Issue 9, 2020

The effect of aggregation behavior on photovoltaic performances in benzodithiophene-thiazolothiazole-based wide band-gap conjugated polymers with side chain position changes

Abstract

Two conjugated donor polymers (PBTz-1 and PBTz-2) based on benzo[1,2-b:4,5-b′]dithiophene and thiazolothiazole (TzTz) with different side chain (2-hexyldecyl) positions were designed and synthesized. Both polymers had similar optical and electrochemical bandgaps as well as deep HOMO levels, but significantly different aggregation behaviors in solution and photovoltaic performances in NF PSCs. Combining their absorption spectra, atomic force microscopy and X-ray diffraction measurements, we found that PBTz-1 exhibited stronger aggregation in solution and crystallization in film than PBTz-2. When they were blended with a non-fullerene acceptor (IT-4F), their blend films showed large differences in organizations and morphologies. In PSCs, the power conversion efficiency (PCE) of the PBTz-1:IT-4F-based PSC was only 6.2%, while the PCE of the PBTz-2:IT-4F-based PSC was up to 12.4%.

Graphical abstract: The effect of aggregation behavior on photovoltaic performances in benzodithiophene-thiazolothiazole-based wide band-gap conjugated polymers with side chain position changes

Supplementary files

Article information

Article type
Paper
Submitted
24 Ndz 2019
Accepted
24 N’w 2019
First published
26 N’w 2019

Polym. Chem., 2020,11, 1629-1636

The effect of aggregation behavior on photovoltaic performances in benzodithiophene-thiazolothiazole-based wide band-gap conjugated polymers with side chain position changes

P. Wan, C. An, T. Zhang, K. Ma, N. Liang, Y. Xu, S. Zhang, B. Xu, J. Zhang and J. Hou, Polym. Chem., 2020, 11, 1629 DOI: 10.1039/C9PY01438A

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