Issue 2, 2020

Supramolecular assembly of bent dinuclear amphiphilic alkynylplatinum(ii) terpyridine complexes: diverse nanostructures through subtle tuning of the mode of molecular stacking

Abstract

A new class of bent amphiphilic alkynylplatinum(II) terpyridine complexes was found to adopt different modes of molecular stacking to give diverse nanostructures. In chlorinated solvents, the complexes aggregate in the presence of water droplets and assist in the formation of porous networks, while in DMSO solutions, they self-assemble to give fibrous nanostructures. The complexes would adopt a head-to-tail tetragonal stacking arrangement, as revealed by X-ray crystallographic studies, computational studies and powder X-ray diffraction (PXRD) studies. Their self-assembly follows a cooperative growth mechanism in DMSO and an isodesmic growth mechanism in DMSO–H2O mixture. The balance between hydrophobic and hydrophilic components of the complex system, in conjunction with the nuclearity and the positioning of the substituents, are found to govern the mode of molecular stacking and the fabrication of precise functional nanostructures. This class of complexes serve as versatile building blocks to construct orderly packed molecular materials and functional materials in a well-controlled manner.

Graphical abstract: Supramolecular assembly of bent dinuclear amphiphilic alkynylplatinum(ii) terpyridine complexes: diverse nanostructures through subtle tuning of the mode of molecular stacking

Supplementary files

Article information

Article type
Edge Article
Submitted
05 Ndz 2019
Accepted
16 Huk 2019
First published
27 Huk 2019
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2020,11, 499-507

Supramolecular assembly of bent dinuclear amphiphilic alkynylplatinum(II) terpyridine complexes: diverse nanostructures through subtle tuning of the mode of molecular stacking

S. K. Leung, A. K. Chan, S. Y. Leung, M. Leung and V. W. Yam, Chem. Sci., 2020, 11, 499 DOI: 10.1039/C9SC04475B

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