Russell and M. C. Grossel, CrystEngComm, 2021, 23, 6755 DOI: 10.1039/D1CE01075A

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements