Issue 35, 2021

A phosphonate–lanthanoid polyoxometalate coordination polymer: {Ce2P2W16O60L2}n zipper chains

Abstract

2,Image ID:d1ce00896j-t2.gif-P2W16O60} polyoxotungstate cluster units featuring phenylphosphonates and CeIII ions embedded into the segregated lacunary sites of the cluster shell organize into the first coordination polymer of a polyoxometalate functionalized by both organophosphonate and lanthanoid. Inter-cluster Ce–O[double bond, length as m-dash]W links result in double-chains, with {CeIII22,Image ID:d1ce00896j-t3.gif-PV2WVI16O60)L2} cluster units oriented alternatingly perpendicular to the chain propagation direction, akin to the protruding teeth of a zipper.

Graphical abstract: A phosphonate–lanthanoid polyoxometalate coordination polymer: {Ce2P2W16O60L2}n zipper chains

Supplementary files

Article information

Article type
Communication
Submitted
08 Maw 2021
Accepted
23 Mha 2021
First published
23 Mha 2021

CrystEngComm, 2021,23, 5989-5993

A phosphonate–lanthanoid polyoxometalate coordination polymer: {Ce2P2W16O60L2}n zipper chains

W. Wang, N. V. Izarova, J. van Leusen and P. Kögerler, CrystEngComm, 2021, 23, 5989 DOI: 10.1039/D1CE00896J

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