Issue 42, 2020

Architectural and catalytic aspects of designer materials built using metalloligands of pyridine-2,6-dicarboxamide based ligands

Abstract

This perspective presents the design, synthesis and crystal structures of a large number of architectures constructed using assorted metalloligands of pyridine-2,6-dicarboxamide based ligands. The metalloligands offered various appended functional groups, whereas design strategies included varying both their position and number. A combination of these parameters resulted in the development of assorted architectures including discrete trinuclear and tetranuclear complexes as well as 1D/2D/3D coordination polymers. The metalloligand strategy not only assisted in the construction of ordered crystalline materials with varied dimensionalities but also judiciously allowed the incorporation of Lewis acidic and redox-active secondary metals in the resultant architectures. As a result, such designer architectures illustrated their noteworthy role both as homogenous and heterogeneous catalysts in different organic transformation reactions.

Graphical abstract: Architectural and catalytic aspects of designer materials built using metalloligands of pyridine-2,6-dicarboxamide based ligands

Article information

Article type
Perspective
Submitted
01 Ndz 2020
Accepted
22 Ndz 2020
First published
22 Ndz 2020

Dalton Trans., 2020,49, 14731-14748

Architectural and catalytic aspects of designer materials built using metalloligands of pyridine-2,6-dicarboxamide based ligands

S. Pachisia and R. Gupta, Dalton Trans., 2020, 49, 14731 DOI: 10.1039/D0DT03058A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements